Granted Patent B2

US 12,589,059 · App. 17/490,652 · Granted Mar 31, 2026

Inventors: Zachary Maron (Jersey City, NJ); Brian Bodnar (Manasquan, NJ); Anil Shah (East Windsor, NJ)

Assignee: L'OREAL

A61K8/062A61K8/27A61K8/29A61K8/345A61K8/362A61K8/37A61K8/585A61K8/737A61K8/8152A61K8/92A61Q17/04A61K2800/48A61K2800/52A61K2800/594

Abstract

Claims (43)

1 . A sunscreen composition comprising an oil-in-water emulsion of aqueous and oil phases, comprising:

i. at least one lipophilic oil thickener comprising C12-22 alkyl acrylate/hydroxyethylacrylate copolymer;

ii. at least one mineral UV filter including zinc oxide; and

iii. at least one nonionic surfactant selected from the group consisting of polyethylene glycol ethers, polyethylene glycol esters of fatty acids, and combinations thereof,

wherein the composition has an SPF in a range from about 30 to about 55 and exhibits phase stability and processibility.

2 . The sunscreen composition according to claim 1 , wherein:

i. the C12-22 alkyl acrylate/hydroxyethylacrylate copolymer is present from about 0.5% to about 5%;

ii. the zinc oxide is present from about 1% to about 25%; and

iii. the at least one nonionic surfactant selected from the group consisting of polyethylene glycol ethers, polyethylene glycol esters of fatty acids, and combinations thereof is present from at least about 0.1% to about 5%,

wherein the components are present by weight, based on the total weight of the sunscreen composition.

3 . The sunscreen composition according to claim 1 , wherein:

i. the C12-22 alkyl acrylate/hydroxyethylacrylate copolymer is present from about 0.75% to about 3%;

ii. the zinc oxide is present from about 5% to about 15%; and

iii. the at least one nonionic surfactant selected from the group consisting of polyethylene glycol ethers, polyethylene glycol esters of fatty acids, and combinations thereof is present from at least about 0.2% to about 3%,

wherein the components are present by weight, based on the total weight of the sunscreen composition.

4 . The sunscreen composition according to claim 1 , wherein:

i. the C12-22 alkyl acrylate/hydroxyethylacrylate copolymer is present at about 1.8%;

ii. the zinc oxide is present at about 7%; and

iii. the at least one nonionic surfactant selected from the group consisting of polyethylene glycol ethers, polyethylene glycol esters of fatty acids, and combinations thereof is present in a total amount of about 2%,

wherein the components are present by weight, based on the total weight of the sunscreen composition.

5 . The sunscreen composition according to claim 1 , wherein the at least one nonionic surfactant comprises at least one of steareth-2 or steareth-20.

6 . The sunscreen composition according to claim 1 , further comprising one or more non-mineral UV filters selected from organic UV filters.

7 . The sunscreen composition according to claim 1 , further comprising one or more organic UV filters comprising homosalate, octisalate and octocrylene.

8 . The sunscreen composition according to claim 7 , wherein the at least one mineral UV filter comprises the zinc oxide present in an amount in the range from about 5% to about 10%, and wherein homosalate is present in an amount in the range from about 5% to about 15%, octisalate is present in an amount in the range from about 1% to about 7%, and octocrylene is present in an amount in the range from about 7% to about 15%, each present by weight based on the total weight of the sunscreen composition.

9 . The sunscreen composition according to claim 1 , further comprising one or a combination of additives selected from the group consisting of solvents, SPF boosters, humectants, skin care actives, oils, waxes, thickeners, preservatives, pH adjusters, chelating agents, viscosity adjusters, cooling agents, fillers, fragrances, dyes, pigments, and combinations thereof.

10 . The sunscreen composition according to claim 1 , further comprising one or more additives selected from the group consisting of glycerin, propanediol, ethylhexyl methoxycrylene, butyloctyl salicylate, dicaprylyl carbonate, dicaprylyl ether, isopropyl palmitate, diethylhexyl syringylidenemalonate, trisodium ethylenediamine disuccinate, hydroxyacetophenone, citric acid, coco-caprylate/caprate, Oryza sativa cera, candelilla wax, sunflower seed wax, carnauba wax, polyhydroxystearic acid, xanthan gum, chlorphenesin, and combinations thereof.

11 . The sunscreen composition according to claim 1 , wherein the sunscreen composition excludes one or more ingredients selected from the group consisting of gemini surfactants, anionic gelling agents, Aristoflex polymers, pigments, iron oxides, and combinations thereof.

12 . A sunscreen composition comprising an oil-in-water emulsion of aqueous and oil phases, comprising:

i. at least one or more lipophilic thickener comprising C12-22 alkyl acrylate/hydroxyethylacrylate copolymer;

ii. at least one mineral UV filter including zinc oxide;

iii. at least one or more nonionic surfactant consisting of steareth-20 or a mixture of steareth-2 and steareth-20;

iv. at least one or more organic UV filters selected from the group consisting of homosalate, octisalate and octocrylene, and combinations thereof; and

V. one or a combination of additives selected from the group consisting of glycerin, propanediol, ethylhexyl methoxycrylene, butyloctyl salicylate, dicaprylyl carbonate, dicaprylyl ether, isopropyl palmitate, diethylhexyl syringylidenemalonate, trisodium ethylenediamine disuccinate, hydroxyacetophenone, citric acid, coco-caprylate/caprate, Oryza sativa cera, candelilla wax, polyhydroxystearic acid, sunflower seed wax, carnauba wax, xanthan gum, chlorphenesin, and combinations thereof.

13 . The sunscreen composition according to claim 12 , wherein the sunscreen composition demonstrates emulsion structural stability wherein the sun screen composition does not exhibit signs of phase separation, or become inhomogeneous after up to 12 weeks in an ambient temperature in the range from about 25° C. up to and including about 45° C., and maintains processibility wherein the sun screen composition can be produced at commercial scale characterized by a production volume of at least 15 kilograms without loss of emulsion structural stability, and wherein the sunscreen composition demonstrates an SPF (in vivo) in a range from about 30 to about 55.

14 . A sunscreen composition comprising an oil-in-water emulsion of aqueous and oil phases, comprising:

i. at least one or more lipophilic oil thickener comprising C12-22 alkyl acrylate/hydroxyethylacrylate copolymer, present at about 1.8%;

ii. at least one mineral UV filter including zinc oxide, the zinc oxide present at about 7%;

iii. at least one or more nonionic surfactant including steareth-20 or a mixture of steareth-2 and steareth-20, present in a total amount of about 2%;

iv. at least one or more organic UV filters, present in a total amount of about 18%; and

V. one or a combination of ingredients selected from the group consisting of solvents, SPF boosters, humectants, skin care actives, oils, waxes, thickeners, preservatives, pH adjusters, chelating agents, viscosity adjusters, cooling agents, fillers, fragrances, dyes, pigments, and combinations thereof, each present by weight, based on the total weight of the sunscreen composition.

15 . The sunscreen composition according to claim 14 , wherein the sunscreen composition excludes one or more ingredients selected from the group consisting of gemini surfactants, anionic gelling agents, Aristoflex polymers, pigments, iron oxides, and combinations thereof, and wherein the sunscreen composition demonstrates emulsion structural stability, and wherein the sun screen composition does not exhibit signs of phase separation, or become inhomogeneous after up to 12 weeks in an ambient temperature in the range from about 25° C. up to and including about 45° C., and maintains processibility wherein the sun screen composition can be produced at commercial scale characterized by a production volume of at least 15 kilograms without loss of emulsion structural stability, and wherein the sunscreen composition demonstrates an SPF in a range from about 30 to about 55.

16 . The sunscreen composition according to claim 1 , wherein the at least one lipophilic oil thickener is disposed entirely within and thickening the oil phase of the sunscreen composition.

17 . The sunscreen composition according to claim 1 , wherein the sunscreen composition is free of surfactants other than steareth-2 and steareth-20.

Assignments (1)

Continuity (1)

References Cited (23)