Fibre-reinforced resin, porous structure, and molded member
Provided is a porous structure, made from fiber-reinforced resin, which is lightweight and has excellent mechanical properties. The fiber-reinforced resin comprises a reinforcing fiber base material and a thermoplastic resin, wherein the reinforcing fiber base material includes 50-100 weight % reinforcing fibers having a fiber length of 2-10 mm, the total amount of reinforcing fibers being 100 weight %, and the thermoplastic resin has a long chain branched structure.
1 . A fiber reinforced resin comprising a reinforcing fiber base material and a thermoplastic resin, wherein
reinforcing fibers having fiber lengths of 2 mm or more and 10 mm or less account for 50 or more and 100 or less wt % of the total weight, which accounts for 100 wt %, of the reinforcing fibers present in the reinforcing fiber base material,
the thermoplastic resin has long chain branched structures, and
the reinforcing fiber base material has a three-dimensional network structure formed of the reinforcing fibers.
2 . The fiber reinforced resin as set forth in claim 1 , wherein the melt complex viscosity η(0.001) is 3,500 [Pa·s] or more and is measured at a frequency of 0.001 Hz and at a temperature higher by 30° C. than the melting point in the case where the thermoplastic resin is a crystalline resin or at a temperature higher by 80° C. than Tg in the case where it is an amorphous resin.
3 . The fiber reinforced resin as set forth in claim 1 , wherein the ratio G′(0.01)/G′(0.001) of the melt storage modulus G′(0.01) at a frequency of 0.01 Hz to the melt storage modulus G′(0.001) at a frequency of 0.001 Hz is 15 or less when measured at a temperature higher by 30° C. than the melting point in the case where the thermoplastic resin is a crystalline resin or at a temperature higher by 80° C. than Tg in the case where it is an amorphous resin.
4 . The fiber reinforced resin as set forth in claim 1 , wherein the ratio Lw/Ln between the weight average fiber length (Lw) and the number average fiber length (Ln) of the reinforcing fibers is 1 or more and 1.4 or less.
5 . The fiber reinforced resin as set forth in claim 1 , wherein the reinforcing fibers account for 3 or more and 60 or less vol % relative to the total volume of the reinforcing fibers and the thermoplastic resin.
6 . The fiber reinforced resin as set forth in claim 1 , wherein the thermoplastic resin has long chain branched structures and has a branching index of 0.5 or more and 0.95 or less.
7 . The fiber reinforced resin as set forth in claim 1 , wherein the thermoplastic resin has long chain branched structures and has a branching index of 0.8 or more and 0.95 or less.
8 . The fiber reinforced resin as set forth in claim 1 , wherein the thermoplastic resin has a melt flow rate of 1.0 g/10 min or more and 40 g/10 min or less according to JIS K7210:2014.
9 . The fiber reinforced resin as set forth in claim 1 , wherein the reinforcing fiber base material is in the form of nonwoven fabric.
10 . The fiber reinforced resin as set forth in claim 1 , wherein the reinforcing fiber base material is in a compressed state and is immobilized in the thermoplastic resin and also wherein the fiber reinforced resin is expandable when heated at or above a temperature higher by 20° C. than the melting point in the case where the thermoplastic resin is a crystalline resin or at a temperature higher by 100° C. than Tg in the case where it is an amorphous resin.
11 . The fiber reinforced resin as set forth in claim 1 , wherein the thermoplastic resin is a polyolefin based resin or a polystyrene based resin.
12 . A porous structure material of the fiber reinforced resin as set forth in claim 1 , wherein the thermoplastic resin present in meshes of the three-dimensional network structure of the reinforcing fiber base material forms binding structures that bind the reinforcing fibers together and wherein voids are formed as regions that are surrounded by the reinforcing fibers and/or the thermoplastic resin and that contain neither the reinforcing fibers nor the thermoplastic resin.
13 . The porous structure material as set forth in claim 12 wherein the the binding structures formed of the thermoplastic resin extend continuously over 300 μm or more.
14 . Molded members at least partly formed of the porous structure material as set forth in claim 12 .
15 . Molded members at least partly formed of the fiber reinforced resin as set forth in claim 1 .