Adhesive film that can be wound and stamped
An adhesive film that can be wound and stamped having an epoxy-based adhesive compound that can be activated thermally or by UV radiation, and a dye and/or pigment mixed into the adhesive compound for producing a first color change after the activation of the adhesive compound and a second color change after the curing of the adhesive compound.
1 . An adhesive film that can be wound and stamped, comprising:
a UV curable epoxy-based adhesive compound that is activated by UV radiation; and
a dye and/or pigment mixed into the adhesive compound that produces a first color change after the UV activation of the adhesive compound and a second color change after a UV curing of the adhesive compound,
wherein the UV curable adhesive compound of the adhesive film comprises a cationic initiator that is activated by the UV radiation, and the dye and/or pigment comprises a substance that produces the first color change as an effect of an acid produced by the UV activation of the cationic initiator and the second color change due to a decomposition of the acid after UV curing of the UV curable adhesive compound.
2 . The adhesive film of claim 1 , wherein the dye and/or pigment is mixed into the adhesive compound in an amount ranging from 0.001 to 0.2 percent by weight, based on the total weight of the adhesive compound.
3 . The adhesive film of claim 2 , wherein the dye and/or pigment is mixed into the adhesive compound in an amount of 0.01 to 0.07 percent by weight.
4 . The adhesive film of claim 3 , wherein the dye and/or pigment is mixed into the adhesive compound in an amount of 0.015 to 0.04 percent by weight.
5 . The adhesive film of claim 2 , wherein the dye and/or the pigment is an azo dye or an azo pigment.
6 . The adhesive film of claim 1 , wherein the dye and/or pigment is an azo dye or an azo pigment.
7 . The adhesive film of claim 1 , wherein the adhesive compound comprises:
a. 2 to 50 percent by weight of film formers,
b. 10 to 70 percent by weight of aromatic epoxy resins,
c. 0.5 to 7 percent by weight of the cationic initiator,
d. 0.001 to 0.2 percent by weight of the dye and/or pigment,
e. cycloaliphatic epoxy resins, wherein the cycloaliphatic epoxy resins do not exceed 35 percent by weight,
f. 0 to 50 percent by weight of epoxidised polyether compounds, and
g. 0 to 20 percent by weight of a polyol,
wherein the proportions add up to 100%.
8 . The adhesive film of claim 7 , wherein the dye and/or pigment is an azo dye or an azo pigment.
9 . The adhesive film of claim 1 , wherein the adhesive film is a UV-activatable transfer adhesive tape without backing.
10 . The adhesive film of claim 1 , wherein the adhesive film comprises a UV-transparent backing.
11 . The adhesive film of claim 1 , wherein the adhesive film comprises a UV-non-transparent backing.
12 . The adhesive film of claim 1 ,
wherein the dye and/or pigment is selected from the group consisting of: methyl red, methyl orange, Congo red, alizarin yellow R, Fat Blue B01, Orasol Yellow 081, Heliogen Green L8730, and combinations thereof.
13 . The adhesive film of claim 1 , wherein the adhesive film has a structural bond after the UV curing.
14 . The adhesive film of claim 13 , wherein the structural bond of the adhesive film has a quasi-static tensile shear strength of more than 6 MPa.