Granted Patent B2

US 12,599,869 · App. 18/308,352 · Granted Apr 14, 2026

Inventor: Naoki Noguchi (Tokyo, JP)

Assignee: Mitsubishi Chemical Corporation

B01D53/22B01D53/30C07C7/144B01D2257/7025B01D2258/05

Abstract

Claims (54)

1 . A gas separation apparatus comprising a membrane separation device that comprises:

a membrane module that separates a source gas into a primary-side gas and a secondary-side gas with a membrane of the membrane module,

wherein the source gas contains a combustible component,

wherein the primary-side gas has a higher concentration of the combustible component than the secondary-side gas;

a supply line including a pressure pump that pressurizes the source gas and supplies the source gas to a primary side of the membrane module; and

a permeate line including a vacuum pump that depressurizes a secondary side of the membrane module,

wherein the membrane separation device includes:

a detector that detects a composition of the secondary-side gas, and

a controller that stops the pressure pump and the vacuum pump in an instance in which the composition reaches a specified range,

wherein the membrane of the membrane module has a separation factor greater than or equal to 80.

2 . A gas separation apparatus comprising a membrane separation device that comprises:

a membrane module that separates a source gas into a primary-side gas and a secondary-side gas with a membrane of the membrane module,

wherein the source gas contains a combustible component,

wherein the primary-side gas has a higher concentration of the combustible component than the secondary-side gas;

a supply line including a pressure pump that pressurizes the source gas and supplies the source gas to a primary side of the membrane module; and

a permeate line including a vacuum pump that depressurizes a secondary side of the membrane module,

wherein the membrane separation device includes:

a detector that detects a pressure or a flow rate of the secondary side, and

a controller that stops the pressure pump and the vacuum pump in an instance in which the pressure or the flow rate of the secondary side becomes greater than a reference value,

wherein the membrane of the membrane module has a separation factor greater than or equal to 80.

3 . The gas separation apparatus according to claim 2 ,

wherein the reference value is a value at least 10 kPaG higher than a default value in an instance of the pressure, and

wherein the reference value is a value at least 50% higher than a default value in an instance of the flow rate.

4 . The gas separation apparatus according to claim 1 , further comprising a valve controller,

wherein the valve controller causes valves to be closed in the instance in which the composition reaches the specified range, where one of the valves is disposed in a supply line for supplying the source gas to the membrane module, and another of the valves is disposed in a depressurization line of the membrane module.

5 . The gas separation apparatus according to claim 1 , wherein the specified range is an explosive range.

6 . The gas separation apparatus according to claim 1 , wherein the combustible component is methane, and the source gas further comprises carbon dioxide.

7 . The gas separation apparatus according to claim 1 , wherein the vacuum pump is a vacuum pump that reduces a pressure of the secondary side to less than or equal to −30 kPaG.

8 . The gas separation apparatus according to claim 1 , wherein, in an instance in which the source gas is inadvertently introduced, the composition enters the specified range.

9 . The gas separation apparatus according to claim 1 , wherein the source gas is a biogas.

10 . The gas separation apparatus according to claim 2 , wherein the combustible component is methane, and the source gas further comprises carbon dioxide.

11 . A gas separation method, comprising:

performing a gas separation operation with the gas separation apparatus of claim 1 that separates the source gas into the primary-side gas and the secondary-side gas with the membrane of the membrane module, wherein the source gas contains a combustible component, the gas separation operation including:

pressurizing the source gas and supplying the source gas to the primary side of the membrane module, and

depressurizing the secondary side of the membrane module to a pressure lower than an atmospheric pressure;

wherein the primary-side gas has a higher concentration of the combustible component than the secondary-side gas, and

wherein the gas separation method further includes detecting the composition of the secondary-side gas; and

stopping the gas separation operation in an instance in which the composition enters the specified range.

12 . A gas separation method, comprising:

performing a gas separation operation with the gas separation apparatus of claim 2 that separates the source gas into the primary-side gas and the secondary-side gas with the membrane of the membrane module, wherein the source gas contains a combustible component, the gas separation operation including:

pressurizing the source gas and supplying the source gas to the primary side of the membrane module, and

depressurizing the secondary side of the membrane module to a pressure lower than an atmospheric pressure;

wherein the primary-side gas has a higher concentration of the combustible component than the secondary-side gas, and

wherein the gas separation method further includes detecting the pressure or the flow rate of the secondary side; and

stopping the gas separation operation in an instance in which a detected pressure or the pressure or the flow rate exceeds the reference value.

13 . The gas separation method according to claim 12 ,

wherein the reference value is a value at least 10 kPaG higher than a default value in an instance of the detected pressure, and

wherein the reference value is a value at least 50% higher than a default value in an instance of the flow rate.

14 . The gas separation method according to claim 11 , wherein, in the instance in which the composition enters the specified range, valves are closed, where one of the valves is disposed in the supply line for supplying the source gas to the membrane module, and another of the valves is disposed in a depressurization line of the membrane module.

15 . The gas separation method according to claim 11 , wherein the specified range is an explosive range.

16 . The gas separation method according to claim 11 , wherein the combustible component is methane.

17 . The gas separation method according to claim 11 , wherein the pressure of the secondary side is reduced to a pressure 30 kPa or more lower than the atmospheric pressure.

18 . The gas separation method according to claim 11 , wherein, in an instance in which the source gas is inadvertently introduced, the composition enters the specified range.

19 . The gas separation method according to claim 11 , wherein the source gas is a biogas.

Assignments (1)

Priority Claims (1)

Continuity (2)

References Cited (27)