Elastomer composition
A rubber composition is based on 20 to 100 phr of a copolymer of ethylene, of a first 1,3-diene which is 1,3-butadiene, isoprene or a mixture thereof, and of a second 1,3-diene of formula CH 2 ═CR-CH═CH 2 , the symbol R representing a hydrocarbon chain having 3 to 20 carbon atoms, the ethylene units in the copolymer representing more than 50 mol % of the monomer units of the copolymer; 0 to 80 phr of at least one diene elastomer having a weight content of diene units of greater than 50%; 10 to 100 phr of a plasticizing system comprising at least one plasticizing resin having a glass transition temperature above 20° C. and/or at least one plasticizer that is liquid at 23° C.; a reinforcing filler; and a crosslinking system. Also disclosed is an elastomer laminate and a rubber article, in particular a pneumatic or non-pneumatic tire.
1 . A rubber composition based on:
20 to 100 phr of at least one copolymer of ethylene, of a first 1,3-diene which is 1,3-butadiene, isoprene or a mixture thereof, and of a second 1,3-diene of formula (I),
the ethylene units in the copolymer representing more than 50 mol % of the monomer units of the copolymer,
CH 2 ═CR-CH═CH 2 (I),
and
R representing a hydrocarbon chain having 3 to 20 carbon atoms;
0 to 80 phr of at least one diene elastomer having a weight content of diene units of greater than 50%;
35 to 100 phr of a plasticizing system comprising at least one plasticizing resin having a glass transition temperature above 20° C. and at least one plasticizer that is liquid at 23° C.;
a reinforcing filler; and
a crosslinking system.
2 . The rubber composition according to claim 1 , wherein the copolymer contains ethylene units which represent between 50 mol % and 95 mol % of the monomer units of the copolymer.
3 . The rubber composition according to claim 1 , wherein the first 1,3-diene of the copolymer is 1,3-butadiene.
4 . The rubber composition according to claim 1 , wherein the 1,3-diene of formula (I) is myrcene, β-farnesene or a mixture of myrcene and β-farnesene.
5 . The rubber composition according to claim 1 , wherein the copolymer contains units of the first 1,3-diene which represent between 1 mol % and 49 mol % of the monomer units of the copolymer, and
wherein the copolymer contains units of the 1,3-diene of formula (I) which represent between 1 mol % and 50 mol % of the monomer units of the copolymer.
6 . The rubber composition according to claim 1 , wherein the content of the copolymer is within a range extending from 20 to 90 phr, and
wherein the diene elastomer having a weight content of diene units of greater than 50% is present at a content within a range extending from 10 to 80 phr.
7 . The rubber composition according to claim 1 , wherein the diene elastomer having a weight content of diene units of greater than 50% is selected from the group consisting of polybutadienes (BRs), natural rubber (NR), synthetic polyisoprenes (IRs), butadiene copolymers, isoprene copolymers and mixtures of these elastomers.
8 . The rubber composition according to claim 1 , wherein the plasticizer that is liquid at 23° C. is selected from the group consisting of liquid diene polymers, polyolefin oils, naphthenic oils, paraffinic oils, Distillate Aromatic Extract (DAE) oils, Medium Extracted Solvate (MES) oils, Treated Distillate Aromatic Extract (TDAE) oils, Residual Aromatic Extract (RAE) oils, Treated Residual Aromatic Extract (TRAE) oils, Safety Residual Aromatic Extract (SRAE) oils, mineral oils, vegetable oils, ether plasticizers, ester plasticizers, phosphate plasticizers, sulfonate plasticizers and mixtures thereof.
9 . The rubber composition according to claim 1 , wherein the content of plasticizer that is liquid at 23° C. is within a range extending from 1 to 49 phr.
10 . The rubber composition according to claim 1 , wherein the plasticizing resin having a glass transition temperature above 20° C. is selected from the group consisting of cyclopentadiene homopolymer or copolymer resins, dicyclopentadiene homopolymer or copolymer resins, terpene homopolymer or copolymer resins, C5 fraction homopolymer or copolymer resins, C9 fraction homopolymer or copolymer resins, α-methylstyrene homopolymer or copolymer resins and mixtures thereof.
11 . The rubber composition according to claim 1 , wherein the content of plasticizing resin having a glass transition temperature above 20° C. is within a range extending from 1 to 99 phr.
12 . A rubber article comprising the rubber composition according to claim 1 .
13 . The rubber article according to claim 12 , wherein the rubber article is selected from the group consisting of pneumatic tires, non-pneumatic tires, caterpillar tracks, conveyor belts and anti-vibratory articles.