Reducing agent as corrosion inhibitor for machine warewash
Warewash detergent compositions with reducing agents to overcome corrosion challenges in stainless steel dish machines subject to conditions from chlorine sanitizing rinse steps (or other oxidizing chlorine containing compositions) are provided. Liquid and solid detergent composition beneficially containing a reducing agent that reacts with chlorine introduced in sanitizing rinse steps that follow detergent cleaning steps are provided. Methods for ware washing using the detergent compositions with reducing agents and methods for reducing residual chlorine in a ware washing cycle are also provided.
1 . A method of reducing the rate of corrosion in a ware washing machine, comprising:
applying a sanitizing composition to ware in the ware washing machine to provide a sanitizing step, wherein the sanitizing composition comprises at least 30 ppm of chlorine;
reusing water from the sanitizing step to apply a use solution of a liquid or solid detergent composition free of enzymes and bleaching agents, and/or a booster composition to ware in a new wash cycle of the ware washing machine, wherein at least one of the liquid or solid detergent or the booster composition comprises a reducing agent that is a salt containing ammonium cation, and wherein the liquid detergent comprises from about 30 wt-% to about 70 wt-% of an alkalinity source or the solid detergent comprises from about 40 wt-% to about 90 wt-% of an alkalinity source;
reducing a residual chlorine concentration in the reused water for the detergent step of the warewash cycle to less than 20 ppm within 60 seconds; and
reducing the rate of corrosion in the ware washing machine by at least about 50%.
2 . The method of claim 1 , wherein the residual chlorine concentration is reduced by at least about 50% or more.
3 . The method of claim 1 , wherein the use solution of the detergent composition and/or the booster composition comprises from about 10 ppm to about 100 ppm of the reducing agent.
4 . A method of cleaning using a detergent composition that reduces the rate of corrosion in a ware washing machine, comprising:
applying to ware in the ware washing machine a use solution of the detergent composition free of enzymes and bleaching agents using water from a prior sanitizing rinse step containing at least 30 ppm of chlorine, the detergent composition comprising:
a reducing agent that is a salt containing ammonium cation;
about 30 wt-% to about 70 wt-% of an alkalinity source in a liquid detergent composition or about 40 wt-% to about 90 wt-% of an alkalinity source in a solid detergent composition, and;
at least one additional functional ingredient comprising at least one builder, at least one water conditioning polymer, and/or at least one surfactant;
reducing residual chlorine in the ware washing cycle during the detergent step to less than 20 ppm within 60 seconds and thereby reducing the rate of corrosion in the ware washing machine by at least about 50%; and thereafter;
applying a sanitizing composition to ware in the ware washing machine during the sanitizing step of the ware washing cycle, wherein the sanitizing composition comprises chlorine.
5 . The method of claim 4 , wherein the use solution of the detergent composition is diluted with water reused from the chlorine-containing sanitizing rinse step.
6 . The method of claim 4 , wherein the water used to generate the use solution of the detergent composition and/or rinsing ware with the sanitizing composition are heated to a temperature of at least about 120° F.
7 . The method of claim 4 , wherein the use solution of the detergent composition comprises from about 10 ppm to about 100 ppm of the reducing agent.
8 . The method of claim 4 , wherein the use solution of the detergent composition comprises a sufficient concentration of the reducing agent to reduce at least half of the residual chlorine in the use solution.