Method for reducing non-uniform electrode coating degradation and battery cells comprising the same
A method of reducing non-uniform degradation in a battery cell comprising: determining a likely temperature distribution for the battery cell; determining a temperature profile of the battery cell; calculating an electrochemical reaction rate in the battery cell; determining at least one non-uniformity in the electrochemical reaction rate; inducing a non-uniformity in at least one electrode design characteristic to counteract the at least one non-uniformity in the electrochemical reaction rate; and including at least one electrode having the non-uniformity in at least one electrode design characteristic in the battery cell to drive a more uniform electrochemical reaction rate through the battery cell, which could result in decreased fatigue life, particle stress and degradation of the battery cell during, for example, but not limited to high rate operation.
1 . A method of reducing non-uniform degradation in an electrochemical battery cell, comprising:
including at least one electrode in the electrochemical battery cell, the at least one electrode having:
a non-uniformity in at least one electrode design characteristic, wherein the at least one electrode design characteristic having the non-uniformity includes at least one of an electrode coating thickness, and an electrode coating loading,
wherein the non-uniformity in the at least one electrode design characteristic is induced to counteract at least one non-uniformity in an electrochemical reaction rate in the electrochemical battery cell; and
a uniformity in at least another electrode design characteristic, wherein the at least another electrode design characteristic having the uniformity includes an electrode coating porosity.
2 . The method as recited in claim 1 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes:
determining a likely temperature distribution for the electrochemical battery cell;
determining a temperature profile of the electrochemical battery cell;
calculating an electrochemical reaction rate in the electrochemical battery cell;
determining at least one non-uniformity in the electrochemical reaction rate.
3 . The method as recited in claim 2 , wherein the likely temperature distribution is determined based upon a high use case.
4 . The method as recited in claim 3 , wherein the high use case is a DC fast charge.
5 . The method as recited in claim 3 , wherein the high use case is based on a tracked usage.
6 . The method as recited in claim 2 , wherein the battery cell is a cylindrical battery cell and the temperature profile is determined in a radial direction.
7 . The method as recited in claim 6 , wherein the electrochemical reaction rate is highest near a center of the cylindrical battery cell.
8 . The method as recited in claim 6 , wherein the electrochemical reaction rate is highest near an outer diameter of the cylindrical battery cell.
9 . The method as recited in claim 2 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes varying at least one of a porosity, a thickness and a loading.
10 . The method as recited in claim 2 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes varying at least one of the electrode coating thickness and the electrode coating loading, while keeping the electrode coating porosity.
11 . The method as recited in claim 2 , wherein inducing the non-uniformity in the at least one electrode design characteristic including controlling at least one electrode manufacturing process, wherein the at least one electrode manufacturing process includes one of a calendaring pressure, a line speed of a coater, and a flow rate of a slurry.
12 . An electrochemical battery cell, comprising:
at least one electrode having:
a non-uniformity in at least one electrode design characteristic, wherein the at least one electrode design characteristic having the non-uniformity includes at least one of an electrode coating thickness, and an electrode coating loading,
wherein the non-uniformity in the at least one electrode design characteristic is induced to counteract at least one non-uniformity in an electrochemical reaction rate in the electrochemical battery cell; and
a uniformity in at least another electrode design characteristic, wherein the at least another electrode design characteristic having the uniformity includes an electrode coating porosity.
13 . The electrochemical battery cell as recited in claim 12 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes:
determining a likely temperature distribution for the electrochemical battery cell;
determining a temperature profile of the electrochemical battery cell;
calculating the electrochemical reaction in the electrochemical battery cell; and
determining the at least one non-uniformity in the electrochemical reaction rate.
14 . The electrochemical battery cell as recited in claim 13 , wherein the likely temperature distribution is determined based upon a high use case.
15 . The electrochemical battery cell as recited in claim 13 , wherein the electrochemical battery cell is a cylindrical battery cell and the temperature profile is determined in a radial direction.
16 . The electrochemical battery cell as recited in claim 15 , wherein the electrochemical reaction rate is highest near a center of the cylindrical battery cell.
17 . The electrochemical battery cell as recited in claim 15 , wherein the electrochemical reaction rate is highest near an outer diameter of the cylindrical battery cell.
18 . The electrochemical battery cell as recited in claim 12 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes varying at least one of a porosity, a thickness and a loading.
19 . The electrochemical battery cell as recited in claim 12 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes varying the at least one of the electrode coating thickness and the electrode coating loading, while keeping the electrode coating porosity constant.
20 . The electrochemical battery cell as recited in claim 12 , wherein inducing the non-uniformity in the at least one electrode design characteristic includes controlling at least one electrode manufacturing process, wherein the at least one electrode manufacturing process includes one of a calendaring pressure, a line speed of a coater, and a flow rate of a slurry.