Ordered mixture of sulfurized-carbon with ionically conductive particles
Described are active materials for storing metal cations, such as lithium ions, in a cathode of an electrochemical cell. The active materials comprise an ordered mixture of sulfurized carbon (SC) particles, smaller ionically conductive particles, and still smaller electrically conductive particles. In comparison with a random mixture, where SC particles are mixed with particles of another material, the ordered mixture creates discrete, solid composition of more than one type of guest particles on the perimeter of SC host particles for ionic and electronic conduction to and from the SC host particles.
1 . An electrode to store metal cations, the electrode comprising:
sulfurized-carbon particles with an average sulfurized-carbon-particle surface area, the sulfurized-carbon particles to store the metal cations;
each sulfurized-carbon particle including a conductive envelope comprising:
electrically conductive domains in contact with the sulfurized-carbon-particle surface, the electrically conductive domains to conduct electrons to and from the sulfurized-carbon particle; and
close packed ionically conductive particles in contact with the sulfurized-carbon-particle surface forming a continuous envelope around the sulfurized-carbon particle with gaps between adjacent ionically conductive particles sized to permit cation transport to the surface of the sulfurized-carbon particle, wherein the electrically conductive domains are predominantly located in valleys and interstices between the close-packed ionically conductive particles while remaining in contact with the sulfurized-carbon-particle surface, and wherein a median particle size of the ionically conductive particles is at least ten times a median particle size of the electrically conductive domains, the ionically conductive particles to conduct the metal cations to and from the sulfurized-carbon particle.
2 . The electrode of claim 1 , wherein the electrically conductive domains exhibit an electrical conductivity of at least 0.1 S/cm.
3 . The electrode of claim 1 , wherein the ionically conductive particles exhibit an ionic conductivity for the metal cations of at least 10E-5 S/cm.
4 . The electrode of claim 1 , wherein the ionically conductive particles exhibit an ionic conductivity for the metal cations of at least 10E-4 S/cm.
5 . The electrode of claim 1 , wherein the conductive envelope includes gaps between the ionically conductive particles.
6 . The electrode of claim 1 , wherein at least one of the electrically conductive domains and the ionically conductive particles are conductive particles.
7 . The electrode of claim 6 , wherein the conductive particles are spherical.
8 . The electrode of claim 1 , further comprising a current collector, wherein the ionically conductive particles connect into an ionically conductive network encompassing the sulfurized-carbon particles and in contact with the current collector.
9 . The electrode of claim 8 , wherein the electrically conductive domains connect into an electrically conductive network encompassing the sulfurized-carbon particles and in contact with the current collector.
10 . The electrode of claim 1 , further comprising a current collector, wherein the ionically conductive particles are of a concentration gradient that increases away from the current collector.
11 . The electrode of claim 10 , wherein the electrically conductive domains are of a second concentration gradient that increases toward the current collector.
12 . The electrode of claim 1 , wherein the sulfurized-carbon particles comprise agglomerations of smaller sulfurized-carbon particles.
13 . The electrode of claim 1 , wherein the electrically conductive domains are collectively smaller than the ionically conductive particles in dimensions tangential to the sulfurized-carbon-particle surface.
14 . The electrode of claim 13 , wherein the electrically conductive domains are on average smaller than the ionically conductive particles in a dimension normal to the sulfurized-carbon-particle surface.
15 . The electrode of claim 1 , the conductive envelope further comprising a liquid electrolyte.
16 . The electrode of claim 15 , wherein the liquid electrolyte is between and in contact with the ionically conductive particles.
17 . The electrode of claim 1 , wherein the cations are of lithium.
18 . An electrochemical cell comprising:
an anode to store a metal;
an electrolyte in contact with the anode to conduct ions of the metal; and
a cathode in contact with the electrolyte to store the ions of the metal, the cathode including:
sulfurized-carbon particles with an average sulfurized-carbon-particle surface area, the sulfurized-carbon particles to store the ions, each sulfurized-carbon particle including a conductive envelope comprising:
electrically conductive domains in contact with the sulfurized-carbon-particle surface, the electrically conductive domains to conduct electrons to and from the sulfurized-carbon particle; and
close packed ionically conductive particles forming a continuous envelop around and in contact with the sulfurized-carbon-particle surface with gaps between adjacent ionically conductive particles sized to permit cation transport to the surface of the sulfurized-carbon particle, wherein the electrically conductive domains are predominantly located in valleys and interstices between the close-packed ionically conductive particles while remaining in contact with the sulfurized-carbon-particle surface and a median particle size of the ionically conductive particles is at least ten times a median particle size of the electrically conductive domains, the ionically conductive particles to conduct the ions of the metal to and from the sulfurized-carbon particle.
19 . The electrochemical cell of claim 18 , the cathode further comprising a current collector, wherein the ionically conductive particles connect into an ionically conductive network encompassing the sulfurized-carbon particles and in contact with the current collector.
20 . The electrochemical cell of claim 19 , wherein the electrically conductive domains connect into an electrically conductive network encompassing the sulfurized-carbon particles and in contact with the current collector.