IP Library › Granted Patent US 12,613,447
Granted Patent B2
US 12,613,447 · App. 18/439,513 · Granted Apr 28, 2026

Two-dimensional electronic sum-frequency generation apparatus and methods

Inventors: Gugang Chen (Palo Alto, CA); Yi Rao (Logan, UT); Zhi-Chao Huang-Fu (Logan, UT)
Assignees: HONDA MOTOR CO., LTD.; UTAH STATE UNIVERSITY
G02F1/3534G02F1/392H01S3/1625H01S3/1636G02F2203/11
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Quick Facts
Patent No.
US 12,613,447
App. No.
18/439,513
Granted
Apr 28, 2026
Kind
B2
Abstract

Aspects of the present disclosure generally relate to two-dimensional electronic apparatuses and methods of use. A two-dimensional electronic sum frequency generation (2D-ESFG) apparatus includes an amplifier including a laser source. A broadband optical parametric amplifier (BOPA) is optically coupled to the amplifier. The BOPA includes a two-stage amplifier. An etalon is optically coupled to the amplifier. The etalon includes two or more partially reflective substrate optical flats. A noncollinear optical parametric amplifier (NOPA) is optically coupled to the amplifier. A dispersive filter pulse shaper is optically coupled to the NOPA. A synchronizer including a galvanometer mirror is optically coupled to the BOPA, the etalon, and the dispersive filter pulse shaper. A detector is optically coupled to the synchronizer.

Claims (48)

1 . A two-dimensional electronic sum frequency generation (2D-ESFG) apparatus, the apparatus comprising:

an amplifier comprising a laser source;

a broadband optical parametric amplifier (BOPA) optically coupled to the amplifier, the BOPA comprising a two-stage amplifier;

an etalon optically coupled to the amplifier, the etalon comprising two or more partially reflective substrate optical flats;

a noncollinear optical parametric amplifier (NOPA) optically coupled to the amplifier;

a dispersive filter pulse shaper optically coupled to the NOPA;

a synchronizer comprising a galvanometer mirror optically coupled to the BOPA, the etalon, and the dispersive filter pulse shaper; and

a detector optically coupled to the synchronizer.

2 . The apparatus of claim 1 , wherein the laser source comprises a titanium:sapphire laser.

3 . The apparatus of claim 1 , further comprising a first beam splitter and a second beam splitter.

4 . The apparatus of claim 3 , wherein the first beam splitter is optically coupled to the amplifier, the BOPA, and the second beam splitter.

5 . The apparatus of claim 3 , wherein the second beam splitter is optically coupled to the first beam splitter, the etalon, and the NOPA.

6 . The apparatus of claim 1 , wherein the galvanometer mirror comprises a single-axis galvanometer mirror.

7 . The apparatus of claim 1 , wherein the detector comprises a charge-coupled detector (CCD).

8 . A two-dimensional electronic sum frequency generation (2D-ESFG) apparatus, the apparatus comprising:

an amplifier comprising a laser source adapted to emit a laser light;

a noncollinear optical parametric amplifier (NOPA) adapted to shape the laser light emitted from the amplifier;

a dispersive filter pulse shaper adapted to generate a pulse pump pair from the laser light shaped by the NOPA;

a synchronizer comprising a galvanometer mirror adapted to reflect the pulse pump pair; and

a detector adapted to detect a wavelength of the pulse pump pair.

9 . The apparatus of claim 8 , wherein the laser source comprises a titanium:sapphire laser.

10 . The apparatus of claim 8 , further comprising a first beam splitter optically coupled to an amplifier.

11 . The apparatus of claim 10 , wherein the first beam splitter is further optically coupled to a second beam splitter.

12 . The apparatus of claim 11 , wherein the second beam splitter is further optically coupled to the NOPA.

13 . The apparatus of claim 8 , wherein the galvanometer mirror comprises a single-axis galvanometer mirror.

14 . The apparatus of claim 8 , wherein the detector comprises a charge-coupled detector (CCD).

15 . A method, the method comprising:

emitting a light from an amplifier to a first beam splitter, the first beam splitter configured to produce a first portion of light and a second portion of light;

producing a third portion of light and a fourth portion of light by directing the second portion of light to a second beam splitter;

directing the first portion of light to a broadband optical parametric amplifier (BOPA);

directing the third portion of light to an etalon comprising two or more partially reflective substrate optical flats;

directing the fourth portion of light to a noncollinear optical parametric amplifier (NOPA), wherein the fourth portion of light exits the NOPA and is directed to a dispersive filter pulse shaper;

producing an electronic sum frequency generation (ESFG) light by overlaying the first portion of light exiting the BOPA, the third portion of light exiting the etalon, and the fourth portion of light exiting the dispersive filter pulse shaper on a sample;

splitting the ESFG light using a synchronizer to form a first portion of ESFG light and a second portion of ESFG light; and

detecting the first portion of ESFG light and the second portion of ESFG light.

16 . The method of claim 15 , wherein the first portion of light comprises an ultra-broadband short wave infrared light (SWIR) comprising:

a wavelength of about 1200 nm to about 2400 nm;

pulse energy of about 200 μJ to about 300 μJ; and

a pulse duration of about 100 fs to about 300 fs.

17 . The method of claim 15 , wherein the third portion of light comprises:

a wavelength of about 700 nm to about 900 nm;

a pulse energy of about 1.7 mJ to about 1.9 mJ; and

a pulse duration of about 1 ps to about 1000 ps.

18 . The method of claim 15 , wherein the fourth portion of light comprises:

a wavelength of about 500 nm to about 540 nm; and

a pulse energy of about 5 μJ to about 10 μJ.

19 . The method of claim 15 , further comprising splitting the ESFG light by rotating the synchronizer at a scan angle of about −1.5° to about 1.5°.

20 . The method of claim 15 , further comprising splitting the ESFG light by oscillating the synchronizer at a frequency of about 400 Hz to about 600 Hz.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 5, 2024
From: RAO, YI; HUANGFU, ZHICHAO
To: UTAH STATE UNIVERSITY
Reel/Frame 067917/0072 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 11, 2024
From: CHEN, GUGANG
To: HONDA MOTOR CO., LTD.
Reel/Frame 066713/0681 →
Continuity (1)
Related Publication 20250258420A1 · Aug 14, 2025
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Liu, S.; Liu, A.-a.; Wen, B.; Zhang, R.; Zhou, C.; Liu, L.-M.; Ren, Z. Coverage Dependence of Methanol Dissociation on TiO2(110). The Journal of Physical Chemistry Letters 2015, 6 (16), 3327-3334. [cited by applicant]
Rao, Y.; Comstock, M.; Eisenthal, K. B. Absolute Orientation of Molecules at Interfaces. The Journal of Physical Chemistry B 2006, 110 (4), 1727-1732. [cited by applicant]
Esenturk, O.; Walker, R. A. Surface vibrational structure at alkane liquid/vapor interfaces. The Journal of Chemical Physics 2006, 125 (17), 174701. [cited by applicant]
Isaienko, O.; Nihonyanagi, S.; Sil, D.; Borguet, E. Observation of the Bending Mode of Interfacial Water at Silica Surfaces by Near-Infrared Vibrational Sum-Frequency Generation Spectroscopy of the [Stretch + Bend] Comb… [cited by applicant]
Zhang, Z.; Kim, J.; Khoury, R.; Saghayezhian, M.; Haber, L. H.; Plummer, E. W. Surface sum frequency generation spectroscopy on non-centrosymmetric crystal GaAs (001). Surface Science 2017, 664, 21-28. [cited by applicant]
Stiopkin, I. V.; Weeraman, C.; Pieniazek, P. A.; Shalhout, F. Y.; Skinner, J. L.; Benderskii, A. V. Hydrogen bonding at the water surface revealed by isotopic dilution spectroscopy. Nature 2011, 474 (7350), 192-195. [cited by applicant]
Chowdhury, A. U.; Liu, F.; Watson, B. R.; Ashkar, R.; Katsaras, J.; Patrick Collier, C.; Lutterman, D. A.; Ma, Y.-Z.; Calhoun, T. R.; Doughty, B. Flexible approach to vibrational sum-frequency generation using shaped ne… [cited by applicant]
Wang, Z.; Carter, J. A.; Lagutchev, A.; Koh, Y. K.; Seong, N.-H.; Cahill, D. G.; Dlott, D. D. Ultrafast Flash Thermal Conductance of Molecular Chains. Science 2007, 317 (5839), 787-790. [cited by applicant]
Pullanchery, S.; Kulik, S.; Rehl, B.; Hassanali, A.; Roke, S. Charge transfer across C—H—O hydrogen bonds stabilizes oil droplets in water. Science 2021, 374 (6573), 1366-1370. [cited by applicant]
Bredenbeck, J.; Ghosh, A.; Smits, M.; Bonn, M. Ultrafast Two Dimensional-Infrared Spectroscopy of a Molecular Monolayer. Journal of the American Chemical Society 2008, 130 (7), 2152-2153. [cited by applicant]
Nihonyanagi, S.; Singh, P. C.; Yamaguchi, S.; Tahara, T. Ultrafast Vibrational Dynamics of a Charged Aqueous Interface by Femtosecond Time-Resolved Heterodyne-Detected Vibrational Sum Frequency Generation. Bulletin of t… [cited by applicant]
Singh, P. C.; Nihonyanagi, S.; Yamaguchi, S.; Tahara, T. Ultrafast vibrational dynamics of water at a charged interface revealed by two-dimensional heterodyne-detected vibrational sum frequency generation. The Journal o… [cited by applicant]
Xiong, W.; Laaser, J. E.; Mehlenbacher, R. D.; Zanni, M. T. Adding a dimension to the infrared spectra of interfaces using heterodyne detected 2D sum-frequency generation spectroscopy. Proceedings of the National Academ… [cited by applicant]
Dunkelberger, E. B.; Grechko, M.; Zanni, M. T. Transition Dipoles from 1D and 2D Infrared Spectroscopy Help Reveal the Secondary Structures of Proteins: Application to Amyloids. The Journal of Physical Chemistry B 2015,… [cited by applicant]
Deng, G.-H.; Qian, Y.; Rao, Y. Development of ultrafast broadband electronic sum frequency generation for charge dynamics at surfaces and interfaces. The Journal of Chemical Physics 2019, 150 (2), 024708. [cited by applicant]
Deng, G.-H.; Qian, Y.; Wei, Q.; Zhang, T.; Rao, Y. Interface-Specific Two-Dimensional Electronic Sum Frequency Generation Spectroscopy. The Journal of Physical Chemistry Letters 2020, 11 (5), 1738-1745. [cited by applicant]
Deng, G.-H.; Qian, Y.; Zhang, T.; Han, J.; Chen, H.; Rao, Y. Two-dimensional electronic-vibrational sum frequency spectroscopy for interactions of electronic and nuclear motions at interfaces. Proceedings of the Nationa… [cited by applicant]