Granted Patent B2

US 12,622,132 · App. 18/229,808 · Granted May 5, 2026

Inventors: Akira Nagasaka (Atsugi, JP); Kunihiko Suzuki (Isehara, JP); Ryo Narukawa (Hadano, JP)

Assignee: Semiconductor Energy Laboratory Co., Ltd.

H10K50/167H10K50/157H10K59/131H10K59/351H10K59/40H10K85/6572H10K85/6574H10K85/6576H10K2101/10H10K2101/30

Abstract

Claims (57)

1 . A light-emitting device comprising:

a first electrode;

a second electrode; and

a light-emitting layer between the first electrode and the second electrode,

wherein the light-emitting layer comprises a light-emitting substance and a first organic compound,

wherein a difference between a sum of energy of the first organic compound in a ground state and energy of an oxygen molecule in a ground state and energy of a transition state formed by the first organic compound and the oxygen molecule is greater than or equal to 1.84 eV, and

wherein a difference between the energy of the transition state formed by the first organic compound and the oxygen molecule and energy of an oxygen adduct of the first organic compound in a ground state is less than or equal to 0.87 eV.

2 . The light-emitting device according to claim 1 ,

wherein the energy of the oxygen adduct of the first organic compound in a ground state is higher than the sum of the energy of the first organic compound in a ground state and the energy of the oxygen molecule in a ground state, and

wherein a difference between the energy of the oxygen adduct of the first organic compound in a ground state and the sum of the energy of the first organic compound in a ground state and the energy of the oxygen molecule in a ground state is greater than or equal to 0.97 eV.

3 . The light-emitting device according to claim 1 ,

wherein the first organic compound comprises a first partial structure and a second partial structure different from the first partial structure,

wherein highest occupied molecular orbital distribution of the first organic compound is located on the first partial structure, and

wherein the oxygen adduct is formed when an oxygen molecule is added to the second partial structure.

4 . A light-emitting apparatus comprising:

the light-emitting device according to claim 1 ; and

a transistor or a substrate.

5 . An electronic device comprising:

the light-emitting apparatus according to claim 4 ; and

a sensor unit, an input unit, or a communication unit.

6 . A lighting device comprising:

the light-emitting apparatus according to claim 4 ; and

a housing.

7 . A light-emitting device comprising:

a first electrode;

a second electrode; and

a light-emitting layer between the first electrode and the second electrode,

wherein the light-emitting layer comprises a light-emitting substance and a first organic compound,

wherein the first organic compound is represented by any one of General Formula (G1-1), General Formula (G1-2), and General Formula (G1-3),

wherein, in the Formula (G1-1), General Formula (G1-2), and General Formula (G1-3):

Q 1 represents oxygen or sulfur;

each of R 1 to R 8 independently represents any one of hydrogen, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, substituted or unsubstituted monocyclic saturated hydrocarbon having 5 to 7 carbon atoms, and substituted or unsubstituted polycyclic saturated hydrocarbon having 7 to 10 carbon atoms;

n represents an integer of 0 to 4;

Ht uni represents a hole-transport skeleton;

each of A1, A2, and A3 is represented by any one of General Formulae (Ax-1) to (Ax-5);

Q 2 represents oxygen or sulfur;

each of R 11 to R 14 independently represents any one of hydrogen, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, substituted or unsubstituted monocyclic saturated hydrocarbon having 5 to 7 carbon atoms, and substituted or unsubstituted polycyclic saturated hydrocarbon having 7 to 10 carbon atoms;

each of R 15 to R 19 represents 1 to 4 substituents and independently represents any one of hydrogen, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, substituted or unsubstituted monocyclic saturated hydrocarbon having 5 to 7 carbon atoms, and substituted or unsubstituted polycyclic saturated hydrocarbon having 7 to 10 carbon atoms; and

* represents a bonding portion with any one of benzofuropyrimidine rings and benzothienopyrimidine rings in the General Formula (G1-1), General Formula (G1-2), and General Formula (G1-3),

wherein a difference between a sum of energy of the first organic compound in a ground state and energy of an oxygen molecule in a ground state and energy of a transition state formed by the first organic compound and the oxygen molecule is greater than or equal to 1.84 eV, and

wherein a difference between the energy of the transition state formed by the first organic compound and the oxygen molecule and energy of an oxygen adduct of the first organic compound in a ground state is less than or equal to 0.87 eV.

8 . The light-emitting device according to claim 7 ,

wherein the energy of the oxygen adduct of the first organic compound in a ground state is higher than the sum of the energy of the first organic compound in a ground state and the energy of the oxygen molecule in a ground state, and

wherein a difference between the energy of the oxygen adduct of the first organic compound in a ground state and the sum of the energy of the first organic compound in a ground state and the energy of the oxygen molecule in a ground state is greater than or equal to 0.97 eV.

9 . The light-emitting device according to claim 7 ,

wherein the first organic compound comprises a first partial structure and a second partial structure different from the first partial structure,

wherein highest occupied molecular orbital distribution of the first organic compound is located on the first partial structure, and

wherein the oxygen adduct is formed when an oxygen molecule is added to the second partial structure.

10 . A light-emitting apparatus comprising:

the light-emitting device according to claim 7 ; and

a transistor or a substrate.

11 . An electronic device comprising:

the light-emitting apparatus according to claim 10 ; and

a sensor unit, an input unit, or a communication unit.

12 . A lighting device comprising:

the light-emitting apparatus according to claim 10 ; and

a housing.

Assignments (1)

Priority Claims (2)

Continuity (1)

References Cited (13)