IP Library Granted Patent US 12,624,271
Granted Patent B2
US 12,624,271 · App. 18/747,841 · Granted May 12, 2026

Methods for freeing differentially stuck pipes

Inventors: Hasmukh A. Patel (Houston, TX); Ahmet Atilgan (Houston, TX); Nicolas Osorio Labrador (Houston, TX); Qusai Darugar (Houston, TX)
Assignee: SAUDI ARABIAN OIL COMPANY
C09K8/05C09K8/206C09K8/24E21B31/035
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Quick Facts
Patent No.
US 12,624,271
App. No.
18/747,841
Granted
May 12, 2026
Kind
B2
Abstract

Methods for freeing differentially stuck pipes may comprise introducing a spotting fluid composition in the vicinity of a portion of a differentially stuck pipe in a well, such that the spotting fluid contacts a material surrounding the portion of the differentially stuck pipe. The spotting fluid may comprise about 0.01 M to about 5 M of an oxidative agent comprising a metal ferrate(VI) and an aqueous solution.

Claims (28)

1 . A method comprising:

introducing a spotting fluid composition in the vicinity of a portion of a differentially stuck pipe in a well, such that the spotting fluid contacts a material surrounding the portion of the differentially stuck pipe, the spotting fluid composition comprising:

about 0.01 M to about 5 M of an oxidative agent comprising a metal ferrate(VI); and

an aqueous alkaline solution.

2 . The method of claim 1 , wherein the metal ferrate(VI) comprises potassium ferrate, sodium ferrate, or a combination thereof.

3 . The method of claim 1 , wherein a pH of the spotting fluid composition is about 4 to about 11.

4 . The method of claim 1 , wherein the aqueous alkaline solution comprises potassium hydroxide.

5 . The method of claim 1 , wherein the spotting fluid composition is able to withstand a temperature of about 70° F. to about 250° F.

6 . The method of claim 1 , wherein a downhole pressure of the well is about 50 psi to about 1,500 psi.

7 . The method of claim 1 , further comprising allowing the spotting fluid composition to interact with the material surrounding the portion of the differentially stuck pipe over a period of time.

8 . The method of claim 7 , wherein after the period of time, the spotting fluid composition contributes to a degradation of the material surrounding the portion of differentially stuck pipe.

9 . The method of claim 1 , wherein the material comprises a filter cake, the filter cake comprising a drilling mud.

10 . The method of claim 9 , wherein the drilling mud comprises a water-based mud, a brine-based mud, or a combination thereof.

11 . The method of claim 9 , wherein the drilling mud comprises a swellable clay, a polymer viscosifier, a weighting material, a chemical additive, a pH modifier, or any combination thereof.

12 . The method of claim 11 , wherein the polymer viscosifier comprises a natural polymer, a synthetic polymer, or a combination thereof.

13 . The method of claim 12 , wherein the polymer viscosifier comprises a natural polymer, and the natural polymer comprises xanthan gum, starch, or a combination thereof.

14 . The method of claim 12 , wherein the polymer viscosifier comprises a synthetic polymer, and the synthetic polymer comprises an acrylamide-based polymer.

15 . A method comprising:

introducing a spotting fluid composition in the vicinity of a portion of a differentially stuck pipe in a well having a downhole pressure of about 50 psi to about 1,500 psi, such that the spotting fluid contacts a filter cake surrounding the portion of the differentially stuck pipe, the spotting fluid composition comprising:

about 0.01 M to about 5 M of an oxidative agent comprising potassium ferrate, sodium ferrate, or a combination thereof; and

an aqueous alkaline solution comprising potassium hydroxide;

wherein the spotting fluid has a pH of about 4 to about 11 and is able to withstand a temperature of about 70° F. to about 250° F.; and

allowing the spotting fluid composition to interact with the filter cake surrounding the portion of the differentially stuck pipe over a period of time, wherein after the period of time, the spotting fluid composition contributes to a degradation of the filter cake surrounding the portion of differentially stuck pipe.

16 . The method of claim 15 , wherein the filter cake comprises a drilling mud, the drilling mud comprising a water-based mud, a brine-based mud, or a combination thereof.

17 . The method of claim 16 , wherein the drilling mud comprises a swellable clay, a polymer viscosifier, a weighting material, a chemical additive, a pH modifier, or any combination thereof.

18 . The method of claim 17 , wherein the polymer viscosifier comprises a natural polymer, a synthetic polymer, or a combination thereof.

19 . The method of claim 18 , wherein the polymer viscosifier comprises a natural polymer, and the natural polymer comprises xanthan gum, starch, or a combination thereof.

20 . The method of claim 18 , wherein the polymer viscosifier comprises a synthetic polymer, and the synthetic polymer comprises an acrylamide-based polymer.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 28, 2025
From: SAUDI ARAMCO UPSTREAM TECHNOLOGY COMPANY
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 071235/0170 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 2, 2025
From: ARAMCO SERVICES COMPANY
To: SAUDI ARAMCO UPSTREAM TECHNOLOGY COMPANY
Reel/Frame 070716/0110 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2024
From: PATEL, HASMUKH A.; ATILGAN, AHMET; LABRADOR, NICOLAS OSORIO; DARUGAR, QUSAI
To: ARAMCO SERVICES COMPANY
Reel/Frame 067771/0470 →
Continuity (1)
Related Publication 20250388800A1 · Dec 25, 2025
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