IP Library › Granted Patent US 12,624,416
Granted Patent B2
US 12,624,416 · App. 17/803,831 · Granted May 12, 2026

Rare earth laser-assisted metal production and separation

Inventors: Cajetan Ikenna Nlebedim (Ames, IA); Abhishek Sarkar (Kanpur, IN); Pranav Shrotriya (Ames, IA); Denis Prodius (Ames, IA); Ho-won Noh (Ames, IA); Thomas Lograsso (Ames, IA)
Assignee: Iowa State University Research Foundation, Inc.
C22B4/08B01J19/121C22B4/04C22B59/00B01J2219/12
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Quick Facts
Patent No.
US 12,624,416
App. No.
17/803,831
Granted
May 12, 2026
Kind
B2
Abstract

A compound or complex containing a rare earth element is impinged with a pulsed laser that is so controlled as to photochemically reduce and obtain a rare earth metal (REM). A mixture of REM salts can be impinged using laser light tuned to selectively reduce a particular rare earth-containing salt of the mixture to separate out as its respective rare earth metal.

Claims (19)

1 . A method of producing a rare earth metal, comprising impinging a precursor rare earth element-containing compound material in a sub-atmospheric processing chamber with a pulsed laser light controlled in a manner to reduce at least part of the rare earth element-containing compound material in the chamber to yield a rare earth metal.

2 . The method of claim 1 wherein the precursor rare earth element-containing material comprises a rare earth compound or rare earth complex.

3 . The method of claim 1 wherein the rare earth metal comprises at least one of La, Ce, Pr, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and/or Lu.

4 . The method of claim 2 wherein the precursor rare earth element-containing compound material comprises at least one of an oxide, hydroxide, oxalate, halide or other salts of the rare earth element.

5 . The method of claim 1 wherein the rare earth element-containing compound material is at ambient temperature when impinged with the pulsed laser light.

6 . The method of claim 1 wherein the rare earth element-containing compound material resides as a pressed powder body in the processing chamber having sub-atmospheric pressure during impingement with the pulsed laser light.

7 . The method of claim 1 wherein the pulsed laser light is scanned across the rare earth element-containing material.

8 . The method of claim 1 wherein the pulsed laser light is UV to IR light.

9 . A method of producing a rare earth metal, comprising impinging a mixture of different constituent rare earth element-containing materials in a sub-atmospheric processing chamber with a pulsed laser light whose wavelength is tuned in a manner to selectively reduce at least one of the constituent rare earth element-containing materials of the mixture to yield a selected rare earth metal.

10 . The method of claim 9 wherein the selected rare earth metal comprises at least one of La, Ce, Pr, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and/or Lu.

11 . The method of claim 9 wherein Ce metal is selectively produced.

12 . The method of claim 9 wherein Pr metal is selectively produced.

13 . The method of claim 9 wherein Nd metal is selectively produced.

14 . The method of claim 9 wherein a metal alloy comprising Pr and Nd is selectively produced.

15 . The method of claim 9 wherein La metal is selectively produced.

16 . The method of claim 9 wherein the rare earth element-containing materials of the mixture comprise a rare earth oxide, rare earth hydroxide, rare earth oxalate, rare earth halide and/or other rare earth salts.

17 . The method of claim 9 wherein the mixture of the rare earth element-containing materials resides as a pressed powder body in the processing chamber having the sub-atmospheric pressure during impingement with the pulsed laser light.

18 . The method of claim 9 wherein the pulsed laser light is scanned across the mixture of rare earth element-containing materials.

19 . The method of claim 9 wherein the pulsed laser light is UV to IR light.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2024
From: NLEBEDIM, CAJETAN IKENNA; SARKAR, ABHISHEK; SHROTRIYA, PRANAV; PRODIUS, DENIS; NOH, HO-WON; LOGRASSO, THOMAS
To: IOWA STATE UNIVERSITY RESEARCH FOUNDATION, INC.
Reel/Frame 068189/0673 →
CONFIRMATORY LICENSE Recorded Feb 23, 2023
From: IOWA STATE UNIVERSITY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 062837/0390 →
Continuity (2)
Provisional Application 63361516 · Dec 29, 2021
Related Publication 20230212709A1 · Jul 6, 2023
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