Polymer and organic light-emitting diode using same
The present specification relates to a polymer and an organic light emitting device using the same, wherein the polymer is represented by the following Chemical Formula 1: E1-[A] a —[B] b —[C] c -E2 [Chemical Formula 1] Wherein A, B, C, E1, E2, a, b and c are described herein.
1 . A polymer represented by Chemical Formula 1:
E1-[A] a —[B] b —[C] c -E2 [Chemical Formula 1]
in Chemical Formula 1,
A is represented by Chemical Formula 2-1,
B is represented by Chemical Formula 3,
C is a substituted or unsubstituted arylene group; a substituted or unsubstituted divalent heterocyclic group;
R37 to R39 are the same as or different from each other, and are each independently deuterium; a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; or a cross-linkable group,
k4 is an integer from 0 to 4, k5 is an integer from 0 to 3, when k4 and k5 are each 2 or higher, each occurrence of R37 to R39 is the same as or different from each other, respectively, and
* is a part that bonds to at least one of E1, A, B, C, or E2,
E1 and E2 are the same as or different from each other, and are each independently hydrogen; deuterium; a substituted or unsubstituted alkyl group; a substituted or unsubstituted silyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted arylamine group; a substituted or unsubstituted siloxane group; a cross-linkable group; or a combination thereof,
a, b, and c are each a mole fraction,
a is a real number of 0<a≤1,
b is a real number of 0<b<1,
c is a real number of 0≤c<1, and
a+b+c=1,
in Chemical Formula 2-1,
Ar2 and Ar3 are the same as or different from each other, and are each independently an aryl group unsubstituted or substituted with an alkyl group,
Ar1 and Ar4 are the same as or different from each other, and are each independently an arylene group,
R1 and R2 are each a F,
R3 is a hexyl group,
n3 is 2, and
* is a part that bonds to at least one of E1, A, B, C, or E2,
in Chemical Formula 3,
m is an integer of 3 or 4,
when m is 3, Z is CRa; SiRa; N; or a substituted or unsubstituted trivalent aryl group,
when m is 4, Z is C; Si; or a substituted or unsubstituted tetravalent aryl group,
Ra is hydrogen; a substituted or unsubstituted alkyl group; or a substituted or unsubstituted aryl group,
Y is a direct bond; a substituted or unsubstituted alkylene group; or a substituted or unsubstituted arylene group,
when Y is a direct bond; or a substituted or unsubstituted alkylene group, Z is a substituted or unsubstituted trivalent or tetravalent aryl group, and
* is a part that bonds to at least one of E1, A, B, C, or E2.
2 . The polymer of claim 1 , wherein E1 and E2 are the same as or different from each other, and are each independently a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a cross-linkable group; or a combination thereof.
3 . A polymer comprising a unit represented by Chemical Formula 2-1 and an end group represented by Chemical Formula 5:
in Chemical Formulae 2-1 and 5,
Ar2 and Ar3 are the same as or different from each other, and are each independently an aryl group unsubstituted or substituted with an alkyl group,
Ar1 and Ar4 are the same as or different from each other, and are each independently an arylene group,
R1 and R2 are each a F,
R3 is a hexyl group,
n3 is 2,
E is hydrogen; deuterium; a substituted or unsubstituted alkyl group; a substituted or unsubstituted silyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted arylamine group; a substituted or unsubstituted siloxane group; a cross-linkable group; or a combination thereof, and
* is an attachment point in the polymer.
4 . The polymer of claim 3 , further comprising a unit represented by Chemical Formula 3:
in Chemical Formula 3,
m is an integer of 3 or 4,
when m is 3, Z is CRa; SiRa; N; or a substituted or unsubstituted trivalent aryl group,
when m is 4, Z is C; Si; or a substituted or unsubstituted tetravalent aryl group,
Ra is hydrogen; a substituted or unsubstituted alkyl group; or a substituted or unsubstituted aryl group,
Y is a direct bond; a substituted or unsubstituted alkylene group; or a substituted or unsubstituted arylene group,
when Y is a direct bond; or a substituted or unsubstituted alkylene group, Z is a substituted or unsubstituted trivalent or tetravalent aryl group, and
* is an attachment point in the polymer.
5 . The polymer of claim 3 , further comprising a unit represented by Chemical Formula 4:
*—[C]—* [Chemical Formula 4]
in Chemical Formula 4,
C is a substituted or unsubstituted arylene group; a substituted or unsubstituted divalent heterocyclic group;
R37 to R39 are the same as or different from each other, and are each independently deuterium; a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; or a cross-linkable group,
k4 is an integer from 0 to 4, k5 is an integer from 0 to 3, when k4 and k5 are each 2 or higher, each occurrence of R37 to R39 is the same as or different from each other, respectively, and
* is an attachment point in the polymer.
6 . The polymer of claim 1 , wherein Chemical Formula 3 is represented by any one of Chemical Formulae 3-1 to 3-4:
in Chemical Formulae 3-1 to 3-4,
Z1 is CRa; SiRa; N; or a substituted or unsubstituted trivalent aryl group,
Z2 and Z3 are the same as or different from each other, and are each independently C; Si; or a substituted or unsubstituted tetravalent aryl group,
L1 is a direct bond; or a substituted or unsubstituted arylene group,
Ra is hydrogen; a substituted or unsubstituted alkyl group; or a substituted or unsubstituted aryl group,
R10 to R20 are the same as or different from each other, and are each independently hydrogen; deuterium; a halogen group; a cyano group; an alkoxy group; an aryloxy group; a fluoroalkoxy group; a siloxane group; a substituted or unsubstituted amine group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heterocyclic group; or a cross-linkable group, and adjacent groups may be bonded to each other to form a ring,
k1 is an integer from 1 to 4,
k2 is an integer from 1 to 5,
when k1 is 2 or higher, each occurrence of R10 to R19 is the same as or different from each other, respectively,
when k2 is 2 or higher, each occurrence of R20 is the same as or different from each other, and
* is a part that bonds to at least one of E1, A, B, C, or E2.
7 . The polymer of claim 1 , which has a weight average molecular weight of 70,000 g/mol to 2,000,000 g/mol.
8 . The polymer of claim 1 , wherein Chemical Formula 3 is represented by any one of the following structures:
* is a part that bonds to at least one of E1, A, B, C, or E2.
9 . The polymer of claim 1 , wherein the C is represented by any one of the following structures:
wherein:
Y1 is S, O, or NR100,
R30 to R33 and R36 to R39 are the same as or different from each other, and are each independently deuterium; a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; or a cross-linkable group,
k3 is an integer of 0 to 2,
k4 is an integer from 0 to 4,
k5 is an integer from 0 to 3,
k6 is an integer from 0 to 8,
when k3 to k6 are each 2 or higher, each occurrence of R30 to R33 and R36 to R39 is the same as or different from each other, respectively,
R34, R35 and R100 are the same as or different from each other, and are each independently hydrogen; deuterium; a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; or a cross-linkable group, and
* is a part that bonds to at least one of E1, A, B, C, or E2.
10 . The polymer of claim 1 , wherein E1 and E2 are each any one of the following structures:
* is a part that bonds to A, B or C, respectively.
11 . The polymer of claim 1 , wherein a is a real number from 0.4 to 1, b is a real number from 0 to 0.4, and c is a real number from 0 to 0.2.
12 . An organic light emitting device comprising:
a first electrode;
a second electrode provided to face the first electrode; and
an organic material layer having one or more layers, which includes a light emitting layer provided between the first electrode and the second electrode,
wherein one or more layers of the organic material layer comprise the polymer of claim 1 .
13 . The organic light emitting device of claim 12 , wherein the organic material layer comprising the polymer is a hole injection layer, a hole transport layer, or a layer which simultaneously injects and transports holes.
14 . The organic light emitting device of claim 12 , wherein the light emitting layer comprises an organic compound.
15 . The organic light emitting device of claim 12 , wherein the light emitting layer comprises a quantum dot.