Absorbent cores comprising a superabsorbent polymer immobilizing material
Described herein is an absorbent article having an absorbent core. The absorbent core includes a superabsorbent polymer material and an auxiliary adhesive. The auxiliary adhesive includes from about 20% to about 70% of a first polymer and from about 30% to about 80% of a second polymer. The auxiliary adhesive has a Shear Viscosity at 10 (1/s) at 230° C. of from about 300 mPa·s to about mPa·s.
1 . An absorbent article comprising:
an absorbent core comprising a superabsorbent polymer material and an auxiliary adhesive;
wherein the auxiliary adhesive comprises from about 20% to about 70% of a first polymer, by weight of the auxiliary adhesive;
wherein the auxiliary adhesive comprises from about 30% to about 80% of a second polymer, by weight of the auxiliary adhesive;
wherein the first polymer has a peak molecular weight of from about 65,000 g/mol to about 700,000 g/mol, according to the Peak Molecular Weight Test Method described herein;
wherein the first polymer is a random and/or block copolymer having ethylene derived units and/or C3-C10 alpha olefin derived units, or the first polymer is a polyolefinic homopolymer having ethylene derived units or propylene derived units or 1-butene derived units, or the first polymer is a styrenic block copolymer;
wherein the second polymer has a peak molecular weight of from about 1,000 g/mol to about 60,000 g/mol, according to the Peak Molecular Weight Test Method described herein;
wherein the second polymer is a polyolefin;
wherein the auxiliary adhesive has a Shear Viscosity at 10 (1/s) at 230° C. of from about 300 mPa·s to about 10,000 mPa·s, according to the Viscosity Rheometry Test Method described herein; and
wherein the auxiliary adhesive is substantially free of a tackifier.
2 . The absorbent article according to claim 1 , wherein the peak molecular weight of the second polymer is from about 15,000 g/mol to about 60,000 g/mol.
3 . The absorbent article according to claim 1 , wherein the absorbent core further comprises a superabsorbent polymer immobilizing material, wherein the superabsorbent polymer immobilizing material is a fiberized net structure.
4 . The absorbent article according to claim 1 , wherein the absorbent article further comprises a topsheet and a backsheet, with the absorbent core disposed therebetween.
5 . The absorbent article according to claim 1 , wherein the absorbent core comprises a first absorbent layer comprising a first substrate, wherein at least a portion of the auxiliary adhesive is deposited on the first substrate, and wherein the first substrate is a nonwoven core cover.
6 . The absorbent article according to claim 1 , wherein the auxiliary adhesive has a Wet Mobilization Value of less than 50%, according to the Wet Mobilization Test Method described herein.
7 . The absorbent article according to claim 1 , wherein the auxiliary adhesive has a Storage Modulus at 100° C. of from about 200 Pa to about 400,000 Pa, according to the Oscillatory Rheometry Test Method described herein.
8 . The absorbent article according to claim 1 , wherein the auxiliary adhesive has a Loss Factor at 100° C. of less than 5, according to the Oscillatory Rheometry Test Method described herein.
9 . The absorbent article according to claim 1 , wherein the auxiliary adhesive has a Strain Hardening Index of from about 25 to about 1,000, according to the Extensional Test Method described herein.
10 . The absorbent article according to claim 1 , wherein the peak molecular weight of the first polymer is from about 75,000 g/mol to about 500,000 g/mol when the first polymer is the random and/or block copolymer having ethylene derived units and/or C3-C10 alpha olefin derived units.
11 . The absorbent article according to claim 1 , wherein the peak molecular weight of the first polymer is from about 65,000 g/mol to about 150,000 g/mol when the first polymer is the styrenic block copolymer.
12 . An absorbent article comprising:
an absorbent core comprising a superabsorbent polymer material and an auxiliary adhesive;
wherein the auxiliary adhesive comprises from about 20% to about 70% of a first polymer, by weight of the auxiliary adhesive;
wherein the auxiliary adhesive comprises from about 30% to about 80% of a second polymer, by weight of the auxiliary adhesive;
wherein the auxiliary adhesive has a Wet Mobilization Value of less than 50%, according to the Wet Mobilization Test Method described herein;
wherein the auxiliary adhesive has a Storage Modulus at 100° C. of from about 200 Pa to about 400,000 Pa, according to the Oscillatory Rheometry Test Method described herein;
wherein the auxiliary adhesive has a Strain Hardening Index of from about 25 to about 1,000, according to the Extensional Test Method described herein; and
wherein the auxiliary adhesive has a Shear Viscosity at 10 (1/s) at 230° C. of from about 300 mPa·s to about 10,000 mPa·s, according to the Viscosity Rheometry Test Method described herein.
13 . The absorbent article according to claim 12 , wherein the auxiliary adhesive has a Strain at Break of from about 2.2 to about 8.5, according to the Extensional Test Method described herein.
14 . The absorbent article according to claim 12 , wherein the first polymer has a peak molecular weight of from about 65,000 g/mol to about 700,000 g/mol, according to the Peak Molecular Weight Test Method described herein, and wherein the first polymer is a random and/or block copolymer having ethylene derived units and/or C3-C10 alpha olefin derived units, or the first polymer is a polyolefinic homopolymer having ethylene derived units or propylene derived units or 1-butene derived units, or the first polymer is a styrenic block copolymer.
15 . The absorbent article according to claim 12 , wherein the second polymer has a peak molecular weight of from about 1,000 g/mol to about 60,000 g/mol, according to the Peak Molecular Weight Test Method described herein, and wherein the second polymer is a polyolefin.
16 . The absorbent article according to claim 12 , wherein the auxiliary adhesive is substantially free of a tackifier.
17 . An absorbent article comprising:
an absorbent core comprising a superabsorbent polymer material and an auxiliary adhesive;
wherein the auxiliary adhesive comprises from about 20% to about 70% of a first polymer, by weight of the auxiliary adhesive;
wherein the auxiliary adhesive comprises from about 30% to about 80% of a second polymer, by weight of the auxiliary adhesive;
wherein the first polymer has a peak molecular weight of from about 20,000 g/mol to about 700,000 g/mol, according to the Peak Molecular Weight Test Method described herein;
wherein the first polymer is a random and/or block copolymer having ethylene derived units and/or C3-C10 alpha olefin derived units, or the first polymer is a polyolefinic homopolymer having ethylene derived units or propylene derived units or 1-butene derived units, or the first polymer is a styrenic block copolymer;
wherein the second polymer has a peak molecular weight of from about 1,000 g/mol to about 90,000 g/mol, according to the Peak Molecular Weight Test Method described herein;
wherein the first polymer is different than the second polymer;
wherein the auxiliary adhesive has a Shear Viscosity at 10 (1/s) at 230° C. of from about 300 mPa·s to about 10,000 mPa·s, according to the Viscosity Rheometry Test Method described herein;
wherein the auxiliary adhesive has a Strain Hardening Index of from about 25 to about 1,000, according to the Extensional Test Method described herein; and
wherein the auxiliary adhesive is substantially free of a tackifier.
18 . The absorbent article according to claim 17 , wherein the Strain Hardening Index is from about 25 to about 175.
19 . The absorbent article according to claim 17 , wherein the second polymer is a polyolefin.
20 . The absorbent article according to claim 17 , wherein the absorbent core has channels, and wherein the channels are free of any absorbent material.