Granted Patent
B2
US 12,646,747 · App. 18/053,507 · Granted Jun 2, 2026
Electrolyte material and methods of forming
Assignee:
SAINT-GOBAIN CERAMICS & PLASTICS, INC.
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Abstract
A solid electrolyte material can include an ammonium-containing complex metal halide. In an embodiment, the ammonium-containing complex metal halide can be represented by (NH 4 ) n M 3−z (Me k+ ) f X n+3−z+k*f , wherein 0<n, 0≤z<3, 2≤k<6, 0≤f≤1; M comprises at least an alkali metal element, X comprises a halogen, and Me comprises a divalent metal element, a trivalent metal element, a tetravalent metal element, a pentavalent metal element, a hexavalent metal element or any combination thereof.
Claims (20)
1 . A solid electrolyte material, comprising a material including an ammonium-containing complex metal halide represented by (NH 4 ) n M 3−z (Me k+ ) f X n+3−z+k*f , wherein 0<n; −1≤z≤1; 2≤k≤6; 0≤f≤1; wherein when f=0, M comprises at least two metal elements; M comprises an alkali metal element; X comprises a halogen; and Me comprises a divalent metal element, a trivalent metal element, a tetravalent metal element, a pentavalent metal element, a hexavalent metal element or any combination thereof.
2 . The solid electrolyte material of claim 1 , wherein M comprises Li.
3 . The solid electrolyte material of claim 1 , wherein M comprises Na.
4 . The solid electrolyte material of claim 1 , wherein f>0, wherein Me comprises Y, Ce, Zr, Yb, Gd, In, Sc, or any combination thereof.
5 . The solid electrolyte material of claim 4 , wherein M comprises Li and Li makes up at least 50 mol % of M.
6 . A solid electrolyte material, comprising a material including an ammonium-containing complex metal halide represented by (NH 4 ) n (Li 1−d Na d ) 2 LiMe k+ X 3+k+n , wherein 0<n, 2≤k≤6, 0≤d<1; X comprises a halogen; and Me comprises a divalent metal element, a trivalent metal element, a tetravalent metal element, a pentavalent metal element, a hexavalent metal element or any combination thereof.
7 . The solid electrolyte material of claim 1 , wherein the ammonium-containing complex metal halide is represented by (NH 4 ) n Li 1−d Na d ) 2 LiMe k+ X 3+k+n , wherein 0≤d<1.
8 . The solid electrolyte material of claim 6 , wherein Me comprises a rare earth element, Zr, Hf, Ti, Sn, Sb, In, Bi, an alkaline earth metal element, or any combination thereof.
9 . The solid electrolyte material of claim 6 , wherein 0<d.
10 . A solid electrolyte layer, comprising the solid electrolyte material of claim 6 .
11 . A mixed electron and ion conductive layer, comprising the solid electrolyte material of claim 6 and an electron conductive material.
12 . The solid electrolyte material of claim 6 , wherein X comprises at least one of Cl and Br.
13 . A solid electrolyte material, comprising a material including an ammonium-containing complex metal halide represented by (NH 4 ) n M 3−z (Me k+ ) f X n+3−z+k*f , wherein 0<n, 0≤z<3, 2≤k≤6, 0<f≤1; M comprises Li, wherein Li makes up at least 50 mol % of M; X comprises a halogen; and Me comprises a divalent metal element, a trivalent metal element, a tetravalent metal element, a pentavalent metal element, a hexavalent metal element or any combination thereof, wherein ammonium is at most 50 mol % for a total of ammonium and M.
14 . The solid electrolyte material of claim 13 , wherein Li makes up at least 66 mol % of M.
15 . The solid electrolyte material of claim 13 , wherein Me comprises a rare earth element, an alkaline earth element, Zr, In, or any combination thereof.
16 . The solid electrolyte material of claim 15 , wherein Li makes up at least 66 mol % of M.
17 . The solid electrolyte material of claim 13 , wherein the ammonium-containing complex metal halide is represented by (NH 4 ) n Li 3−z (Me k+ ) f X 3−z+k*f+n , wherein f>0.
18 . The solid electrolyte material of claim 17 , wherein Me comprises Y, Ce, Zr, Yb, Gd, In, Sc, or any combination thereof.
19 . The solid electrolyte material of claim 13 , wherein the ammonium makes up at least 10 mol % of the total of ammonium and M.
20 . The solid electrolyte material of claim 13 , wherein X comprises at least one of Cl and Br.
Continuity (3)
Provisional Application
63009827
· Apr 14, 2020
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