Electrolytic capacitor
An electrolytic capacitor includes a porous anode body, a dielectric layer formed on a surface of the anode body, and a conductive polymer and a salt compound that are filled inside pores of the anode body. L is a shortest distance from a center of the anode body to a first principal surface of the anode body, the first principal surface being closest to the center, and a region in which a minimum value of respective distances to principal surfaces of the anode body is L/3 or less, and a region in which the minimum value is 2L/3 or more, are defined as a surface layer part and a central part, respectively, inside the anode body. A ratio B/A of an ion strength B derived from the salt compound to a sum A of all ion strengths measured by time-of-flight secondary ion mass spectrometry (TOF-SIMS) in a cross section that passes through the center and that is perpendicular to the first principal surface is defined as an ion strength ratio. A ratio R2/R1 of an ion strength ratio R2 in the central part of the anode body to an ion strength ratio R1 in the surface layer part of the anode body is 0.15 or more.
1 . An electrolytic capacitor comprising:
a porous anode body;
a dielectric layer formed on a surface of the anode body; and
a conductive polymer and a salt compound that are filled inside pores of the anode body, wherein
the salt compound is a salt of a cation and an anion,
when L is a shortest distance from a center of the anode body to a first principal surface of the anode body, the first principal surface being closest to the center,
a region in which a minimum value of respective distances to principal surfaces of the anode body is L/3 or less is defined as a surface layer part inside the anode body,
a region in which a minimum value of the respective distances to the principal surfaces of the anode body is 2L/3 or more is defined as a central part inside the anode body,
R1 (=B1/A1) is a ratio of an ion strength B1 derived from the salt compound to a sum A1 of all ion strengths measured by time-of-flight secondary ion mass spectrometry (TOF-SIMS) in a cross section of the surface layer part that passes through the center and perpendicular to the first principal surface, and
R2 (=B2/A2) is a ratio of an ion strength B2 derived from the salt compound to a sum A2 of all ion strengths measured by the time-of-flight secondary ion mass spectrometry in the cross section of the central part,
R2/R1 is 0.15 or more.
2 . The electrolytic capacitor according to claim 1 , wherein the R2/R1 is 0.4 or more.
3 . The electrolytic capacitor according to claim 1 , further comprising
an anode wire planted from the anode body, wherein
the first principal surface is a surface along a direction in which the anode wire extends inside the anode body.
4 . The electrolytic capacitor according to claim 3 , wherein the cross section is a surface along the direction in which the anode wire extends.
5 . The electrolytic capacitor according to claim 1 , wherein the salt compound is an ionic liquid.
6 . The electrolytic capacitor according to claim 5 , wherein the anion constituting the ionic liquid includes a hydrogen sulfate ion.
7 . The electrolytic capacitor according to claim 1 , wherein the salt compound is a hydrophilic ionic liquid.
8 . The electrolytic capacitor according to claim 1 , wherein the distance L is 0.1 mm or more.
9 . The electrolytic capacitor according to claim 1 , wherein the ion strength is an anion strength.
10 . The electrolytic capacitor according to claim 1 , wherein the ion strength is a cation strength.