Process for manufacturing nickel sulphate
A process for manufacturing nickel sulphate by leaching metal particles comprising nickel in an aqueous sulphuric acid solution, said process comprising the steps of: introducing the metal particles in the aqueous sulphuric acid solution introducing an aqueous hydrogen peroxide solution in the aqueous sulphuric acid solution containing the metal particles wherein the aqueous hydrogen peroxide solution is introduced progressively into the aqueous sulphuric acid solution containing the metal particles.
1 . A process for manufacturing nickel sulphate by leaching metal particles comprising nickel in an aqueous sulphuric acid solution, said process comprising the steps of:
introducing the metal particles in the aqueous sulphuric acid solution; and
introducing an aqueous hydrogen peroxide solution in the aqueous sulphuric acid solution containing the metal particles;
wherein the aqueous hydrogen peroxide solution is introduced progressively into the aqueous sulphuric acid solution containing the metal particles,
wherein the aqueous sulphuric acid solution has a concentration of 60 wt % or less, and
wherein the aqueous hydrogen peroxide solution is introduced by increments of less than 1% of a total amount of hydrogen peroxide to be added into the aqueous sulphuric acid solution containing the metal particles.
2 . The process according to claim 1 , wherein the aqueous sulphuric acid solution has a concentration between 20 wt % and 35 wt %.
3 . The process according to claim 1 , wherein the aqueous hydrogen peroxide solution has a concentration between 30 wt % and 60 wt %.
4 . The process according to claim 1 , wherein the molar ratio Ni:H 2 SO 4 :H 2 O 2 is between 1:1:1.3 and 1:1:1.1.
5 . The process according to claim 1 , wherein the molar ratio Ni:H 2 SO 4 :H 2 O 2 is 1:1.1:1.2.
6 . The process according to claim 1 , wherein the final NiSO 4 concentration of the aqueous sulphuric acid solution is between 80% and 90% of the molar concentration of NiSO4 at saturation at room temperature.
7 . The process according to claim 1 , wherein the process takes place in a vessel and wherein increments of less than 1% of the total amount of hydrogen peroxide to be added are introduced at the same time in different locations of the vessel.
8 . The process according to claim 1 , wherein the introduction of hydrogen peroxide into the sulphuric acid solution containing the metal particles starts within a few seconds or minutes after the metal particles are contacted with the sulphuric acid solution.
9 . The process according to claim 1 , wherein the hydrogen peroxide is introduced in a leaching vessel simultaneously with at least part of the sulphuric acid.
10 . The process according to claim 1 , wherein the hydrogen peroxide introduction starts before the explosive concentration of hydrogen is reached in the gas phase of/above a leaching vessel.
11 . The process according to claim 1 , wherein the pH of the aqueous sulphuric acid solution before the introduction of hydrogen peroxide is below 1 and wherein the pH of the aqueous sulphuric acid solution at the end of the introduction of the total amount of hydrogen peroxide is below 3.
12 . The process according to claim 1 , wherein the aqueous solution of sulphuric acid is stirred or otherwise agitated under mechanical conditions throughout the introduction of the aqueous hydrogen peroxide solution.
13 . The process according to claim 1 , wherein the metal particles are substantially dissolved at the end of the introduction of the aqueous hydrogen peroxide solution into the aqueous sulphuric acid solution.
14 . The process according to claim 1 , wherein the introduction of the aqueous hydrogen peroxide solution takes place at temperatures from 65 to 75° C.
15 . The process according to claim 1 , wherein the process takes place under a pressure of oxygen or air.
16 . The process according to claim 1 , wherein the aqueous hydrogen peroxide solution is introduced in the aqueous sulphuric acid solution as close as possible to the metal particles.
17 . The process according to claim 1 , wherein ultrasounds are used during the introduction of the aqueous hydrogen peroxide solution in the aqueous sulphuric acid solution.
18 . The process according to claim 1 , wherein after the introduction of the aqueous hydrogen peroxide solution in the aqueous sulphuric acid solution, the resulting NiSO4 solution is brought or kept at atmospheric pressure and cooled down to room temperature before being further processed to isolate the NiSO4 produced, or before being used as a feed material for the production of cathode material.
19 . The process according to claim 1 , wherein the aqueous sulphuric acid solution has a concentration of 50 wt % or less.
20 . The process according to claim 1 , wherein the aqueous sulphuric acid solution has a concentration of 35 wt % or less.
21 . A process for manufacturing nickel sulphate by leaching metal particles comprising nickel in an aqueous sulphuric acid solution, said process comprising the steps of:
introducing the metal particles in the aqueous sulphuric acid solution; and
introducing an aqueous hydrogen peroxide solution in the aqueous sulphuric acid solution containing the metal particles,
wherein the aqueous hydrogen peroxide solution is introduced in the aqueous sulphuric acid solution containing the metal particles in the absence of ultrasounds, and
wherein the aqueous hydrogen peroxide solution is introduced progressively into the aqueous sulphuric acid solution containing the metal particles and the aqueous sulphuric acid solution has a concentration of 50 wt % or less, and wherein the aqueous hydrogen peroxide solution is introduced by increments of less than 1% of a total amount of hydrogen peroxide to be added into the aqueous sulphuric acid solution containing the metal particles.