Use of molybdenum compounds in driveline lubricants for reduced friction and copper corrosion
A driveline lubricating composition for electric or hybrid-electric motor systems including a phosphorus antiwear additive and a multi-functional oil-soluble organolmolybdenum friction modifier to provide friction modification and low copper leaching.
1 . A method of lubricating a driveline of an electric or hybrid-electric vehicle, the method comprising:
lubricating the driveline of the electric or hybrid-electric vehicle with a lubricating composition; and
wherein the lubricating composition includes (i) one or more base oils of lubricating viscosity; (ii) a phosphorus antiwear additive providing about 100 ppm or less phosphorus to the driveline lubricating composition; (iii) a multi-functional oil-soluble organomolybdenum friction modifier and corrosion inhibitor having one or more ester and/or amide moieties and having about 1 to about 15 weight percent molybdenum; and wherein the driveline lubricating composition has less than about 300 ppm of total sulfur.
2 . The method of claim 1 , wherein the phosphorus antiwear additive includes an ashless dialkyl dithiophosphate antiwear additive providing about 100 ppm or less phosphorus and about 150 ppm or less sulfur to the driveline lubricating composition.
3 . The method of claim 2 , wherein the ashless dialkyl dithiophosphate is made by a process comprising the steps of reacting an organic hydroxy compound with phosphorus pentasulfide to form a reaction product and further reacting the reaction product with an unsaturated carboxylic acid to form the oil-soluble phosphorus antiwear additive including the ashless dialkyl dithiophosphate.
4 . The method of claim 3 , wherein the ashless dialkyl dithiophosphate includes a compound of Formula V, or a salt thereof:
wherein R 3 and R 4 are, independently, a C 3 to C 8 linear or branched alkyl group, and R 6 is —H or —CH 3 .
5 . The method of claim 1 , wherein the multi-functional oil-soluble organomolybdenum friction modifier and corrosion inhibitor provides about 20 to about 500 ppm molybdenum.
6 . The method of claim 1 , wherein the multi-functional oil-soluble organomolybdenum friction modifier and corrosion inhibitor having ester and/or amide ligands is substantially free of sulfur and/or phosphorus.
7 . The method of claim 2 , wherein the multi-functional oil-soluble organomolybdenum friction modifier and corrosion inhibitor having ester and/or amide ligands is substantially free of sulfur and/or phosphorus.
8 . The method of claim 7 , wherein the multi-functional oil-soluble organomolybdenum friction modifier and corrosion inhibitor having ester and/or amide ligands is derived from a fatty derivative of a dialkanolamine and a molybdenum source.
9 . The method of claim 8 , wherein the fatty derivative of the dialkanolamine is a fatty deriviative of diethanolamine and the molybdenum source is an oxygen-containing molybdenum compound.
10 . The method of claim 9 , wherein the oxygen-containing molybdenum compound is selected from an ammonium molybdate, a molybdenum oxide, or mixtures thereof.
11 . The method of claim 1 , wherein the multi-functional oil-soluble organomolybdenum friction modifier and corrosion inhibitor having one or more ester and/or amide moieties is the reaction product of about 1 mol of a fatty oil or fatty acid having 12 or more carbon atoms, about 1 to 2.5 mols of diethanolamine, and a source of molybdenum sufficient to yield about 1 to about 15 weight percent of molybdenum based on the weight of additive.
12 . The method of claim 1 , wherein a weight ratio of total sulfur and total phosphorus relative to total molybdenum (S+P)/Mo is about 0.7 to about 10.0.
13 . The method of claim 1 , wherein the driveline lubricating composition is substantially free of separate corrosion inhibitors and/or substantially free of separate friction modifiers.
14 . The method of claim 13 , wherein the separate corrosion inhibitors include monocarboxylic acid and/or polycarbocylic acid corrosion inhibitors, alkenyl succinic acid, acid/ester, or anhydride corrosion inhibitors, ether amine corrosion inhibitors, imidazoline corrosion inhibitors, benzotriazole corrosion inhibitors, or combinations thereof.
15 . The method of claim 1 , wherein the driveline lubricating composition has less than 120 ppm of copper leaching when evaluated pursuant to ASTM D130 at 150° C. after 168 hours.
16 . The method of claim 15 , wherein the driveline lubricating composition has a friction coefficient, when measured using a high frequency reciprocating rig (HFRR), of less than 0.160 and when evaluated using a 400 gram load, a 20 Hz frequency, and at a composition temperature of 130° C. for 3 minutes.