Automotive composition
A composition comprising (A) 40 to 80 wt.-% of a first heterophasic composition (HECO1); (B) 7 to 30 wt.-% of a second heterophasic composition (HECO2); (C) 0 to 12 wt.-% of an HDPE; (D) 2 to 12 wt.-% of a plastomer; and (E) 7 to 25 wt.-%, of talc; wherein HECO1 has a Tm of 150 to 159° C., an MFR 2 of 20.0 to 120 g/10 min, a CRYSTEX crystalline fraction of 79.0 to 91.0 wt.-%, a CRYSTEX soluble fraction of 9.0 to 21.0 wt.-%, and an ethylene content of 1.5 to 6.5 mol.-%; HECO2 has an MFR2 of 2.0 to 10.0 g/10 min, a CRYSTEX crystalline fraction of 70.0 to 82.0 wt.-%, a CRYSTEX soluble fraction of 18.0 to 30.0 wt.-% and an ethylene content of 9.0 to 20.0 mol.-%; the plastomer being a C2/C8 or a C2/C4 copolymer having a density of 850 to 900 kg/m 3 .
1 . A composition comprising:
(A) 40 to 80 wt.-%, based on the total composition, of a first heterophasic composition (HECO1);
(B) 7 to 30 wt.-%, based on the total composition, of a second heterophasic composition (HECO2);
(C) 0 to 12 wt.-%, based on the total composition, of a high density polyethylene (HDPE);
(D) 2 to 12 wt.-%, based on the total composition, of plastomer (P); and
(E) 7 to 25 wt.-%, based on the total composition, of talc (T);
wherein the first heterophasic composition (HECO1) comprising
(a) a propylene homopolymer as the matrix, and
(b) an ethylene-propylene rubber being dispersed in the matrix,
wherein the first heterophasic propylene copolymer (HECO1) has
(i) a melting temperature Tm, measured by DSC according to ISO 11357-3 with a heating and cooling rate of 10° C./min, in the range of 150 to 159° C.;
(ii) a melt flow rate MFR 2 (230° C., 2.16 kg), measured according to ISO 1133, in the range from 20.0 to 120 g/10 min;
(ii) a crystalline fraction (CF), determined according to ISO 6427 Annex B in trichlorobenzene at 160° C., present in an amount in the range from 79.0 to 91.0 wt.-%, relative to the total weight of the first heterophasic propylene copolymer (HECO1);
(iii) a soluble fraction (SF), determined according to ISO 6427 Annex B in trichlorobenzene at 160° C., present in an amount in the range from 9.0 to 21.0 wt.-%, relative to the total weight of the first heterophasic propylene copolymer (HECO1); and
(iv) a total ethylene content, measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, in the range of 1.5 to 6.5 mol.-%, wherein ethylene is the sole comonomer in the first heterophasic composition (HECO1);
wherein the second heterophasic composition (HECO2) comprising
(a) a propylene homopolymer as the matrix, and
(b) an ethylene-propylene rubber being dispersed in the matrix,
wherein the heterophasic propylene copolymer (HECO2) has
(i) a melt flow rate MFR 2 (230° C., 2.16 kg), measured according to ISO 1133, in the range from 2.0 to 10.0 g/10 min;
(ii) a crystalline fraction (CF), determined according to ISO 6427 Annex B according to ISO 6427 Annex B, present in an amount in the range from 70.0 to 82.0 wt.-%, relative to the total weight of the heterophasic propylene copolymer (HECO2);
(iii) a soluble fraction (SF), determined according to ISO 6427 Annex B, according to ISO 6427 Annex B present in an amount in the range from 18.0 to 30.0 wt.-%, relative to the total weight of the heterophasic propylene copolymer (HECO2); and
(iv) a total ethylene content, measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, in the range of 9.0 to 20.0 mol.-%, wherein ethylene is the sole comonomer in the second heterophasic composition (HECO2);
the plastomer being an ethylene 1-octene copolymer or an ethylene 1-butene copolymer having a density measured according to ISO 1183-1 in the range of 850 to 900 kg/m 3 .
2 . The composition according to claim 1 , wherein the propylene homopolymer of the first heterophasic propylene copolymer (HECO1) has 2,1 regio defects, determined by 13 C-NMR, in the range of 0.05 to 0.90%.
3 . The composition according to claim 1 , wherein the first heterophasic propylene copolymer (HECO1) has a melting temperature Tm, measured by DSC according to ISO 11357-3 (heating and cooling rate 10° C./min), in the range of 153 to 158° C.
4 . The composition according to claim 1 , wherein the ethylene content of the soluble fraction (C2(SF)) of the first heterophasic composition (HECO1), measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, is in the range from 22.0 to 39.0 mol-%.
5 . The composition according to claim 1 , wherein the first heterophasic composition (HECO1) has
(i) an intrinsic viscosity of the soluble fraction (IV(SF)), measured according to ISO 1628-1 at 135° C. in decalin, in the range from 1.80 to 3.20 dl/g;
(ii) an intrinsic viscosity of the crystalline fraction (IV(CF)), measured according to ISO 1628-1 at 135° C. in decalin, in the range from 0.80 to 1.80 dl/g; and
(iii) a ratio between the intrinsic viscosity of the soluble fraction (SF) and the intrinsic viscosity of the crystalline fraction (CF) [IV(SF)/IV(CF)] in the range from 1.50 to 2.80.
6 . The composition according to claim 1 , wherein
(i) the ethylene content of the soluble fraction (C2(SF)) of the second heterophasic composition (HECO2), measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, is in the range from 25.0 to 39.0 mol-%; and
(ii) the ethylene content of the crystalline fraction (C2(CF)) of the second heterophasic composition (HECO2), measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, is in the range from 1.5 to 5.0 mol-%.
7 . The composition according to claim 1 , wherein the intrinsic viscosity of the soluble fraction (IV(SF)) of the second heterophasic composition (HECO2), measured according to ISO 1628-1 at 135° C. in decalin, is in the range from 5.00 to 9.00 dl/g.
8 . The composition according to claim 1 , wherein the second heterophasic composition (HECO2) has
(i) an intrinsic viscosity of the crystalline fraction (IV(CF)), measured according to ISO 1628-1 at 135° C. in decalin, in the range from 1.70 to 2.50 dl/g; and
(ii) a ratio between the intrinsic viscosity of the soluble fraction (SF) and the intrinsic viscosity of the crystalline fraction (CF) (IV(SF)/IV(CF)) in the range from 3.00 to 3.80.
9 . The composition according to claim 1 , wherein the second heterophasic composition (HECO2) has a melting temperature Tm, measured by DSC according to ISO 11357-3 with a heating and cooling rate of 10° C./min, in the range of 162 to 170° C.
10 . The composition according to claim 1 , wherein
(i) the weight ratio between the first heterophasic composition (HECO1) and the second heterophasic composition (HECO2) [(HECO1)/(HECO2)] is in the range of 1.9 to 5.5; and
(ii) the ratio between the intrinsic viscosity of the soluble fraction (IV(SF)) of the first heterophasic composition (HECO1) and the intrinsic viscosity of the soluble fraction (IV(SF)) of the second heterophasic composition (HECO2) is in the range of 0.22 to 0.40.
11 . The composition according to claim 1 , wherein the plastomer is an ethylene 1-octene copolymer having
(a) a melt flow rate MFR 2 (190° C., 2.16 kg), measured according to ISO 1133, in the range from 2.0 to 10.0 g/10 min; and
(b) a density, measured according to ISO 1183-1, in the range of 860 to 890 kg/m 2 .
12 . The composition according to claim 1 , wherein the composition comprises 2 to 12 wt.-%, based on the total composition, of the high density polyethylene (HDPE) and wherein the high density polyethylene (HDPE) has
(a) a density, measured according to ISO 1183-1, in the range of 940 to 970 kg/m 3 ; and
(b) a melt flow rate MFR 2 (190° C., 2.16 kg), measured according to ISO 1133, in the range of 2.0 to 20.0 g/10 min.
13 . The composition according to claim 1 consisting of
(A) 40 to 80 wt.-%, based on the total composition, of the first heterophasic composition (HECO1);
(B) 7 to 30 wt.-%, based on the total composition, of the second heterophasic composition (HECO2);
(C) 2 to 12 wt.-%, based on the total composition, of the high density polyethylene (HDPE);
(D) 2 to 12 wt.-%, based on the total composition, of the plastomer (P);
(E) 7 to 25 wt.-%, based on the total composition, of the talc (T); and
(F) 1 to 5 wt.-%, based on the total composition, of the additives (A).
14 . The composition according to claim 1 , wherein the talc (T) has a median particle size d 50 measured according to ISO 13317-3 in the range of 0.5 to 2.5 μm and a top cut particle size d 95 measured according to ISO 13317-3 in the range 1.0 to 8.0 μm.
15 . The composition according to claim 1 having a melt flow rate MFR 2 (230° C., 2.16 kg), measured according to ISO 1133, in the range from 10.0 to 30.0 g/10 min.
16 . The composition according to claim 1 , wherein the first heterophasic composition (HECO1), the second heterophasic composition (HECO2), the high density polyethylene (HDPE), the plastomer (P) and the talc (T) make up together at least 90 wt.-% of the total composition.
17 . An automotive article comprising at least 95 wt.-% of the composition according to claim 1 .
18 . A heterophasic propylene copolymer (HECO1) comprising
(a) a propylene homopolymer as the matrix, wherein the propylene homopolymer has 2,1 regio defects, determined by 13 C-NMR, in the range of 0.05 to 0.90%, and
(b) an ethylene-propylene rubber being dispersed in said matrix,
wherein the heterophasic propylene copolymer (HECO1) has
(i) a melting temperature Tm, measured by DSC according to ISO 11357-3 with a heating and cooling rate of 10° C./min, in the range of 153 to 158° C.;
(ii) a melt flow rate MFR 2 (230° C., 2.16 kg), measured according to ISO 1133, in the range from 20.0 to 120 g/10 min;
(iii) a crystalline fraction (CF), determined according to ISO 6427 Annex B in trichlorobenzene at 160° C., present in an amount in the range from 79.0 to 91.0 wt.-%, relative to the total weight of the heterophasic propylene copolymer;
(iv) a soluble fraction (SF), determined according to ISO 6427 Annex B in trichlorobenzene at 160° C., present in an amount in the range from 9.0 to 21.0 wt.-%, relative to the total weight of the heterophasic propylene copolymer;
(v) a total ethylene content, measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, in the range of 1.5 to 6.5 mol.-%, wherein ethylene is the sole comonomer in the heterophasic composition (HECO1);
(vi) an ethylene content of the soluble fraction (C2(SF)), measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, in the range from 22.0 to 39.0 mol-%;
(vii) an intrinsic viscosity of the soluble fraction (IV(SF)), measured according to ISO 1628-1 at 135° C. in decalin, in the range from 2.00 to 3.00 dl/g;
(viii) an intrinsic viscosity of the crystalline fraction (IV(CF)), measured according to ISO 1628-1 at 135° C. in decalin, in the range from 1.00 to 1.60 dl/g; and
(ix) a ratio between the intrinsic viscosity of the soluble fraction and the intrinsic viscosity of the crystalline fraction (IV(SF)/IV(CF)) in the range from 1.60 to 2.70.
19 . The composition according to claim 4 , wherein the ethylene content of the crystalline fraction (C2(CF)) of the first heterophasic composition (HECO1), measured by Fourier Transform Infrared Spectroscopy (FTIR) during analysis according to ISO 6427 Annex B, is in the range from 0.0 to 0.7 mol-%.
20 . The composition according to claim 9 , wherein no 2,1 regio defects are detected by 13 C-NMR for the propylene homopolymer of the second heterophasic composition (HECO2).