IP Library › Granted Patent US 12,678,759
Granted Patent B2
US 12,678,759 · App. 17/769,388 · Granted Jul 14, 2026

Process and system for producing pulp, energy, and bioderivatives from plant-based and recycled materials

Inventors: Sandeep Kumar (Virginia Beach, VA); Peter Majeranowski (Danville, VA); Igor Kostenyuk (Winter Haven, FL); Iulian Bobe (Danville, VA); Florin Barla (Danville, VA)
Assignee: Circ, LLC
B01J19/0053B01D11/0207C10G1/04C10G1/065C12M21/12C12M43/02C12P7/10C12P7/649D21B1/14D21C1/02D21C3/02D21C3/22D21C5/02D21C7/00D21C11/0007D21H11/02B01J2219/00051B01J2219/00162B01J2219/00353B01J2219/00891C10G2300/1014Y02E50/10Y02P30/20Y02W30/64
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,678,759
App. No.
17/769,388
Filed
Apr 15, 2022
Granted
Jul 14, 2026
Kind
B2
Art Unit
1774
USPC
422/630
Abstract

The presently disclosed subject matter relates to an industrial system for processing various plant materials to produce marketable materials. Particularly, the system integrates subcritical water extraction technology and includes a pre-processing module and a two-stage extractor (processing module) with constant control of temperature, pressure, and/or residence time. In some embodiments, the final product of the disclosed system can include feedstock constituents for biofuel production (sugars and/or oil), biochar, raw materials for various industries (such as pulp for manufacturing paper or cellulose for use in various industries). The disclosed system can be modular or non-modular, stationary or mobile, and can include prefabricated elements with programmed automatic or manual operation so that it can be easily moved and/or assembled on site.

Claims (19)

1 . A system comprising:

a pre-processing portion having a mechanical processor/material handler for extraction of water soluble fermentable carbohydrates and preparation of material for further extraction;

an extractor portion comprising a reactor or a reactor assembly to which biomass and subcritical water is supplied, the reactor or the reactor assembly having a first operating condition at a first pressure and a first temperature at a constant level that is held for a first defined period of time to break down carbohydrates of a first chain strength and a second operating condition at a second pressure and a second temperature at a constant level that is held for a defined second period of time to break down remaining oligo-carbohydrates of a second chain strength and fatty acids,

wherein the system is repeatable until the recovery rate of the fermentable carbohydrates, fatty acid, or both reaches a desired yield, and

wherein the mechanical processor/material handler of the pre-processing portion comprises a mechanical press for primary extraction of soluble carbohydrates, a wet or dry mill operably coupled to a material feeding mechanism, or both.

2 . The system according to claim 1 , wherein the mechanical processor/material handler of the pre-processing portion further comprises a storage tank for mixing with water or other liquid.

3 . The system according to claim 1 , further comprising a variable speed and flow rate pump that pumps the mixed biomass and liquid downstream.

4 . The system according to claim 1 , further including:

a high pressure pump for increasing a pressure in the system, wherein a variable speed and flow rate are provided; a pressure control valve for maintaining pressure in the first operating condition;

a pump for increasing the pressure of biomass in the flow channel to the second temperature and second pressure; and

a pressure control valve for maintaining pressure in the second pressure and second temperature section.

5 . The system according to claim 1 , wherein first operating condition comprises a pressure of about 0-300 psi and temperature of up to about 180° C. and the second operating condition comprises a pressure of about 301-3000 psi and a temperature of about 180° C. to 350° C.

6 . The system according to claim 1 , wherein the pre-processing and first and second operating conditions are controlled and monitored by a centralized computer software able to maintain constant a desired pressure, temperature, and flow rate for a desired period of time;

wherein the system comprises multiple sensors that are installed and connected to centralized computer managing software comprising a network in which technical information about major parameters such as pressure, temperature, flow, content level, is collected in real time, relayed to a managing system, and analyzed;

wherein the above parameters are controlled and modified in real time.

7 . The system according to claim 1 , wherein the reactor assembly comprises an assembly of one or more reactors followed by one or more pressure control valves, heat exchangers for cooling down the outputs from the reactor, and separators to collect valuable materials from the water phase and consequently recycle the water.

8 . The system according to claim 1 , wherein the system is configured to produce as its final product feedstock constituents such as fermentable carbohydrates, fatty acids, and other compounds for biofuel production, biochar, pulp, cellulose, or raw materials for various industries, or combinations thereof from plant based materials or putrescible waste.

9 . The system according to claim 1 , wherein the system is modular and scalable, stationary or mobile;

wherein when in mobile form, the system can be mounted on one or more truck trailers, rail cars, shipping containers, other platforms used to transport from one site to another, or combinations thereof.

Assignments (4)
CHANGE OF NAME Recorded Nov 3, 2022
From: CIRC, LLC
To: CIRC, INC.
Reel/Frame 061877/0759 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2022
From: BOBE, IULIAN; BARLA, FLORIN; MAJERANOWSKI, PETER
To: TYTON BIOSCIENCES, LLC
Reel/Frame 059609/0019 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2022
From: BOBE, IULIAN; KUMAR, SANDEEP; KOSTENYUK, IGOR; BARLA, FLORIN; MAJERANOWSKI, PETER
To: TYTON BIOSCIENCES, LLC
Reel/Frame 059609/0733 →
CHANGE OF NAME Recorded Apr 15, 2022
From: TYTON BIOSCIENCES, LLC
To: CIRC, LLC
Reel/Frame 059722/0306 →
Continuity (8)
Continuation 16802651 · Feb 27, 2020
Continuation 16402784 · May 3, 2019
Continuation 15822414 · Nov 27, 2017
Continuation PCTUS2016037188 · Jun 13, 2016
Provisional Application 62332883 · May 6, 2016
Provisional Application 62174478 · Jun 11, 2015
Related Publication 20240131489A1 · Apr 25, 2024
Related Publication 20240226841A9 · Jul 11, 2024
References Cited (83)
US 4542239A · Lamparter et al. · 1985 [cited by applicant]
US 4769274A · Tellvik et al. · 1988 [cited by applicant]
US 5133835A · Goettmann et al. · 1992 [cited by applicant]
US 5411594A · Brelsford · 1995 [cited by applicant]
US 5580905A · Schwartz, Jr. · 1996 [cited by applicant]
US 6468390B1 · Shekkenes et al. · 2002 [cited by applicant]
US 6706843B1 · Ishihara et al. · 2004 [cited by applicant]
US 7521493B2 · Frances et al. · 2009 [cited by applicant]
US 8546560B2 · Kilambi · 2013 [cited by applicant]
US 8546561B2 · Kilambi · 2013 [cited by examiner]
US 8637718B2 · Gupta et al. · 2014 [cited by applicant]
US 8679352B2 · Ollivier et al. · 2014 [cited by applicant]
US 9359651B2 · Kilambi et al. · 2016 [cited by applicant]
US 9469693B2 · Henriksson et al. · 2016 [cited by applicant]
US 9611371B2 · Walker · 2017 [cited by applicant]
US 9751955B2 · Lindstrom et al. · 2017 [cited by applicant]
US 9902815B2 · Tamminen et al. · 2018 [cited by applicant]
US 10266610B2 · Varhimo et al. · 2019 [cited by applicant]
US 10300464B2 · Lin et al. · 2019 [cited by applicant]
US 10322395B2 · Kumar et al. · 2019 [cited by applicant]
US 10603651B2 · Kumar et al. · 2020 [cited by applicant]
US 11305254B2 · Kumar · 2022 [cited by examiner]
US 20090318579A1 · Ikenaga et al. · 2009 [cited by applicant]
US 20110209723A1 · Sullivan et al. · 2011 [cited by applicant]
US 20120161358A1 · Al-Munif et al. · 2012 [cited by applicant]
US 20130192123A1 · Maschmerer et al. · 2013 [cited by applicant]
US 20140234936A1 · Kusuda et al. · 2014 [cited by applicant]
US 20140275299A1 · Badwell et al. · 2014 [cited by applicant]
US 20140331993A1 · Kumar et al. · 2014 [cited by applicant]
US 20140345341A1 · Fiato et al. · 2014 [cited by applicant]
US 20150105532A1 · Allen et al. · 2015 [cited by applicant]
US 20150225901A1 · Asikainen et al. · 2015 [cited by applicant]
US 20160168315A1 · Hernandez et al. · 2016 [cited by applicant]
US 20170008826A1 · Mishra et al. · 2017 [cited by applicant]
US 20170218162A1 · Walker · 2017 [cited by applicant]
US 20170362775A1 · Juvonen et al. · 2017 [cited by applicant]
US 20180127515A1 · Ropponen et al. · 2018 [cited by applicant]
US 20190226015A1 · Provins et al. · 2019 [cited by applicant]
US 20200247961A1 · Ferris et al. · 2020 [cited by applicant]
US 20200338531A1 · Boualleg et al. · 2020 [cited by applicant]
US 20200407530A1 · Barla et al. · 2020 [cited by applicant]
US 20210017353A1 · Sramek et al. · 2021 [cited by applicant]
US 20210237317A1 · Dubois · 2021 [cited by applicant]
US 20210238380A1 · Monsigny et al. · 2021 [cited by applicant]
EP 1383955 · 2010 [cited by applicant]
EP 1454009 · 2010 [cited by applicant]
EP 2425024 · 2013 [cited by applicant]
EP 2247623 · 2014 [cited by applicant]
EP 2452014 · 2016 [cited by applicant]
EP 2817448 · 2016 [cited by applicant]
EP 2678474 · 2017 [cited by applicant]
EP 2632957 · 2018 [cited by applicant]
EP 2895653 · 2019 [cited by applicant]
GB 2528495 · 2016 [cited by applicant]
GB 2560726 · 2018 [cited by applicant]
JP 2007226255A · 2007 [cited by applicant]
JP 2009106244A · 2009 [cited by applicant]
JP 2009261275 · 2009 [cited by applicant]
JP 2011032388 · 2011 [cited by applicant]
JP 6346399 · 2018 [cited by applicant]
KR 101391686 · 2014 [cited by applicant]
WO WO0202871 · 2002 [cited by applicant]
WO WO2009008822 · 2009 [cited by applicant]
WO WO2013124265 · 2013 [cited by applicant]
WO WO2016012755 · 2016 [cited by applicant]
WO WO2016193542 · 2016 [cited by applicant]
WO WO2018073177 · 2018 [cited by applicant]
WO WO2018104330 · 2018 [cited by applicant]
WO WO2018146386 · 2018 [cited by applicant]
WO WO2018197756 · 2018 [cited by applicant]
CNIPA, Second Office Action for corresponding Chinese Patent Application No. 201680033630.6, dated Jul. 17, 2020. [cited by applicant]
CNIPA; Office Action for Chinese Patent Application No. 201680033630.6 dated Sep. 27, 2019, 16 pages. [cited by applicant]
EPO; Extended European Search Report for European Patent Application No. 16808506.6 dated Mar. 20, 2019, 11 pages. [cited by applicant]
ISA/KR; Search Report and Written Opinion for International Patent Application No. PCT/US2016/037188 dated Sep. 12, 2016, 13 pages. [cited by applicant]
JPO, Office Action for corresponding Japanese Patent Application No. 2017-564526, Jul. 28, 2020. [cited by applicant]
Toor, S., et al., “Hydrothermal liquefaction of biomass: A review of subcritical water technologies”, Elsevier, Energy, vol. 36, 2011, pp. 2328-2342. [cited by applicant]
USPTO; Non-Final Office Action for U.S. Appl. No. 15/822,414 dated Aug. 10, 2018, 11 pages. [cited by applicant]
USPTO; Non-Final Office Action for U.S. Appl. No. 16/402,784 dated Jul. 29, 2019, 8 pages. [cited by applicant]
WIPO; International Preliminary Report for Patentability for International Patent Application No. PCT/US2016!037188 ated Dec. 12, 2017, 11 pages. [cited by applicant]
WIPO; International Preliminary Report on Patentability for International Patent Application No. PCT/SE2008/050837 ated Aug. 26, 2009, 13 pages. [cited by applicant]
Hoshio et al. “Extraction of Bamboo Fiber and Biomass Utilization by Hydrothermal Treatment”, dated Dec. 2010, 6 pages. [cited by applicant]
Lee et al., Crystals and Crystal Growth. Handbook of Industrial Crystallization, Jun. 14, 2019, Chap. 2. [cited by applicant]
Shukla et al., “Depolymerization of Poly(ethylene terephthalate) Waste”, J. Appl. Polym. Sci .; vol. 85, pp. 1765-1770, Aug. 2002. [cited by applicant]