IP Library Granted Patent US 7,074,713
Granted Patent B2
US 7,074,713 · App. 10/954,400 · Granted Jul 11, 2006

Plasma enhanced nitride layer

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,074,713
App. No.
10/954,400
Granted
Jul 11, 2006
Kind
B2
Abstract

An etch stop layer located over a plasma enhanced nitride (PEN) layer. Interlayer dielectric material is then formed over the etched stop layer. The etch stop layer is used as an etch stop for etching openings in the interlayer dielectric. In some embodiments, integrated circuits built with the PEN layer may include transistors with improved drive current at a given leakage current. Also, integrated circuits with the PEN layer may exhibit reduced parasitic capacitance.

Claims (59)

1. A method for making a semiconductor device, the method comprising:

forming a plasma enhanced nitride (PEN) layer over a wafer;

forming an etch stop layer over the wafer wherein the forming an etch stop layer includes forming a second layer over the PEN layer, the second layer being of a different material than the PEN layer;

forming a layer of interlayer dielectric material over the second layer;

selectively etching through the interlayer dielectric material utilizing the etch stop layer as an etch stop;

selectively etching through the etch stop layer and the PEN layer with an etchant that is non selective with respect to both the PEN layer and the etch stop layer.

2. The method of claim 1 wherein the etchant is selective with respect to the interlayer dielectric material.

3. The method of claim 1 wherein the PEN layer includes silicon.

4. The method of claim 1 wherein the PEN layer includes hydrogen.

5. The method of claim 1 wherein the PEN layer includes at least 20% hydrogen by weight.

6. The method of claim 1 wherein the PEN layer includes multiple layers of the same material.

7. The method of claim 1 wherein the forming the PEN layer includes:

forming a first layer of the PEN layer at a first deposition station of a processing chamber;

forming a second layer of the PEN layer over the first layer of the PEN layer at a second deposition station of the processing chamber.

8. The method of claim 7 wherein the forming the PEN layer includes:

forming a third layer of the PEN layer over the second layer of the PEN layer at a third deposition station of a processing chamber.

9. The method of claim 1 wherein the second layer has a higher selectivity than the PEN layer with respect to an etch chemistry of an enchant used in the selectively etching through the interlayer dielectric material.

10. The method of claim 1 further comprising:

forming a transistor on the wafer;

wherein the etch stop layer is formed over the transistor;

wherein the selectively etching through the interlayer dielectric material includes forming an opening in the layer of interlayer dielectric material for a contact for a source/drain region of the transistor.

11. The method of claim 1 wherein:

the wafer has a semiconductor on insulator (SOI) configuration and includes a semiconductor substrate and a dielectric layer overlying the semiconductor substrate;

the layer of interlayer dielectric material is formed over the dielectric layer;

the selectively etching through the interlayer dielectric material includes etching an opening through the layer of interlayer dielectric material and through the dielectric layer for a contact for the semiconductor substrate.

12. The method of claim 1 wherein the layer of interlayer dielectric material includes TEOS.

13. The method of claim 1 wherein the second layer includes nitrogen.

14. The method of claim 13 wherein the second layer includes hydrogen.

15. The method of claim 1 further comprising:

forming an interconnect over the layer of interlayer dielectric material after the selectively etching through the etch stop layer and the PEN layer.

16. The method of claim 1 wherein the PEN layer enhances a drive current of a transistor of the wafer at a given leakage current.

17. The method of claim 1 further comprising:

planarizing the layer of interlayer dielectric material prior to the selectively etching through the interlayer dielectric material.

18. The method of claim 1 wherein the PEN layer has at least a relatively high ratio of Si—H bonds to N—H bonds.

19. The method of claim 1 wherein the second layer includes silicon rich oxynitride.

20. The method of claim 1 wherein the PEN layer has a thickness of less than 500 A or less.

21. The method of claim 1 wherein the PEN layer is approximately 36% silicon, 53% nitrogen, and 21% hydrogen by atomic weight.

22. A method for making a semiconductor device, the method comprising:

forming a plasma enhanced nitride (PEN) layer over a wafer;

forming an etch stop layer over the wafer wherein the forming the etch stop layer includes forming a second layer including nitride on the PEN layer, the second layer being of a different material than the PEN layer,

forming a layer of interlayer dielectric material over the second layer;

selectively etching though the interlayer dielectric material utilizing the etch stop layer as an etch stop; and

selectively etching through the etch stop layer and the PEN layer after the selectively etching through the interlayer dielectric material.

23. A method for making a semiconductor device, the method comprising:

forming a plasma enhanced nitride (PEN) layer over a wafer;

forming an etch stop layer over the wafer wherein the forming an etch stop layer includes forming a second layer on the PEN layer, the second layer being of a different material than the PEN layer;

forming a layer of interlayer dielectric material over the second layer;

selectively etching though the interlayer dielectric material utilizing the etch stop layer as an etch stop;

wherein the second layer has a higher selectivity than the PEN layer with respect to an etch chemistry of an enchant used in the selectively etching.

24. A method for making a semiconductor device, the method comprising:

forming multiple plasma enhanced nitride (PEN) layers of the same material on top of each other over a wafer;

forming an etch stop layer over the wafer wherein the forming an etch stop layer includes forming a second layer over the multiple PEN layers, the second layer being of a different material than the multiple PEN layers;

forming a layer of interlayer dielectric material over the second layer;

selectively etching though the interlayer dielectric material utilizing the etch stop layer as an etch stop.

25. The method of claim 24 wherein the forming the multiple PEN layer includes:

forming a first layer of the multiple PEN layers at a first deposition station of a processing chamber;

forming a second layer of the multiple PEN layers over the first layer of the multiple PEN layers at a second deposition station of the processing chamber.

26. The method of claim 25 wherein the forming the multiple PEN layers includes:

forming a third layer of the multiple PEN layers over the second layer of the multiple PEN layers at a third deposition station of a processing chamber.

Assignments (17)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE LISTED CHANGE OF NAME SHOULD BE MERGER AND CHANGE PREVIOUSLY RECORDED AT REEL: 040652 FRAME: 0180. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Jan 12, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 041354/0148 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →