High-strength, chemically resistant laminar film with limited extractables
View Patent ↗A chemically resistant, extractable free, composite laminar film including polyimide, PFA and m-PTFE layers.
1. A chemically resistant reduced extractable laminar film comprising:
a polyimide film layer heat bonded to a first adhesive film layer consisting of PFA, said first adhesive film layer heat bonded to a first m-PTFE film layer having reduced crystallinity and an improved cycle bending fatigue resistance compared to standard PTFE, the polyimide layer, first adhesive film layer, and m-PTFE layer heated in said heat bonding to form a single composite material, the m-PTFE layer configured to be exposed to a fluid, said laminar film does not produce any contamination as metal or particles from film fibrillation after several thousand cycles of bending, wherein the first adhesive film layer bonds the first m-PTFE film layer to the polyimide film layer.
2. The laminar film of claim 1 , further comprising an additional adhesive film layer heat bonded to a side of the polyimide film layer opposite the first adhesive film layer, said additional adhesive film layer heat bonded to an additional layer of m-PTFE, said additional adhesive film layer consisting of PFA and bonds the additional layer of m-PTFE film to the polyimide film layer.
3. The laminar film of claim 1 , wherein said m-PTFE layer contains perfluoro alkyl residue on the main polymer chain.
4. A method for producing a chemically resistant reduced extractable laminar film, the method comprising:
arranging a multi-layered sandwich of material in the following order:
an m-PTFE film layer having reduced crystallinity, an adhesive film layer consisting of PFA, and a polyimide film layer; and
heat bonding, the polyimide film layer, the adhesive film layer, and the m-PTFE film layer wherein said heat bonding forms a single composite material, and wherein the m-PTFE has reduced crystallinity and an improved cycle bending fatigue resistance compared to standard PTFE.
5. The method of claim 4 wherein said laminar film does not produce any contamination as metal or particles from film fibrillation after several thousand cycles of bending.
6. A chemically resistant reduced extractable laminar film consisting of:
a polyimide film layer heat bonded to a first adhesive film layer consisting of PFA, said first adhesive film layer heat bonded to a first m-PTFE film layer having reduced crystallinity and an improved cycle bending fatigue resistance compared to standard PTFE, the polyimide layer, first adhesive film layer, and m-PTFE layer heated in said heat bonding to form a single composite material, the m-PTFE layer configured to be exposed to a fluid.
7. A chemically resistant reduced extractable laminar film consisting of:
a polyimide film layer heat bonded to a first adhesive film layer consisting of PFA, said first adhesive film layer of PFA heat bonded to a first m-PTFE film layer having reduced crystallinity and an improved cycle bending fatigue resistance compared to standard PTFE, an additional adhesive film layer consisting of PFA heat bonded to a side of the polyimide film layer opposite the first adhesive film layer of PFA, said additional adhesive film layer of PFA heat bonded to an additional layer of m-PTFE having reduced crystallinity and an improved cycle bending fatigue resistance compared to standard PTFE, said additional adhesive film layer of PFA bonds the additional layer of m-PTFE film to the polyimide film layer; the polyimide layer, the first adhesive film layer of PFA, the additional adhesive layer of PFA, the additional layer of m-PTFE, and the m-PTFE layer heated in said heat bonding form a single composite material.
8. A method for producing a chemically resistant reduced extractable laminar film, the method consisting of:
arranging a multi-layered sandwich of material in the following order:
a first m-PTFE film layer having reduced crystallinity and improved cycle bending fatigue resistance compared to standard PTFE, an adhesive film layer consisting of PFA, a polyimide film layer, an additional adhesive film layer consisting of PFA, and an additional layer of m-PTFE having reduced crystallinity and improved cycle bending fatigue resistance compared to standard PTFE; and
heat bonding, the first m-PTFE film layer, the adhesive film layer of PFA, the polyimide film layer, the additional adhesive film layer of PFA, and the additional layer of m-PTFE wherein said heat bonding forms a single composite material.