Metal foil with resin and metal-clad laminate, and printed wiring board using the same and method for production thereof
The present invention provides a metal clad laminate or a resin coated metal foil having a metal foil whose both surfaces are not substantially roughening-treated and an insulating resin composition layer using generally used insulating resin, and a printed wiring board and a manufacturing method thereof, in which the metal clad laminate or the resin coated metal foil is used, the reliability and circuit formability are high, and the conductor loss is extremely low.
1. Resin coated metal foil including an insulating resin composition layer and metal foil, wherein said metal foil is fixed to one or both surfaces of said insulating resin composition layer, wherein:
said insulating resin composition layer contains polyamidoimide resin and epoxy resin,
surface treatment which is an anti-corrosive treatment using any one of nickel, tin, zinc, molybdenum, and cobalt or an alloy thereof, a chromate treatment and a silane coupling treatment is performed to at least an insulating resin composition layer side of said metal foil,
a thickness of said metal foil is not more than 3 μm, and
roughening treatment is not substantially performed to both the surfaces of said metal foil.
2. The resin coated metal foil according to claim 1 , characterized in that surface roughness (Rz) of said metal foil is not more than 2.0 μm in both the surfaces.
3. The resin coated metal foil according to claim 2 , wherein the surface roughness (Rz) of said metal foil is not more than 1.5 μm in both the surfaces.
4. The resin coated metal foil according to claim 2 , wherein the surface roughness (Rz) of said metal foil is not more than 1.0 μm in both the surfaces.
5. The resin coated metal foil according to claim 1 , characterized in that interfacial roughness (Rz) between said insulating resin composition layer and said metal foil is not more than 2.0 μm.
6. The resin coated metal foil according to claim 1 , characterized in that a silane coupling agent used for said silane coupling treatment chemically reacts with said insulating resin composition by heating.
7. The resin coated metal foil according to claim 1 , characterized in that said insulating resin composition contains epoxy resin which is liquid at room temperatures.
8. The resin coated metal foil according to claim 1 , characterized in that, said insulating resin composition after being cured has a relative dielectric constant is not more than 3.0 at 1 GHz or a dielectric loss tangent is not more than 0.01 at 1 GHz.
9. A printed wiring board characterized by being manufactured with resin coated metal foil according to claim 1 .
10. The printed wiring board according to claim 9 , characterized in that surface roughness (Rz) of a conductor circuit is not more than 2.0 μm.
11. The printed wiring board according to claim 9 , characterized in that peel strength between said insulating resin composition layer and a conductor circuit having a width of 1 mm is not lower than 0.6 kN/m.
12. The printed wiring board according to claim 9 , characterized in that the peel strength between said insulating resin composition layer that has been heated at 150° C. for 240 hours and a conductor circuit having the width of 1 mm is not lower than 0.4 kN/m.
13. The resin coated metal foil according to claim 1 , wherein the metal foil is a copper foil.
14. The resin coated metal foil according to claim 1 , wherein said polyamidoimide resin is siloxane denatured polyamidoimide resin.
15. The resin coated metal foil according to claim 14 , wherein said siloxane denatured polyamidoimide resin has a molecular weight not lower than 50,000.
16. A metal clad laminate including an insulating resin composition layer and metal foil, wherein said metal foil is fixed to one or both surfaces of said insulating resin composition layer, wherein:
said insulating resin composition layer contains polyamidoimide resin and epoxy resin,
surface treatment which is an anti-corrosive treatment using any one of nickel, tin, zinc, molybdenum, and cobalt or an alloy thereof, a chromate treatment and a silane coupling treatment is performed to at least an insulating resin composition layer side of said metal foil,
a thickness of said metal foil is not more than 3 μm, and
roughening treatment is not substantially performed to both the surfaces of said metal foil.
17. The metal clad laminate according to claim 16 , characterized in that surface roughness (Rz) of said metal foil is not more than 2.0 μm in both the surfaces.
18. The metal clad laminate according to claim 16 , characterized in that interfacial roughness (Rz) between said insulating resin composition layer and said metal foil is not more than 2.0 μm.
19. The metal clad laminate according to claim 16 , characterized in that a silane coupling agent used for said silane coupling treatment chemically reacts with said insulating resin composition by heating.
20. The metal clad laminate according to claim 16 , characterized in that said insulating resin composition contains epoxy resin which is liquid at room temperatures.
21. The metal clad laminate according to claim 16 , characterized in that, said insulating resin composition after being cured has a relative dielectric constant is not more than 3.0 at 1 GHz or a dielectric loss tangent is not more than 0.01 at 1 GHz.
22. A printed wiring board characterized by being manufactured with a metal clad laminate according to claim 16 .
23. The printed wiring board according to claim 22 , characterized in that surface roughness (Rz) of a conductor circuit is not more than 2.0 μm.
24. The printed wiring board according to claim 22 , characterized in that peel strength between said insulating resin composition layer and a conductor circuit having a width of 1 mm is not lower than 0.6 kN/m.
25. The printed wiring board according to claim 22 , characterized in that the peel strength between said insulating resin composition layer that has been heated at 150° C. for 240 hours and a conductor circuit having the width of 1 mm is not lower than 0.4 kN/m.
26. The metal clad laminate according to claim 16 , wherein the metal foil is a copper foil.
27. The metal clad laminate according to claim 16 , wherein said polyamidoimide resin is siloxane denatured polyamidoimide resin.
28. The metal clad laminate to claim 27 , wherein said siloxane denatured polyamidoimide resin has a molecular weight not lower than 50,000.