Method for block-copolymer lithography
View Patent ↗The present disclosure relates to a method ( 10 ) for block-copolymer lithography. This method comprises the step of obtaining ( 12 ) a self-organizing block-copolymer layer comprising at least two polymer components having mutually different etching resistances, and the steps of applying at least once each of first plasma etching ( 14 ) of said self-organizing block-copolymer layer using a plasma formed from a substantially ashing gas, and second plasma etching ( 16 ) of said self-organizing block-copolymer layer using plasma formed from a pure inert gas or mixture of inert gases in order to selectively remove a first polymer phase. A corresponding intermediate product also is described.
1. A method for block-copolymer lithography, the method comprising:
obtaining a self-organizing block-copolymer layer on a substrate, said self-organizing block-copolymer layer comprising at least two polymer components having mutually different etching resistances, said self-organizing block-copolymer layer furthermore comprising a copolymer pattern structure formed by micro-phase separation of said at least two polymer components,
applying at least once each
a first plasma etching of said self-organizing block-copolymer layer using plasma formed from a gas comprising an ashing gas, and
a second plasma etching of said self-organizing block-copolymer layer using a plasma formed from a substantially pure inert gas or mixture of inert gases in order to selectively remove a first polymer phase.
2. A method according to claim 1 , wherein said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching.
3. A method according to claim 1 , wherein the ashing gas is oxygen.
4. The method according to claim 1 , wherein the first plasma etching step is applied at least once before application of the second plasma etching step.
5. The method according to claim 1 , wherein the second plasma etching step is applied at least once before application of the first plasma etching step.
6. The method according to claim 1 , wherein performing said first plasma etching and said second plasma etching comprises repeating said first plasma etching and said second plasma etching at least once alternatingly.
7. The method according to claim 1 , wherein said substantially pure inert gas is argon.
8. The method according to claim 1 , wherein said performing a first plasma etching of said layer comprises using a plasma formed from an argon-oxygen gas mixture.
9. The method according to claim 1 , furthermore comprising providing a pre-mask pattern on said substrate, said pre-mask pattern comprising a plurality of guides for aligning said copolymer pattern structure.
10. The method according to claim 1 , in which said copolymer pattern structure is formed by annealing the block copolymer layer.
11. The method according to claim 1 , wherein said block-copolymer comprises a di-block copolymer comprising two types of polymer chains covalently bonded to each other.
12. The method according to claim 11 , wherein said di-block copolymer comprises polystyrene-polyisobutene, polystyrene-isoprene, polydimethylsiloxane-polyisobutene, polystyrene-polyethylene oxide, polystyrene-polypropylene oxide, polyethyleneoxide-poly(cyanobiphenyloxy)hexyl methacrylate, polystyrene-polymethyl methacrylate, polystyrene-polymethacrylic acid, polyethylene oxide-polyvinylpyridine, polystyrene-polyvinylpyridine, or polyisoprene-polyhydroxystyrene.
13. The method according to claim 1 , wherein said block copolymer comprises a triblock copolymer in which two types of polymer chains A,B are bonded in an A-B-A form or in which three types of polymer chains A,B,C are bonded in an A-B-C form.
14. The method according to claim 1 , furthermore comprising the step of etching the substrate using the remaining polymer component or components after etching away said first polymer component from the block copolymer layer as a resist mask.
15. The method according to claim 1 , wherein
said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching; and
the ashing gas is oxygen.
16. The method according to claim 1 , wherein
said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching; and
performing said first plasma etching and said second plasma etching comprises repeating said first plasma etching and said second plasma etching at least once alternatingly.
17. The method according to claim 1 ,
wherein said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching; and
further comprising providing a pre-mask pattern on said substrate, said pre-mask pattern comprising a plurality of guides for aligning said copolymer pattern structure.
18. The method according to claim 1 , wherein
said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching; and
said di-block copolymer comprises polystyrene-polyisobutene, polystyrene-isoprene, polydimethylsiloxane-polyisobutene, polystyrene-polyethylene oxide, polystyrene-polypropylene oxide, polyethyleneoxide-poly(cyanobiphenyloxy)hexyl methacrylate, polystyrene-polymethyl methacrylate, polystyrene-polymethacrylic acid, polyethylene oxide-polyvinylpyridine, polystyrene-polyvinylpyridine, or polyisoprene-polyhydroxystyrene.
19. The method according to claim 1 ,
wherein said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching; and
further comprising the step of etching the substrate using the remaining polymer component or components after etching away said first polymer component from the block copolymer layer as a resist mask.
20. The method according to claim 1 ,
wherein said applying second plasma etching is performed at a plasma etch sputtering power lower or equal to the plasma etch sputtering power of the first plasma etching and/or wherein said applying second plasma etching is performed at a plasma etch gas pressure lower or equal to the plasma etch gas pressure of the first plasma etching;
wherein said first plasma etching and said second plasma etching comprises repeating said first plasma etching and said second plasma etching at least once alternatingly; and
further comprising the step of etching the substrate using the remaining polymer component or components after etching away said first polymer component from the block copolymer layer as a resist mask.