IP Library Granted Patent US 9,105,805
Granted Patent B2
US 9,105,805 · App. 14/146,138 · Granted Aug 11, 2015

Enhancing efficiency in solar cells by adjusting deposition power

Inventors: Ahmed Abou-Kandil (Elmsford, NY); Augustin J. Hong (White Plains, NY); Jeehwan Kim (White Plains, NY); Devendra K. Sadana (Pleasantville, NY)
Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
H01L31/1884C23C16/22H01L31/02167H01L31/075H01L31/204Y02E10/548
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Quick Facts
Patent No.
US 9,105,805
App. No.
14/146,138
Granted
Aug 11, 2015
Kind
B2
Abstract

Methods for forming a photovoltaic device include adjusting a deposition power for depositing a buffer layer including germanium on a transparent electrode. The deposition power is configured to improve device efficiency. A p-type layer is formed on the buffer layer. An intrinsic layer and an n-type layer are formed over the p-type layer.

Claims (22)

1. A method for forming a photovoltaic device, comprising:

adjusting a deposition power for depositing a buffer layer including germanium on a transparent electrode, the deposition power being configured to improve device efficiency, wherein the buffer layer aligns band gap energies between the transparent electrode and a subsequently formed p-type layer by ramping the deposition power at least during deposition of the buffer layer;

forming the p-type layer on the buffer layer; and

forming an intrinsic layer and an n-type layer over the p-type layer.

2. The method as recited in claim 1 , wherein depositing the buffer layer includes depositing at least one of a hydrogenated amorphous silicon germanium alloy, a hydrogenated microcrystalline silicon-germanium alloy, a hydrogenated amorphous germanium or a hydrogenated microcrystalline germanium.

3. The method as recited in claim 1 , wherein the deposition power is increased to increase fill factor.

4. The method as recited in claim 1 , wherein the buffer layer is formed by a GeH 4 plasma enhanced deposition.

5. The method as recited in claim 1 , wherein the p-type layer, the intrinsic layer and the n-type layer are formed at a temperature of about 250 degrees Celsius.

6. The method as recited in claim 1 , further comprising adjusting a deposition power for the p-type layer to improve device efficiency.

7. The method as recited in claim 1 , wherein the p-type layer includes a form of silicon.

8. The method as recited in claim 7 , wherein the p-type layer includes at least one of amorphous silicon, amorphous silicon carbide, hydrogenated amorphous silicon, or hydrogenated amorphous silicon carbide.

9. A method for forming a photovoltaic device, comprising:

adjusting a deposition power for depositing a buffer layer including germanium on a transparent electrode, the deposition power being configured to improve device efficiency, wherein the adjusting of the deposition power for depositing the buffer layer to improve device efficiency occurs by ramping the deposition power at least during deposition of the buffer layer;

forming the p-type layer on the buffer layer; and

forming an intrinsic layer and an n-type layer over the p-type layer.

10. The method as recited in claim 9 , wherein depositing the buffer layer includes depositing at least one of a hydrogenated amorphous silicon germanium alloy, a hydrogenated microcrystalline silicon-germanium alloy, a hydrogenated amorphous germanium or a hydrogenated microcrystalline germanium.

11. The method as recited in claim 9 , wherein the deposition power is increased to increase fill factor.

12. The method as recited in claim 9 , wherein the buffer layer is formed by a GeH 4 plasma enhanced deposition.

13. The method as recited in claim 9 , wherein the p-type layer, the intrinsic layer and the n-type layer are formed at a temperature of about 250 degrees Celsius.

14. The method as recited in claim 9 , further comprising adjusting a deposition power for the p-type layer to improve device efficiency.

15. The method as recited in claim 9 , wherein the p-type layer includes a form of silicon.

16. The method as recited in claim 7 , wherein the p-type layer includes at least one of amorphous silicon, amorphous silicon carbide, hydrogenated amorphous silicon, or hydrogenated amorphous silicon carbide.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2015
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: INTERNATIONAL BUSINESS MACHINES CORPORATION; EGYPT NANOTECHNOLOGY CENTER (EGNC)
Reel/Frame 037057/0605 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 2, 2014
From: ABOU-KANDIL, AHMED; HONG, AUGUSTIN J.; KIM, JEEHWAN; SADANA, DEVENDRA K.
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 031875/0767 →
Continuity (2)
Continuation 13406970 · Feb 28, 2012
Related Publication 20140120655A1 · May 1, 2014