IP Library Granted Patent US 9,447,329
Granted Patent B2
US 9,447,329 · App. 14/070,078 · Granted Sep 20, 2016

Analogue ionic liquids for the separation and recovery of hydrocarbons from particulate matter

Inventors: Paul Painter (Boalsburg, PA); Phil Williams (State College, PA); Ehren Mannebach (Fond du Lac, WI); Aron Lupinsky (State College, PA)
Assignee: The Penn State Research Foundation
C10G1/045C10G1/04C10G2300/1033C10G2300/44C10G2300/805
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Quick Facts
Patent No.
US 9,447,329
App. No.
14/070,078
Granted
Sep 20, 2016
Kind
B2
Abstract

Systems, methods and compositions for the separation and recovery of hydrocarbons from particulate matter are herein disclosed. According to one embodiment, a method includes contacting particulate matter with at least one analogue ionic liquid. The particulate matter contains at least one hydrocarbon and at least one solid particulate. When the particulate matter is contacted with the analogue ionic liquid, the hydrocarbon dissociates from the solid particulate to form a multiphase system.

Claims (26)

1. A method of separating a hydrocarbon from particulate matter, the method comprising:

preparing a mixture of an ionic liquid and particulate matter containing a hydrocarbon;

subjecting the mixture to electromagnetic heating; and

separating the hydrocarbon from the particulate matter,

wherein the ionic liquid separates at least 90% of the hydrocarbon from the particulate matter.

2. The method of claim 1 , wherein the particulate matter includes rock containing hydrocarbon.

3. The method of claim 1 , subjecting the mixture to microwave heating as the electromagnetic heating.

4. The method of claim 1 , further comprising recycling the ionic liquid to mix the ionic liquid with additional particulate matter.

5. A method of separating a hydrocarbon from particulate matter, the method comprising:

mixing particulate matter containing a hydrocarbon with an ionic liquid comprising a tetraalkyl ammonium salt;

subjecting the mixture to electromagnetic heating; and

separating the hydrocarbon from the particulate matter.

6. The method of claim 5 further comprising mixing an organic solvent with the particulate matter and the ionic liquid.

7. The method of claim 5 , wherein the ionic liquid includes 2-hydroxyethyl(trimethyl) ammonium chloride (choline chloride) as the tetraalkyl ammonium salt.

8. The method of claim 5 , wherein the mixture is subjected to electromagnetic heating to heat the mixture to a temperature below 100° C.

9. The method of claim 5 , wherein the mixture is subjected to electromagnetic heating to heat the mixture to a temperature less than or equal to 50° C.

10. The method of claim 5 , wherein the ionic liquid separates at least 90% of the hydrocarbon from the particulate matter.

11. A method of separating a hydrocarbon from particulate matter, the method comprising:

mixing particulate matter containing a hydrocarbon with an ionic liquid comprising a tetraalkyl ammonium salt, wherein the particulate matter includes bitumen as the hydrocarbon;

subjecting the mixture to electromagnetic heating; and

separating the bitumen from the particulate matter.

12. The method of claim 11 , wherein the ionic liquid includes 2-hydroxyethyl(trimethyl) ammonium chloride (choline chloride).

13. The method of claim 12 , wherein mixing the particulate matter comprises mixing the particulate matter with a composition including the ionic liquid and at least one organic solvent.

14. The method of claim 11 , wherein mixing the particulate matter comprises mixing the particulate matter with a composition including the ionic liquid and at least one organic solvent.

15. The method of claim 11 , wherein the mixture is subjected to electromagnetic heating to heat the mixture to a temperature less than or equal to 50 ° C.

16. The method of claim 11 , wherein the ionic liquid separates at least 90% of the bitumen, oil or drilling fluid from the particulate matter.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2014
From: PAINTER, PAUL; WILLIAMS, PHIL; MANNEBACH, EHRENN; LUPINSKY, ARON
To: THE PENN STATE RESEARCH FOUNDATION
Reel/Frame 033844/0303 →
CONFIRMATORY LICENSE Recorded Jul 22, 2014
From: THE PENNSYLVANIA STATE UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 033380/0379 →
Continuity (4)
Continuation 13252523 · Oct 4, 2011
Continuation In Part 12854553 · Aug 11, 2010
Provisional Application 61236405 · Aug 24, 2009
Related Publication 20140054200A1 · Feb 27, 2014