Synthesis of pyrochlore nanostructures and uses thereof
A template-free reverse micelle (RM) based method is used to synthesize pyrochlore nanostructures having photocatalytic activity. In one embodiment, the method includes separately mixing together a first acid stabilized aqueous solution including pyrochlore precursor A and a second acid stabilized aqueous solution including pyrochlore precursor B with an organic solution including a surfactant to form an oil-in-water emulsion. Next, equimolar solutions of the first and second acid stabilized oil-in-water emulsions are mixed together. Then, the mixture of the first and second acid stabilized oil-in-water emulsion is treated with a base to produce a precipitate including pyrochlore precursors A and B. After which, the precipitate is dried to remove volatiles. The precipitate is then calcined in the presence of oxygen to form a pyrochlore nanostructure, such as a bismuth titanate (Bi 2 Ti 2 O 7 ) pyrochlore nanorod. The method of synthesizing the pyrochlore nanorod is template-free.
1. A pyrochlore nanorod having the general formula A 2 B 2 O 7 , wherein A is bismuth (Bi), calcium (Ca), strontium (Sr), yttrium (Y), barium (Ba), lanthanum (La), or combinations thereof; B is titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), zirconium (Zr), hafnium (Hf), tantalum (Ta), tungsten (W), or combinations thereof; and O is oxygen.
2. The pyrochlore nanorod of claim 1 , wherein the pyrochlore nanorod has an aspect ratio of about 1:10.
3. The pyrochlore nanorod of claim 1 , wherein the pyrochlore nanorod has a diameter of about 40 nm to about 50 nm, and a length of about 400 nm to about 500 nm.
4. The pyrochlore nanorod of claim 1 having photocatalytic activity.
5. The pyrochlore nanorod of claim 1 wherein A is bismuth (Bi) and B is titanium (Ti).
6. The pyrochlore nanorod of claim 1 , wherein B comprises a combination of two elements selected from titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), zirconium (Zr), hafnium (Hf), tantalum (Ta), and tungsten (W).
7. A sphere-shaped pyrochlore nanostructure having the general formula A 2 B 2 O 7 , wherein A is bismuth (Bi), calcium (Ca), strontium (Sr), yttrium (Y), barium (Ba), lanthanum (La), or combinations thereof; B is titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), zirconium (Zr), hafnium (Hf), tantalum (Ta), tungsten (W), or combinations thereof; O is oxygen; and wherein the sphere-shaped pyrochlore nanostructure has a diameter of about 20 nm.
8. A sphere-shaped pyrochlore nanostructure having the general formula A 2 B 2 O 7 , wherein A is bismuth (Bi), calcium (Ca), strontium (Sr), yttrium (Y), barium (Ba), lanthanum (La), or combinations thereof; B comprises a combination of two elements selected from titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), zirconium (Zr), hafnium (Hf), tantalum (Ta), and tungsten (W); and O is oxygen.
9. A pyrochlore nanorod having the general formula A 2 B 2 O 7 , wherein A is bismuth (Bi), calcium (Ca), strontium (Sr), yttrium (Y), barium (Ba), lanthanum (La), or combinations thereof; B is titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), zirconium (Zr), tin (Sn), hafnium (Hf), tantalum (Ta), tungsten (W), or combinations thereof; O is oxygen; and wherein the pyrochlore nanorod has a diameter of about 40 nm to about 50 nm, and a length of about 400 nm to about 500 nm.