IP Library Granted Patent US 7,749,631
Granted Patent B2
US 7,749,631 · App. 11/142,583 · Granted Jul 6, 2010

Fuel cell separator plate coating

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Quick Facts
Patent No.
US 7,749,631
App. No.
11/142,583
Granted
Jul 6, 2010
Kind
B2
Abstract

A fuel cell electroconductive element, or bipolar plate, that includes a substrate with a cationic or anionic exchange resin coating deposited thereon, and a method for making the same. The bipolar plate has a fluid flow field formed therein. The ion-exchange polymer is preferably deposited on a region of the surface of the substrate by a process of dip coating or spraying. The resin coating is substantially hydrophobic in nature when dry and substantially hydrophilic when wet.

Claims (20)

1. A fuel cell electrically conductive element comprising:

a non-porous substrate having a surface constructed and arranged to distribute reactant gas, wherein at least one region of the surface comprises a discontinuous resin coating, the resin coating being substantially hydrophobic when dry and substantially hydrophilic when wet.

2. The electrically conductive element of claim 1 , wherein the resin coating comprises an ion-exchange resin.

3. The electrically conductive element of claim 1 , wherein the resin coating comprises a perfluorosulfonic acid polymer.

4. The electrically conductive element of claim 1 , wherein the resin coating exhibits a static water contact angle less than about 45 degrees during conditions greater than 100% Local Relative Humidity.

5. The electrically conductive element of claim 1 , wherein the resin coating exhibits a static water contact angle greater than about 90 degrees during conditions less than about 90% Local Relative Humidity.

6. The electrically conductive element of claim 1 , wherein the resin coating has a thickness of from about 0.01 to about 10 μm.

7. The electrically conductive element of claim 1 , wherein the resin coating comprises a first region having a first thickness and a second region having a second thickness different from the first thickness.

8. The electrically conductive element of claim 1 , wherein the substrate comprises one of a composite material, metallic material, or both.

9. The electrically conductive element of claim 1 , wherein the resin coating comprises a plurality of discontinuous regions spaced apart such that a distance between coated regions is on average from about 10 to about 100 μm.

10. A fuel cell comprising:

an anode;

a cathode;

a proton exchange membrane disposed between the anode and cathode; and

at least one non-porous flow field plate disposed adjacent to the anode or the cathode or both the anode and the cathode,

wherein the flow field plate comprises an ion-exchange resin coating having a plurality of discontinuous regions, the resin coating being substantially hydrophobic when dry and substantially hydrophilic when wet.

11. The fuel cell according to claim 10 , wherein the resin coating has a thickness of from about 0.01 to about 10 μm.

12. The fuel cell according to claim 10 , wherein the plurality of discontinuous regions are spaced apart such that a distance between coated regions is on average from about 10 to about 100 μm.

13. The fuel cell according to claim 10 , further comprising a gas diffusion layer adjacent to at least one of the anode and cathode and comprising a fibrous material, wherein the plurality of discontinuous regions are spaced apart such that a distance between coated regions is from about 1 to about 10 times the size of an average fiber diameter of the fibrous material.

14. The fuel cell according to claim 10 , wherein the resin coating comprises a perfluorosulfonic acid polymer.

Assignments (12)
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2014
From: WILMINGTON TRUST COMPANY
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 034371/0676 →
CHANGE OF NAME Recorded Feb 10, 2011
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 025780/0936 →
SECURITY AGREEMENT Recorded Nov 8, 2010
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: WILMINGTON TRUST COMPANY
Reel/Frame 025327/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2010
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025245/0442 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2010
From: UAW RETIREE MEDICAL BENEFITS TRUST
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025311/0770 →
SECURITY AGREEMENT Recorded Aug 28, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UAW RETIREE MEDICAL BENEFITS TRUST
Reel/Frame 023162/0001 →
SECURITY AGREEMENT Recorded Aug 27, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 023156/0052 →
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2009
From: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023127/0402 →
RELEASE OF SECURITY INTEREST Recorded Aug 20, 2009
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023124/0519 →
SECURITY AGREEMENT Recorded Apr 16, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
Reel/Frame 022553/0493 →
SECURITY AGREEMENT Recorded Feb 3, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 022195/0334 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2005
From: ABD ELHAMID, MAHMOUD H.; VYAS, GAYATRI; TRABOLD, THOMAS A.; MIKHAIL, YOUSSEF M.
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 016577/0204 →