Memory cell containing copolymer containing diarylacetylene portion
View Patent ↗An organic memory cell containing an organic semiconductor layer containing a copolymer is disclosed. The copolymer contains a diarylacetylene portion and at least one of an arylacetylene portion and a heterocyclic acetylene portion. The copolymer may be a random copolymer, an alternating copolymer, a random block copolymer, or a block copolymer. Methods of making an organic memory devices/cells containing the copolymer, methods of using the organic memory devices/cells, and devices such as computers containing the organic memory devices/cells are also disclosed.
1. An organic memory cell comprising:
a first electrode and a second electrode;
a controllably conductive media between the first and second electrodes, the controllably conductive media comprising a passive layer comprising at least copper sulfide and an organic semiconductor layer, the organic semiconductor layer comprising a copolymer comprising a diarylacetylene portion and at least one of an arylacetylene portion and a heterocyclic acetylene portion,
wherein the copolymer is formed by polymerization of at least a diarylacetylene in the presence of at least one selected from an arylacetylene and a heterocyclic acetylene.
2. The organic memory cell of claim 1 , wherein the first electrode comprises at least copper.
3. The organic memory cell of claim 1 , wherein the copolymer is a random copolymer, an alternating copolymer, a random block copolymer, or a block copolymer.
4. The organic memory cell of claim 1 , wherein the diarylacetylene portion and the arylacetylene portion independently comprises at least one of monocyclic aromatic hydrocarbon group consisting of 6 to 18 carbon atoms and fused polycyclic aromatic hydrocarbon group.
5. The organic memory cell of claim 1 , wherein the heterocyclic acetylene portion comprises at least one selected from the group consisting of a pyridyl group, a pyridazinyl group, a pyrimidyl group, a pyrazinyl group, a quinolyl group, an isoquinolyl group, a quinazolinyl group, a cinnolinyl group, and a phthalazinyl group.
6. The organic memory cell of claim 1 , wherein at least one of the diarylacetylene portion, the arylacetylene portion, and the heterocyclic acetylene portion has at least one substituted group thereon.
7. The organic memory cell of claim 4 , wherein the monocyclic aromatic hydrocarbon group is a phenyl group.
8. The organic memory cell of claim 4 , wherein the fused polycyclic aromatic hydrocarbon group comprises at least one selected from the group consisting of a naphthyl group, an anthryl group, a phenanthryl group, a naphthacenyl group, a pyrenyl group, a triphenylenyl group, and a chrysenyl group.
9. The organic memory cell of claim 1 , wherein the copolymer comprises a diphenylacetylene portion and a phenylacetylene portion.
10. The organic memory cell of claim 1 , wherein the copolymer comprises from about 0.05% to about 99.95% by weight of the diarylacetylene portion and from about 99.95% to about 0.05% by weight of at least one of the arylacetylene portion and the heterocyclic acetylene portion.
11. The organic memory cell of claim 1 , wherein the copolymer comprises from about 50% to about 99.9% by weight of the diarylacetylene portion and from about 50% to about 0.1% by weight of at least one of the arylacetylene portion and the heterocyclic acetylene portion.
12. The organic memory cell of claim 1 , wherein the organic semiconductor layer has a thickness of about 0.001 μm or more and about 5 μm or less and the passive layer has a thickness of about 2 Å or more and about 0.1 μm or less.
13. A hand held device comprising the organic memory cell of claim 1 .
14. A memory device comprising a plurality of memory cells, the plurality of memory cells comprising:
a first electrode and a second electrode;
a controllably conductive media between the first and second electrodes, the controllably conductive media comprising a passive layer comprising at least copper sulfide and an organic semiconductor layer, the organic semiconductor layer comprising a copolymer comprising a diarylacetylene portion and at least one of an arylacetylene portion and a heterocyclic acetylene portion,
wherein the copolymer is formed by polymerization of at least a diarylacetylene in the presence of at least one selected from an arylacetylene and a heterocyclic acetylene.
15. The memory device of claim 14 , wherein the copolymer comprises a diphenylacetylene portion and a phenylacetylene portion.
16. The memory device of claim 14 , wherein the copolymer comprises from about 0.05% to about 99.95% by weight of the diarylacetylene portion and from about 99.95% to about 0.05% by weight of at least one of the arylacetylene portion and the heterocyclic acetylene portion.
17. The memory device of claim 14 , wherein the first electrode comprises at least copper.
18. The memory device of claim 14 , wherein the diarylacetylene portion and the arylacetylene portion independently comprises at least one of monocyclic aromatic hydrocarbon group consisting of 6 to 18 carbon atoms and fused polycyclic aromatic hydrocarbon group.
19. A hand held device comprising the memory device of claim 14 .
20. A cell phone comprising the memory device of claim 14 .