Targeted deposition of nanotubes
View Patent ↗A method for targeted deposition of a nanotube on a planar surface includes providing a ram made from elastomeric material and having a relief structure on its surface. A microfluid capillary system, with an inlet and an outlet, is then formed by applying the ram to a planar substrate. A dispersion of nanotubes is brought into contact with the inlet, thereby enabling capillary force to disperse the nanotubes. through the microfluid capillary system. The resulting dispersion of nanotubes is then dried and the ram removed.
1. A method for the targeted deposition of a nanotube on a planar surfaces, the method comprising:
providing a ram made from elastomeric material, the ram having a relief structure on a ram surface thereof;
forming a microfluid capillary system by applying the ram to a planar substrate, the microfluid capillary system having at least one capillary having an inlet and an outlet;
bringing a dispersion of nanotubes into contact with the inlet, thereby enabling capillary force to disperse the nanotubes through the microfluid capillary system;
drying the resulting dispersion of nanotubes; and
removing the ram.
2. The method of claim 1 , further comprising selecting the nanotubes from the group consisting of carbon nanotubes, carbon nanotubes doped with boron nitride, and oxidized carbon nanotubes.
3. The method of claim 1 , further comprising dispersing the nanotubes in a polar organic solvent.
4. The method of claim 1 , further comprising selecting the substrate from the group consisting of silicon, gallium phosphide, indium phosphide, glass, and aluminum oxide.
5. The method of claim 1 , further comprising selecting the elastomeric material from the group consisting of polydialkylsiloxane, polyurethane, polyimide, polydimethylsiloxane, and cross-linked Novolak resin.
6. The method of claim 1 , further comprising subjecting the ram to hydrophilization prior to applying the ram to the planar substrate.
7. The method of claim 6 , wherein subjecting the ram to hydrophilization comprises exposing the ram to oxygen plasma.
8. The method of claim 1 , further comprising selecting a width and height of the capillary to be between 0.05 microns and 10 microns and selecting a length of the capillary to be between 0.1 microns and 1.5 centimeters.
9. The method of claim 8 , further comprising selecting the width and height of the capillary to be between 0.3 microns and 10 microns.
10. The method of claim 1 further comprising orienting the nanotubes prior to drying the dispersion of nanotubes.
11. The method of claim 10 , wherein orienting the nanotubes comprises exposing the nanotubes to an applied magnetic field.
12. The method of claim 10 , further comprising selecting the nanotubes to be oxidized carbon nanotubes, and wherein orienting the oxidized carbon nanotubes comprises exposing the nanotubes to an applied electric field.
13. A method for targeted deposition of a nanotube on a planar surface, the method comprising:
executing the method recited in claim 1 using a ram having a first relief structure on a ram surface thereof;
re-executing the method recited in claim 1 using a ram having a second relief structure on a ram surface thereof, the second relief structure being different from the first relief structure.
14. A method for targeted deposition of a nanotube on a planar surface, the method comprising:
depositing a first layer of nanotubes by executing the method recited in claim 1 , the first layer of nanotubes having a first orientation;
depositing a second layer of nanotubes by executing the method recited in claim 1 a second time with the ram applied to the substrate already structured during execution of the method recited in claim 1 the first time, the second layer of nanotubes having a second orientation that differs from the first orientation.
15. The method of claim 14 , further comprising selecting the first and second orientations to be perpendicular to each other.