Process for fabricating RuSixOy-containing adhesion layers
View Patent ↗A method for use in the fabrication of integrated circuits includes providing a substrate assembly having a surface. An adhesion layer is formed over at least a portion of the surface. The adhesion layer is formed of RuSi x O y , where x and y are in the range of about 0.01 to about 10. The adhesion layer may be formed by depositing RuSi x O y by chemical vapor deposition, atomic layer deposition, or physical vapor deposition or the adhesion layer may be formed by forming a layer of ruthenium or ruthenium oxide over a silicon-containing region and performing an anneal to form RuSi x O y from the layer of ruthenium and silicon from the adjacent silicon-containing region. Capacitor electrodes, interconnects or other structures may be formed with such an adhesion layer. Semiconductor structures and devices can be formed to include adhesion layers formed of RuSi x O y .
1. A method for forming a capacitor, comprising:
forming an adhesion layer of RuSi x O y on at least a portion of a substrate assembly, where x and y are in a range of about 0.01 to about 10 and wherein forming the adhesion layer of RuSi x O y comprises:
forming a layer of ruthenium on the at least a portion of a silicon-containing region of the substrate assembly; and
annealing the layer of ruthenium formed on the at least a portion of the silicon-containing region, resulting in the adhesion layer of RuSi x O y ;
providing a high dielectric constant material over at least a portion of the adhesion layer of RuSi x O y ; and
providing an electrode over the high dielectric constant material.
2. The method of claim 1 , further including forming the adhesion layer with RuSi x O y where x and y are in a range of about 0.01 to about 1.
3. The method of claim 1 , further including forming the adhesion layer with RuSi x O y where x is about 0.4.
4. The method of claim 1 , further including forming the adhesion layer with RuSi x O y where y is about 0.05.
5. The method of claim 1 , further including forming the adhesion layer with RuSi x O y where x is in a range of about 0.01 to about 3.
6. The method of claim 1 , further including forming the adhesion layer with RuSi x O y where y is in a range of about 0.01 to about 1.
7. The method of claim 1 , wherein forming the layer of ruthenium includes depositing the layer of ruthenium by chemical vapor deposition to a thickness of from about 10 Å to about 5000 Å.
8. The method of claim 1 , wherein forming the layer of ruthenium includes depositing the layer of ruthenium by atomic layer deposition to a thickness of from about 10 Å to about 1000 Å.
9. The method of claim 8 , wherein forming the layer of ruthenium includes depositing three to five monolayers of ruthenium.
10. The method of claim 8 , wherein forming the layer of ruthenium comprises forming the layer of ruthenium to the thickness of from about 50 Å to about 500 Å.
11. The method of claim 8 , wherein forming the layer of ruthenium comprises forming the layer of ruthenium to the thickness of about 300 Å.
12. The method of claim 1 , wherein annealing the layer of ruthenium formed on the at least a portion of the silicon-containing region includes annealing at a temperature in a range of about 400° C. to about 1000° C. for about 0.5 minutes to about 60 minutes in an inert gas atmosphere.
13. A method for forming a capacitor, comprising:
forming an adhesion layer of RuSi x O y on at least a portion of a substrate assembly, where x and y are in a range of about 0.01 to about 10 and wherein the adhesion layer of RuSi x O y is formed by chemical vapor deposition using a ruthenium precursor and a silicon precursor;
providing a high dielectric constant material over at least a portion of the adhesion layer of RuSi x O y ; and
providing an electrode over the high dielectric constant material.
14. The method of claim 13 , further including forming the adhesion layer with RuSi x O y where x and y are in the range of about 0.01 to about 1.
15. The method of claim 13 , further including forming the adhesion layer with RuSi x O y where x is about 0.4.
16. The method of claim 13 , further including forming the adhesion layer with RuSi x O y where y is about 0.05.