Method to passivate conductive surfaces during semiconductor processing
View Patent ↗A method for processing semiconductor wafers is disclosed. A solution is applied to a semiconductor wafer to prevent dendrites and electrolytic reactions at the surface of metal interconnects. The solution can be applied during a CMP process or during a post CMP cleaning process. The solution may include a surfactant and a corrosion inhibitor. In one embodiment, the concentration of the surfactant in the solution is less than approximately one percent by weight and the concentration of the corrosion inhibitor in the solution is less than approximately one percent by weight. The solution may also include a solvent and a cosolvent. In an alternate embodiment, the solution includes a solvent and a cosolvent without the surfactant and corrosion inhibitor. In one embodiment, the CMP process and post CMP cleaning process can be performed in the presence of light having a wavelength of less than approximately one micron.
1. A method for processing semiconductor wafers, comprising:
rinsing a surface of a semiconductor wafer having a plurality of conductive interconnects, wherein the plurality of the conductive interconnects are electrically isolated along the surface of the semiconductor wafer;
applying a solution to the semiconductor wafer, wherein the solution comprises a surfactant and a corrosion inhibitor and is applied during rinsing or after the rinsing of the surface of the semiconductor wafer; and
drying the semiconductor wafer after applying the solution to the semiconductor wafer, wherein at least one of the rinsing and the drying is performed in the presence of light having a wavelength of less than approximately one micron.
2. The method of claim 1 , wherein the solution is applied during and after the rinsing of the surface of the semiconductor wafer.
3. The method of claim 1 , wherein the rinsing is performed during a chemical mechanical polishing (CMP) process.
4. The method of claim 3 , wherein the drying is performed during a post CMP clean.
5. The method of claim 1 , wherein the surfactant comprises one of polyethylene glycol (PEG), polypropylene glycol (PPG), a block copolymer of polypropylene oxide (PPO) or polyethylene oxide (PLO), ammonium dodecyl sulfate, or alkyl phenol ether phosphate, amino ethyl imidazoline.
6. The method of claim 1 , wherein the corrosion inhibitor comprises one of benzene triazole (BTA), triazole, caffeine, theophylline, or bipyridyl.
7. The method of claim 1 , wherein the solution further comprises a solvent selected from a group consisting of alcohol, glycol, and acetone.
8. The method of claim 1 , wherein both the rinsing and the drying are performed in the presence of light having a wavelength of less than approximately one micron.
9. The method of claim 1 , wherein the plurality of the conductive interconnects comprise a conductive material selected from a group consisting of copper, aluminum, tungsten, silver, tantalum, and titanium.
10. The method of claim 1 , wherein the surfactant comprises the corrosion inhibitor.
11. The method of claim 1 , wherein applying the solution comprises at least one of submerging the semiconductor wafer into the solution, spraying the solution onto the semiconductor wafer, or pouring the solution onto the semiconductor wafer.
12. The method of claim 1 , wherein a concentration of the surfactant in the solution is less than approximately one percent by weight.
13. The method of claim 1 , wherein a concentration of the corrosion inhibitor in the solution is less than approximately one percent by weight.