IP Library Granted Patent US 6,916,865
Granted Patent B2
US 6,916,865 · App. 10/451,977 · Granted Jul 12, 2005

Organic carboxylic acid salt composition, process for preparation thereof and additives for epoxy resins

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Quick Facts
Patent No.
US 6,916,865
App. No.
10/451,977
Granted
Jul 12, 2005
Kind
B2
Abstract

The present invention provides an organic carboxylate composition that has long working life, cures epoxy resins, and improves adhesive properties, and also provides a method for producing the same. An organic carboxylate composition, obtained by heating and mixing a basic silane coupling agent and an amine compound with a softening point or melting point of 40° C. or greater together with an organic carboxylic acid; a method for producing the same; an additive for epoxy resin that contains this as the active ingredient thereof; and an epoxy resin composition containing the same. The basic silane coupling agent should preferably be a specific imidazole-group containing silane coupling agent, amino group-containing silane coupling agent, dialkylamino group-containing silane coupling agent, monomethylamino group-containing silane coupling agent, benzimidazole group-containing silane coupling agent, benzotriazole group-containing silane coupling agent, and pyridine ring-containing silane coupling agent.

Claims (10)

1. An organic carboxylate composition, obtained by heating and mixing a basic silane coupling agent and an amine compound having a softening point or melting point of 40° C. or greater together with an organic carboxylic acid.

2. A method for producing an organic carboxylate composition, comprising heating and mixing a basic silane coupling agent and an amine compound having a softening point or melting point of 40° C. or greater together with an organic carboxylic acid.

3. The organic carboxylate composition according to claim 1 , wherein the basic silane coupling agent is comprised of one compound or a mixture of two or more compounds selected from the group consisting of compounds expressed by the general formulas (1) through (4) below, or at least one selected from the group consisting of amino group-containing silane coupling agents, dialkylamino group-containing silane coupling agents, monomethylamino group-containing silane coupling agents, benzimidazole group-containing silane coupling agents, benzotriazole group-containing silane coupling agents, and pyridine ring-containing silane coupling agents,

wherein in the formulas (1) through (3), R 1 , R 2 , and R 3 each represent hydrogen, a vinyl group, or an alkyl group having 2 to 20 carbon atoms and R 2 and R 3 may form an aromatic ring; R 4 and R 5 each represent an alkyl group having 1 to 5 carbon atoms; and m and n are integers off 1 to 10 and 1 to 3, respectively, and

wherein in the formula (4), R 6 , R 7 , and R 8 each represent hydrogen, an alkyl group having 1 to 20 carbon atoms, a vinyl group, a phenyl group, or a benzyl group, and R 7 and R 8 may bond and form an aromatic ring; R 9 represents hydrogen or an alkyl group having 1 to 3 carbon atoms; R 10 and R 11 each represent an alkyl group having 1 to 5 carbon atoms; and a and p are integers of 1 to 10 and 1 to 3, respectively.

4. A method for producing the organic carboxylate composition according to claim 2 , wherein the basic silane coupling agent is comprised of one compound or a mixture of two or more compounds selected from the group consisting of compounds expressed by the general formulas (1) through (4) below, or at least one selected from the group consisting of amino group-containing silane coupling agents, dialkylamino group-containing silane coupling agents, monomethylamino group-containing silane coupling agents, benzimidazole group-containing silane coupling agents, benzotriazole group-containing silane coupling agents, and pyridine ring-containing silane coupling agents,

wherein in the formulas (1) through (3), R 1 , R 2 , and R 3 each represent hydrogen, a vinyl group, or an alkyl group having 1 to 20 carbon atoms and R 2 and R 3 may form an aromatic ring; R 4 and R 5 each represent an alkyl group having 1 to 5 carbon atoms; and m and n are integers of 1 to 10 and 1 to 3, respectively, and

wherein in the formula (4), R 6 , R 7 and R 8 each represent hydrogen, an alkyl group having 1 to 20 carbon atoms, a vinyl group, a phenyl group, or a benzyl group, and R 7 and R 8 may bond and form an aromatic ring; R 9 represents hydrogen or an alkyl group having 1 to 3 carbon atoms; R 10 and R 11 each represent an alkyl group having 1 to 5 carbon atoms; and o and p are integers of 1 to 10 and 1 to 3, respectively.

5. An epoxy resin composition, containing the organic carboxylate composition according to claim 1 .

6. An additive for epoxy resin, containing the organic carboxylate composition according to claim 1 .

Assignments (4)
CHANGE OF ADDRESS Recorded Feb 7, 2017
From: JX NIPPON MINING & METALS CORPORATION
To: JX NIPPON MINING & METALS CORPORATION
Reel/Frame 041649/0733 →
CHANGE OF NAME/MERGER Recorded Jun 9, 2011
From: NIPPON MINING & METALS CO., LTD.
To: JX NIPPON MINING & METALS CORPORATION
Reel/Frame 026417/0023 →
CHANGE OF NAME Recorded Sep 27, 2006
From: NIKKO MATERIALS CO., LTD.
To: NIPPON MINING & METALS CO., LTD.
Reel/Frame 018303/0546 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2003
From: KUMAGAI, MASASHI; OUCHI, TAKASHI; TSUCHIDA, KATSUYUKI
To: NIKKO MATERIALS CO., LTD.
Reel/Frame 014689/0499 →