IP Library Granted Patent US 6,955,967
Granted Patent B2
US 6,955,967 · App. 10/609,361 · Granted Oct 18, 2005

Non-volatile memory having a reference transistor and method for forming

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Quick Facts
Patent No.
US 6,955,967
App. No.
10/609,361
Granted
Oct 18, 2005
Kind
B2
Abstract

A non-volatile memory ( 30 ) comprises nanocrystal memory cells ( 50, 51, 53 ). The program and erase threshold voltage of the memory cell transistors ( 50, 51, 53 ) increase as a function of the number of program/erase operations. During a read operation, a reference transistor ( 46 ) provides a reference current for comparing with a cell current. The reference transistor ( 46 ) is made from a process similar to that used to make the memory cell transistors ( 50, 51, 53 ), except that the reference transistor ( 46 ) does not include nanocrystals. By using a similar process to make both the reference transistor ( 46 ) and the memory cell transistors ( 50, 51, 53 ), a threshold voltage of the reference transistor ( 46 ) will track the threshold voltage shift of the memory cell transistor ( 50, 51, 53 ). A read control circuit ( 42 ) is provided to bias the gate of the reference transistor ( 46 ). The read control circuit ( 42 ) senses a drain current of the reference transistor ( 46 ) and adjusts the gate bias voltage to maintain the reference current at a substantially constant value relative to the cell current.

Claims (40)

1. A process for forming a nonvolatile memory comprising:

providing a substrate;

identifying a first area of the substrate for a memory array and a second area of the substrate for a reference transistor;

forming a first dielectric layer overlying the substrate;

forming a storage material layer overlying the first dielectric layer;

forming a second dielectric layer overlying and surrounding the storage material layer;

forming a first barrier layer overlying the second dielectric layer;

providing a pattern to selectively remove the first barrier layer, the first and second dielectric layers and the storage material layer from all areas except above the first area of the substrate;

forming a third dielectric layer overlying the second area of the substrate and overlying the first barrier layer above the first area of the substrate;

forming a fourth dielectric layer overlying the third dielectric layer above the first area of the substrate and the second area of the substrate;

forming a second barrier layer overlying the fourth dielectric layer;

selectively removing the second barrier layer, the third dielectric and the fourth dielectric everywhere except overlying the second area of the substrate;

removing the first barrier layer overlying the first area of the substrate and removing the second barrier layer overlying the second area of the substrate;

forming a conductive gate layer overlying the second dielectric in the first area of the substrate and overlying the fourth dielectric in the second area of the substrate;

patterning gate stacks of transistors in the first area of the substrate and a reference gate stack in the second area of the substrate; and

forming current electrode regions in the first area of the substrate and the second area of the substrate to form memory cells in the first area of the substrate and a reference transistor in the second area of the substrate.

2. The process of claim 1 wherein forming the storage material layer further comprises forming a layer of nanoclusters.

3. The process of claim 2 wherein the forming of nanoclusters further comprises forming dots comprising at least one of silicon, nitride, germanium, silver, platinum, gold, tungsten, and tantalum that are spaced apart at least in some regions so as to not be in direct contact.

4. The process of claim 1 further comprising:

identifying a third area of the substrate to form other circuitry for communication with the nonvolatile memory.

5. The process of claim 1 further comprising:

implementing the first area of the substrate in a first well region having a first doping concentration;

implementing the second area of the substrate in a second well region having a second doping concentration; and

implementing the first doping concentration to be substantially equal to the second doping concentration.

6. The process of claim 1 further comprising:

implementing the first area of the substrate in a first well region having a first doping concentration;

implementing the second area of the substrate in a second well region having a second doping concentration; and

implementing the first doping concentration to be different from the second doping concentration.

7. A process for forming a nonvolatile memory comprising:

providing a substrate having a first region for a memory army and a second region for a reference transistor;

forming a plurality of memory cell transistors in the first region of the substrate, each of the plurality of memory cell transistors comprising a gate stack structure comprising a gate dielectric and a layer of storage material having a predetermined height; and

forming the reference transistor in the second region of the substrate, the reference transistor having a reference transistor gate stack structure comprising a first dielectric layer and a second dialectic layer, the first dielectric and the second dielectric collectively permitting the threshold voltage of the reference transistor to vary with respect to program and erase operations of the nonvolatile memory over time.

8. The process of claim 7 further comprising:

implementing the first dielectric layer and the second dielectric layer with a material of substantially a same composition but formed by differing formation methods.

9. The process of claim 7 further comprising:

implementing the first dielectric layer and the second dielectric layer with materials of differing composition.

10. The process of claim 7 further comprising:

implementing the layer of storage material within the plurality of memory cell transistors by providing nanocrystals that have at least some regions where the nanocrystals are physically spaced apart.

11. The process of claim 7 further comprising:

implementing the reference transistor so that the first dielectric layer and the second dielectric layer collectively have a height substantially equal to the predetermined height.

Assignments (22)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
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From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
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CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
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SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
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To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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SECURITY AGREEMENT Recorded Nov 6, 2013
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To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SECURITY AGREEMENT Recorded May 13, 2010
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To: CITIBANK, N.A., AS COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Feb 2, 2007
From: FREESCALE SEMICONDUCTOR, INC.; FREESCALE ACQUISITION CORPORATION; FREESCALE ACQUISITION HOLDINGS CORP.; FREESCALE HOLDINGS (BERMUDA) III, LTD.
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From: MOTOROLA, INC
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ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2003
From: CHINDALORE, GOWRISHANKAR L.; RAO, RAJESH A.; YATER, JANE A.
To: MOTOROLA, INC.
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