IP Library Granted Patent US 6,986,974
Granted Patent B2
US 6,986,974 · App. 10/688,589 · Granted Jan 17, 2006

Attenuated phase shift mask for extreme ultraviolet lithography and method therefore

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Quick Facts
Patent No.
US 6,986,974
App. No.
10/688,589
Granted
Jan 17, 2006
Kind
B2
Abstract

Methods and apparatus are provided for extreme ultraviolet phase shift masks. The apparatus comprises a substrate, a reflectance region, and an attenuating phase shifter. The reflectance region overlies the substrate. The attenuating phase shifter overlies the reflectance region. The attenuating phase shifter includes a plurality of openings that expose portions of the reflectance region. The attenuating phase shifter attenuates radiation through a combination of absorption and destructive interference. The method comprises projecting radiation having a wavelength less than 40 nanometers towards a mask having a plurality of openings through an attenuating phase shifter. The plurality of openings expose a reflectance region in the mask. The attenuating phase shifter is less than 700 angstroms thick. Radiation impinging on the reflectance region exposed by said plurality of openings is reflected whereas radiation impinging on the attenuating phase shifter is attenuated and shifted in phase. The attenuating phase shifter attenuates using absorption and destructive interference.

Claims (48)

1. An extreme ultraviolet (EUV) lithographic mask comprising:

a substrate;

a first reflectance region overlying said substrate; and

an attenuating phase shifter overlying said first reflectance region and comprised of a first layer, and a second layer having a second reflectance region formed therebetween, the first layer having a thickness selected to alter the phase relationship between the first reflectance region and the second reflectance region resulting in destructive interference between a reflection from the first reflectance region and a reflection from the second reflectance region, wherein a plurality of openings through said attenuating phase shifter expose portions of said first reflectance region and wherein said attenuating phase shifter attenuates EUV radiation through a combination of absorption and destructive interference.

2. The extreme ultraviolet (EUV) lithographic mask as recited in claim 1 wherein said attenuating phase shifter comprises:

an embedded layer overlying said first reflectance region;

a second reflectance region overlying said embedded layer; and

an absorber layer overlying said embedded layer.

3. The extreme ultraviolet (EUV) lithographic mask as recited in claim 2 wherein said embedded layer is an etch stop for etching said plurality of openings through said attenuating phase shifter.

4. The extreme ultraviolet (EUV) lithographic mask as recited in claim 3 wherein said embedded layer is optically tuned for destructive interference to attenuate EUV thereby minimizing a stack height of said embedded layer, said second reflectance region, and said absorber layer.

5. The extreme ultraviolet (EUV) lithographic mask as recited in claim 4 wherein said first and second reflectance regions comprise multilayer thin films for reflecting EUV radiation.

6. The extreme ultraviolet (EUV) lithographic mask as recited in claim 5 wherein said first and second reflectance regions comprise alternating thin film layers of molybdenum and silicon.

7. The extreme ultraviolet (EUV) lithographic mask as recited in claim 6 wherein a period of said first and second reflectance region has a thickness approximately equal to a half of the wavelength of EUV radiation that is directed at the EUV lithographic mask for patterning a semiconductor substrate.

8. The extreme ultraviolet (EUV) lithographic mask as recited in claim 4 wherein said embedded layer comprises NiFe.

9. The extreme ultraviolet (EUV) lithographic mask as recited in claim 4 wherein said absorber layer comprises TaN.

10. The extreme ultraviolet (EUV) lithographic mask as recited in claim 4 wherein said substrate comprises LTEM (low thermal expansion material).

11. The extreme ultraviolet (EUV) lithographic mask as recited in claim 4 wherein a total stack height of said embedded layer, said second reflectance region, and said absorber layer is less than 700 angstroms.

12. The extreme ultraviolet (EUV) lithographic mask as recited in claim 11 wherein EUV radiation reflected from said embedded layer, said second reflectance region, and said absorber layer is phase shifted approximately 180 degrees out of phase to EUV radiation reflected from said first reflectance region.

13. The extreme ultraviolet (EUV) lithographic mask as recited in claim 12 wherein said embedded layer comprises a layer of NiFe approximately 27 angstroms thick.

14. The extreme ultraviolet (EUV) lithographic mask as recited in claim 13 wherein said absorber layer comprises approximately 292 angstroms of TaN and wherein said second reflectance region comprises 7 periods of molybdenum and silicon.

15. A method of manufacturing an integrated circuit comprising the steps of:

projecting radiation having a wavelength less than 40 nanometers towards a mask having a plurality of openings through an attenuating phase shifter, said plurality of openings expose a reflectance region in said mask wherein said attenuating phase shifter is less than 700 angstroms thick;

reflecting radiation impinging on said reflectance region exposed by said plurality of openings; and

attenuating and phase shifting radiation impinging on said attenuating phase shifter wherein said attenuating phase shifter attenuates radiation through destructive interference and absorption, said attenuating phase shifter overlying said first reflectance region and comprised of a first layer, and a second layer having a second reflectance region formed therebetween, the first layer having a thickness selected to alter the phase relationship between the first reflectance region and the second reflectance region resulting in destructive interference between a reflection from the first reflectance region and a reflection from the second reflectance region.

16. The method of manufacturing an integrated circuit as recited in claim 15 further including a step of directing radiation reflected from said mask to a semiconductor wafer.

17. The method of manufacturing an integrated circuit as recited in claim 16 wherein said step of attenuating and phase shifting radiation impinging on said attenuating phase shifter wherein said attenuating phase shifter attenuates radiation through destructive interference and absorption further includes a step of using an approximately 27 angstrom layer of NIFe in said attenuating phase shifter to destructively interfere with radiation impinging thereon.

18. The method of manufacturing an integrated circuit as recited in claim 16 further including the steps of:

exposing photoresist on a surface of said semiconductor wafer with radiation reflected from said mask;

removing some of said photoresist corresponding to photoresist exposed by radiation reflected from said mask to form a pattern of photoresist on said surface of said semiconductor wafer; and

using said pattern of photoresist to form devices and interconnect of the integrated circuit.

19. The method of manufacturing an integrated circuit as recited in claim 15 wherein said step of attenuating and phase shifting radiation impinging on said attenuating phase shifter wherein said attenuating phase shifter attenuates radiation through destructive interference and absorption further includes a step of providing an attenuating phase shifter comprising an embedded layer, a second reflectance region, and an absorber layer.

20. The method of manufacturing an integrated circuit as recited in claim 19 further including a step of using said embedded layer as an etch stop for etching said plurality of openings through said attenuating phase shifter.

21. The method of manufacturing an integrated circuit as recited in claim 19 further including a step of using a multilayer thin film for said second reflectance region.

22. The method of manufacturing an integrated circuit as recited in claim 19 using alternating layers of molybdenum and silicon in said second reflectance region.

23. The method of manufacturing an integrated circuit as recited in claim 19 using a period in said reflectance region and said second reflectance region substantially equal to a half of the wavelength of the projected EUV radiation.

24. The method of manufacturing an integrated circuit as recited in claim 19 further including the step of shifting EUV radiation reflected from said attenuating phase shifter 180 degrees out of phase with EUV radiation reflected from said reflectance region.

25. The method of manufacturing an integrated circuit as recited in claim 15 further including a step of supporting said reflectance region and said attenuating phase shifter with a low thermal expansion substrate.

26. The method of manufacturing an integrated circuit as recited in claim 19 further including a step of using 7 periods of molybdenum and silicon as said second reflectance region.

27. The method of manufacturing an integrated circuit as recited in claim 19 further including the step of using a layer of TaN approximately 292 angstroms thick as said absorber layer.

28. A method of forming an extreme ultraviolet (EUV) mask for reflecting radiation having a wavelength less than 40 nanometers comprising the steps of:

providing a substrate;

forming a first reflectance region overlying said substrate;

forming an attenuating phase shifter overlying said first reflectance region wherein said attenuating phase shifter attenuates EUV radiation through a combination of destructive interference and absorption and wherein said attenuating phase shifter is less than 700 angstroms thick, said attenuating phase shifter comprised of a first layer, and a second layer having a second reflectance region formed therebetween, the first layer having a thickness selected to alter the phase relationship between the first reflectance region and the second reflectance region resulting in destructive interference between a reflection from the first reflectance region and a reflection from the second reflectance region; and

forming a plurality of openings through said attenuating phase shifter to expose said first reflectance region.

29. The method of forming an extreme ultraviolet (EUV) mask as recited in claim 28 wherein said step of forming an attenuating phase shifter overlying said first reflectance region wherein said attenuating phase shifter attenuates EUV radiation through a combination of destructive interference and absorption and wherein said attenuating phase shifter is less than 700 angstroms thick further includes the steps of:

forming an embedded layer overlying said first reflectance region, said embedded layer being tuned to destructively interfere with EUV radiation;

forming a second reflectance region overlying said embedded layer; and

forming an absorber layer overlying said second reflectance region wherein said embedded layer acts as an etch stop when forming said plurality of openings.

Assignments (22)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE LISTED CHANGE OF NAME SHOULD BE MERGER AND CHANGE PREVIOUSLY RECORDED AT REEL: 040652 FRAME: 0180. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Jan 12, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 041354/0148 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 13, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024397/0001 →
SECURITY AGREEMENT Recorded Feb 2, 2007
From: FREESCALE SEMICONDUCTOR, INC.; FREESCALE ACQUISITION CORPORATION; FREESCALE ACQUISITION HOLDINGS CORP.; FREESCALE HOLDINGS (BERMUDA) III, LTD.
To: CITIBANK, N.A. AS COLLATERAL AGENT
Reel/Frame 018855/0129 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 7, 2004
From: MOTOROLA, INC
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 015360/0718 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 16, 2003
From: HAN, SANG-IN; HECTOR, SCOTT D.; MANGAT, PAWITTER
To: MOTOROLA, INC.
Reel/Frame 014625/0594 →