Low-temperature, low-resistivity heavily doped p-type polysilicon deposition
View Patent ↗A method to create a low resistivity P+in-situ doped polysilicon film at low temperature from SiH 4 and BCl 3 with no anneal required. At conventional dopant concentrations using these source gases, as deposition temperature decreases below about 550 degrees C., deposition rate decreases and sheet resistance increases, making production of a high-quality film impossible. By flowing very high amounts of BCl 3 , however, such that the concentration of boron atoms in the resultant film is about 7×10 20 or higher, the deposition rate and sheet resistance are improved, and a high-quality film is produced.
1. A method for depositing a doped polysilicon film comprising:
providing a surface; and
substantially simultaneously flowing SiH 4 and BCl 3 over the surface at a temperature between about 460 and about 500 degrees Celsius under conditions that achieve an average concentration in the doped polysilicon film of between about 7×10 20 and about 3 ×10 21 boron atoms per cubic centimeter, wherein the doped polysilicon film is polycrystalline as deposited.
2. The method of claim 1 wherein the temperature is less than or about 480 degrees Celsius.
3. The method of claim 2 wherein pressure is between about 200 mTorr and about 1 Torr.
4. The method of claim 3 wherein an inert gas is flowed over the surface with the SiH 4 and BCl 3.
5. The method of claim 4 wherein the inert gas is helium.
6. The method of claim 1 , wherein the resistivity of the doped polysilicon film is at least about 200 ohms/square and less than about 280 ohms/square.
7. A method for forming an in-situ doped polysilicon film, the method comprising:
providing a surface; and
substantially simultaneously flowing a first source gas comprising SiH 4 and a second source gas comprising BCl 3 over the surface at a temperature between about 460 and about 500 degrees Celsius under conditions sufficient to achieve in the doped polysilicon an average concentration of between about 7×10 20 and about 3×10 21 boron atoms per cubic centimeter, wherein during this flowing step, polycrystalline silicon is deposited.
8. The method of claim 7 , wherein the second source gas comprises about 0.1 percent BCl 3 or more.
9. The method of claim 8 , wherein the second source gas further comprises an inert gas.
10. The method of claim 9 , wherein the temperature is less then or about 480 degrees Celsius.
11. The method of claim 10 , wherein the inert gas is helium.
12. The method of claim 9 , wherein the pressure is between about 200 mTorr and about 1 Torr.
13. The method of claim 7 , wherein the resistivity of the doped polysilicon is at least about 200 ohms/square and less than about 280 ohms/square.
14. A method for depositing an in-situ doped polysilicon film comprising:
providing a substrate comprising a substantially horizontal surface and a substantially vertical sidewall descending from the horizontal surface, the sidewall having a top; and
depositing the in-situ doped polysilicon film on the surface at a temperature between about 460 and about 500 degrees Celsius, wherein:
a first thickness of the film at its thinnest point on the vertical sidewall is at least 80 percent of a second thickness of the film on the sidewall at the top of the sidewall, and
a third thickness of the film on the horizontal surface is at least 200 angstroms,
wherein an average concentration of boron atoms in the polysilicon is between about 7×10 20 and about 3×10 21 per cubic centimeter,
and wherein, during the depositing step, doped polycrystalline silicon is deposited.
15. The method of claim 14 wherein the step of depositing the polysilicon film comprises substantially simultaneously flowing SiH 4 and BCl 3 over the surface.
16. The method of claim 15 wherein the temperature is less than or about 480 degrees Celsius.
17. The method of claim 16 wherein the pressure is between 200 mTorr and 1 Torr.
18. The method of claim 14 , wherein the resistivity of the doped polysilicon is at least about 200 ohms/square and less than about 280 ohms/square.