Fuel cell with a device for storing water
View Patent ↗A fuel cell system with flow passages and/or flow chambers which conduct moist gases in operation is characterized in that at least a part of the flow passages and/or flow chambers is provided with a coating which takes up water in distributed form at low temperatures and releases the water again at least in part at higher temperatures. This coating makes it possible to operate the fuel cell system at pronounced temperatures below zero, such as, for example, −40° C., and to ensure an adequate humidification of the operating gases, which protects the membranes from damage and favors a faster starting up of the fuel cell system.
1. A fuel cell system comprising flow passages and/or flow chambers which are formed in a bipolar plate of a fuel cell and which conduct moist gases in operation, and wherein at least a part of the flow passages and/or flow chambers which are formed in the bipolar plate of the fuel cell are provided with a coating which, at low temperatures, takes up water in distributed form and releases the water at least in part again at higher temperatures.
2. A fuel cell system in accordance with claim 1 , wherein the coating is a silicate with the general formula:
X 12 [(AlO 2 ) 12 (SiO 2 ) 12 ].x H 2 O
or X 12 (AlSi 12 O 24 ). x H 2 O
or X 43 (Al 43 Si 83 O 24 ). x H 2 O
or X 28 (Al 28 Si 68 O 96 ). x H 2 O
where X=Li, Na, K, Rb, or Cs and x is an integer and the water is taken up in the pores of the coating.
3. A fuel cell system in accordance with claim 1 , wherein the coating is a silicate with the general formula:
Y 6 [(AlO 2 ) 12 (SiO 2 ) 12 ].x H 2 O, where Y=Be, Mg, Ca, Sr, or Ba,
and x is an integer and the water is taken up in the pores of the coating.
4. A fuel cell system in accordance with claim 1 , wherein the coating comprises alkaline and alkaline earth aluminum silicates.
5. A fuel cell system in accordance with claim 1 , wherein the coating comprises polysiloxane.
6. A fuel cell system in accordance with claim 1 , wherein the coating comprises a polymer which is provided with acid radicals or alkaline radicals which have a chemical affinity for water.
7. A fuel cell system in accordance with claim 6 , wherein the polymer is a modified polyethylene glycol.
8. A fuel cell system in accordance with claim 1 , wherein the coating is present on said flow passages and/or flow chambers which are formed in the bipolar plate of the fuel cell and which define an anode side of said fuel cell system.
9. A fuel cell system in accordance with claim 1 , wherein the coating is located on said flow passages and/or flow chambers which are formed in the bipolar plate of the fuel cell and which define a cathode side of said fuel cell system.
10. A fuel cell system in accordance with claim 2 in which the pores of the coating have sizes in the range of 0.1 nm to 12 nm.
11. A fuel cell system in accordance with claim 3 in which the pores of the coating have sizes in the range of 0.1 nm to 12 nm.
12. A fuel cell system in accordance with claim 1 in which the coating is present at base surfaces and side surfaces of the flow passages and/or flow chambers which are formed in the bipolar plate.