Thermosetting resin composition for high performance laminates
View Patent ↗This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as the prepregs, laminates and composites made from the thermosetting resin composition.
1. A thermosetting resin composition comprising:
at least one elastomer selected from the group consisting of a styrene-butadiene-divinylbenzene terpolymer, a maleinized polybutadiene styrene copolymer, and mixtures thereof;
from about 2 to about 8 wt % of at least one ester; and
at least one flame retardant,
wherein the at least one ester includes about 0% free styrene.
2. The composition of claim 1 wherein the at least one elastomer comprises from about 20 wt % to about 60 wt %; and the at least one flame retardant comprises from about 5 wt % to about 50 wt %, each as a percentage of the composition solids content.
3. The composition of claim 1 wherein the at least one ester is an unsaturated ester.
4. The composition of claim 3 wherein the unsaturated ester is an unsaturated polyester.
5. The composition of claim 1 further comprising at least one catalyst.
6. The composition of claim 5 wherein the at least one catalyst is a peroxide catalyst.
7. The composition of claim 6 wherein the at least one catalyst is selected from dicumyl peroxide, tert-butyl peroxbenzoate, and mixtures thereof.
8. The composition of claim 5 wherein the at least one catalyst comprises about 2 wt % to about 8 wt % as a percentage of the composition solids content.
9. The composition of claim 1 wherein the at least one flame retardant is decabromodiphenylethane.
10. The composition of claim 1 further comprising at least one filler selected from the group consisting of teflon, talc, quartz, ceramics, particulate metal oxides, silica, titanium dioxide, alumina, ceria, clay, boron nitride, wollastonite, and mixtures thereof.
11. The composition of claim 10 wherein the filler comprises about 5% to about 40% as a percentage of the composition solids content.
12. The composition of claim 10 wherein the filler is silane treated fused silica.
13. A prepreg comprising the thermosetting resin composition of claim 1 and a core material.
14. The prepreg of claim 13 wherein the core material comprises a woven glass web.
15. A prepreg comprising a sheet of partially cured thermosetting resin of claim 1 .
16. The prepreg of claim 15 wherein the coefficient of thermal expansion 0-100° C. is from 25-30 ppm/m/° C.
17. A thermosetting resin composition comprising:
a polybutadiene styrene divinylbenzene terpolymer;
from about 2 wt % to about 4 wt % of an unsaturated polyester;
decabromodiphenylethane;
fused silica; and
dicumyl peroxide, wherein the unsaturated polyester includes about 0% free styrene.
18. The composition of claim 17 wherein the terpolymer comprises from about 30 wt % to about 35 wt %; the decabromodiphenylethane comprises from about 20 wt % to about 25 wt %; the fused silica comprises from about 32 wt % to about 38 wt %; and the dicumyl peroxide comprises from about 5 wt % to about 6 wt %, each as a percentage of the composition solids content.