Reforming diesel fuel for NOx reduction
View Patent ↗The selective catalytic reduction of nitrogen oxides (especially NO and NO 2 ) in exhaust from diesel and other lean burn engines is improved by use of a compact hyperplasma reactor for generating ozone and other highly oxidizing species in a stream of air. A portion of the ozone containing air stream is blown directly into the exhaust for oxidizing NO to NO 2 . The other portion of plasma treated air is used to fractionate and reform a volume of diesel fuel to produce low molecular weight hydrocarbons and oxidized hydrocarbons to be added to the exhaust as NO 2 reductants in the catalytic reduction.
1. A method of reducing nitrogen oxides, including NO and NO 2 , in an exhaust stream at a temperature above about 150° C., said method comprising:
flowing ambient air through a nonthermal plasma reactor to generate a plasma reactor output stream comprising oxidizing constituents, including ozone, and residual air constituents;
bubbling at least a portion of the plasma reactor output stream through a volume of liquid diesel fuel to strip a vapor portion of diesel fuel hydrocarbons from the liquid volume into the plasma reactor output stream and to produce a fractionated and reformed diesel fuel containing stream comprising hydrogen-carbon-oxygen containing molecules;
adding the fractionated and reformed diesel fuel containing stream to said exhaust stream for the reduction of said nitrogen oxides.
2. A method of reducing nitrogen oxides as recited in claim 1 , the method further comprising:
adding a portion of the plasma reactor output stream to the exhaust stream for oxidation of NO to NO 2 , the ozone containing plasma being added to the exhaust stream separately from said fractionated and reformed diesel fuel-containing stream.
3. A method of reducing nitrogen oxides as recited in claim 1 , the method further comprising:
adding a portion of the plasma reactor output stream to the exhaust stream for oxidation of NO to NO 2 , the ozone containing plasma being added to the exhaust stream separately from the fractionated and reformed diesel fuel-containing stream; and, thereafter contacting the exhaust stream with a reduction catalyst for nitrogen oxides.
4. A method of reducing nitrogen oxides as recited in claim 1 further comprising:
adding a portion of the plasma reactor output stream to the exhaust stream for oxidation of NO to NO 2 , the ozone-containing plasma being added to the exhaust stream separately from the fractionated and reformed diesel fuel-containing stream; and, thereafter
contacting the exhaust stream with a dual-bed reduction catalyst comprising NaY zeolite and/or BaY zeolite in the first bed and CuY zeolite in the second bed to reduce the nitrogen oxides to N 2 .
5. A method of reducing nitrogen oxides as recited in claim 1 wherein the non-thermal plasma reactor is a tubular vessel having a reactor space therein for flow-through passage of air, the plasma reactor comprising a high voltage electrode disposed within said reactor space and a ground electrode helically coiled around said tubular vessel in a discretely spaced pattern, thereby providing intertwined helical passive and active electric fields for the generation of the plasma reactor output stream.
6. A method of reducing nitrogen oxides, including NO and NO 2 , in an exhaust stream from a diesel engine at a temperature above about 150° C., the method comprising:
flowing ambient air through a nonthermal plasma reactor to generate a plasma reactor output stream comprising oxidizing constituents including ozone, and residual air constituents;
adding a first portion of said plasma reactor output stream to the exhaust stream for oxidation of NO to NO 2 ;
bubbling a second portion of the plasma reactor output stream through a volume of liquid diesel fuel to strip a vapor portion of diesel fuel hydrocarbons from the liquid volume into the plasma reactor output stream and to produce a fractionated and reformed diesel fuel containing stream comprising hydrogen-carbon-oxygen containing molecules;
adding the fractionated and reformed diesel fuel containing stream to said exhaust stream for the reduction of said nitrogen oxides separately from the addition of the first portion of said plasma reactor output stream to the exhaust stream; and, thereafter
contacting said exhaust stream with a reduction catalyst for nitrogen oxides.
7. A method of reducing nitrogen oxides as recited in claim 6 further comprising:
contacting the exhaust stream with a dual-bed reduction catalyst comprising NaY zeolite and/or BaY zeolite in the first bed and CuY zeolite in the second bed to reduce said nitrogen oxides to N 2 .
8. A method of reducing nitrogen oxides as recited in claim 6 wherein the non-thermal plasma reactor is a tubular vessel having a reactor space therein for flow-through passage of air, the plasma reactor comprising a high voltage electrode disposed within said reactor space and a ground electrode helically coiled around said tubular vessel in a discretely spaced pattern, thereby providing intertwined helical passive and active electric fields for the generation of the plasma reactor output stream.
9. A method of reducing nitrogen oxides, including NO and NO 2 , in an exhaust stream from a diesel engine for powering a vehicle, the exhaust being at a temperature above about 150° C., the method comprising:
blowing ambient air through a tubular non-thermal plasma reactor to generate a plasma reactor output stream comprising oxidizing constituents including ozone, and residual air constituents;
bubbling a first portion of the plasma reactor output stream through a volume of liquid diesel fuel to strip a vapor portion of diesel fuel hydrocarbons from the liquid volume into the plasma reactor output stream and to produce a fractionated and reformed diesel fuel containing stream comprising hydrogen-carbon-oxygen containing molecules;
adding the fractionated and reformed diesel fuel containing stream to said exhaust stream for the reduction of said nitrogen oxides
adding a second portion of said plasma reactor output stream to said exhaust stream for oxidation of NO to NO 2 , said ozone containing plasma being added to said exhaust stream separately from, and prior to, the addition of the fractionated and reformed diesel fuel containing stream; and, thereafter
contacting said exhaust stream with a reduction catalyst for nitrogen oxides.
10. A method of reducing nitrogen oxides as recited in claim 9 comprising:
contacting said exhaust stream with a dual bed reduction catalyst comprising NaY zeolite and/or BaY zeolite in the first bed and CuY zeolite in the second bed to reduce said nitrogen oxides to N 2 .
11. A method of reducing nitrogen oxides as recited in claim 9 wherein the non-thermal plasma reactor is a tubular vessel having a reactor space therein for flow-through passage of air, the plasma reactor comprising a high voltage electrode disposed within said reactor space and a ground electrode helically coiled around said tubular vessel in a discretely spaced pattern, thereby providing intertwined helical passive and active electric fields for the generation of the plasma reactor output stream.