IP Library Granted Patent US 7,309,652
Granted Patent B2
US 7,309,652 · App. 11/146,538 · Granted Dec 18, 2007

Method for removing photoresist layer and method for forming metal line in semiconductor device using the same

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Quick Facts
Patent No.
US 7,309,652
App. No.
11/146,538
Granted
Dec 18, 2007
Kind
B2
Abstract

Disclosed are a method for removing a photoresist layer and a method for forming a metal line using the same. The method for removing a photoresist pattern, including the steps of: forming a bottom layer on a substrate by using the photoresist pattern as a mask; and removing the photoresist pattern with use of a high density plasma (HDP) apparatus. The method for forming a metal line, including the steps of: preparing a semi-finished substrate including an inter-layer insulation layer; forming a photoresist pattern on the inter-layer insulation layer; forming an opening by etching the inter-layer insulation layer with use of the photoresist pattern as an etch mask; removing the photoresist pattern by using a high density plasma (HDP) apparatus; and forming the metal line by filling the opening with a predetermined material.

Claims (24)

1. A method for removing a photoresist pattern, comprising the steps of:

forming a bottom layer on a substrate by using the photoresist pattern as a mask, wherein the bottom layer is a low-k dielectric layer; and

removing the photoresist pattern with use of a high density plasma (HDP) apparatus by applying a source power ranging from approximately 2,000 W to approximately 2,500 W and a bias power less than approximately 300 W.

2. The method as recited in claim 1 , wherein the HDP apparatus is an inductively coupled plasma reactor.

3. The method as recited in claim 1 , wherein a temperature of an inner chamber of the HDP apparatus is maintained in a range from approximately −20° C. to approximately 200° C.

4. The method as recited in claim 1 , wherein a plasma density of the HDP apparatus ranges from approximately 5×10 8 /cm 3 to 5×10 13 /cm 3 .

5. The method as recited in claim 1 , wherein the photoresist pattern is removed under a pressure ranging from approximately 1 mmtorr to approximately 1,000 mmtorr.

6. The method as recited in claim 1 , wherein the photoresist pattern is removed by using a gas containing at least one selected from oxygen (O 2 ), nitrogen (N 2 ) and hydrogen (H 2 ).

7. The method as recited in claim 1 , wherein the low-k dielectric layer obtained as one of a silicon oxide (SiO)-based material and a silicon dioxide (SiO 2 )-based material locally including one of a substitutional substance and an interstitial substance selected from the group consisting of fluorine (F), hydrogen (H), carbon (C), methyl (CH 3 ), silicon (Si) and phosphorus (P).

8. The method as recited in claim 7 , wherein the SiO-based material and the SiO 2 -based material have a dielectric constant ranging from approximately 1.5 to approximately 4.5.

9. The method as recited in claim 1 , wherein the HDP apparatus increases a removal rate of the photoresist pattern by attracting plasma ions generated inside the chamber in one direction through using one of an electric field and a magnetic field.

10. The method as recited in claim 9 , wherein the magnetic field ranges from approximately 1 Gauss to approximately 200 Gauss.

11. The method as recited in claim 1 , wherein the step of removing the photoresist pattern includes the steps of: removing the photoresist pattern; and loading the substrate in which the photoresist pattern is removed into the chamber of the HDP apparatus and performing a HDP dry etching process, thereby removing remnants remaining on the bottom layer during the removal of the photoresist pattern.

12. The method as recited in claim 1 , wherein the bottom layer is an impurity-doped layer by performing an ion implantation process.

13. A method for forming a metal line, comprising the steps of:

preparing a semi-finished substrate including an inter-layer insulation layer;

forming a photoresist pattern on the inter-layer insulation layer;

forming an opening by etching the inter-layer insulation layer with use of the photoresist pattern as an etch mask;

removing the photoresist pattern through the use of a high density plasma (HDP) apparatus by applying a source power ranging from approximately 2,000 W to approximately 2,500 W and a bias power less than approximately 300 W; and

forming the metal line by filling the opening with a predetermined material.

14. The method as recited in claim 13 , wherein the inter-layer insulation layer is formed by employing a low-k dielectric layer obtained as one of a silicon oxide (SiO)-based material and a silicon dioxide (SiO 2 )-based material locally including one of a substitutional substance and an interstitial substance selected from a group consisting of fluorine (F), hydrogen (H), carbon (C), methyl (CH 3 ), silicon (Si) and phosphorus (P).

15. The method as recited in claim 14 , wherein the SiO-based material and the SiO 2 -based material have a dielectric constant ranging from approximately 1.5 to approximately 4.5.

16. The method as recited in claim 13 , further including the step of forming one of a capping layer and an anti-reflective coating layer on the inter-layer insulation layer prior to forming the photoresist pattern.

17. The method as recited in claim 16 , wherein the capping layer is based on a material selected from a group consisting of SiO 2 , SiC, SiN(Si 3 N 4 ), SiOC, SiOCH and SiON and the anti-reflective coating layer is based on an organic material.

Assignments (6)
CHANGE OF NAME Recorded Mar 12, 2024
From: KEY FOUNDRY CO., LTD.
To: SK KEYFOUNDRY INC.
Reel/Frame 066794/0290 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2020
From: MAGNACHIP SEMICONDUCTOR, LTD.
To: KEY FOUNDRY CO., LTD.
Reel/Frame 053703/0227 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY ADDRESS PREVIOUSLY RECORDED AT REEL: 024563 FRAME: 0807. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE BY SECURED PARTY. Recorded Nov 25, 2014
From: US BANK NATIONAL ASSOCIATION
To: MAGNACHIP SEMICONDUCTOR LTD.
Reel/Frame 034469/0001 →
RELEASE OF SECURITY INTEREST Recorded Jun 22, 2010
From: U.S. BANK NATIONAL ASSOCIATION
To: MAGNACHIP SEMICONDUCTOR LTD.
Reel/Frame 024563/0807 →
AFTER-ACQUIRED INTELLECTUAL PROPERTY KUN-PLEDGE AGREEMENT Recorded Feb 18, 2009
From: MAGNACHIP SEMICONDUCTOR, LTD.
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 022277/0133 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2005
From: RYU, SANG-WOOK
To: MAGNACHIP SEMICONDUCTOR, LTD.
Reel/Frame 016660/0646 →