IP Library Granted Patent US 7,402,477
Granted Patent B2
US 7,402,477 · App. 11/393,563 · Granted Jul 22, 2008

Method of making a multiple crystal orientation semiconductor device

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,402,477
App. No.
11/393,563
Granted
Jul 22, 2008
Kind
B2
Abstract

A method of having transistors formed in enhanced performance crystal orientations begins with a wafer having a semiconductor substrate ( 12,52 ) of a first surface orientation, a thin etch stop layer ( 14,54 ) on the semiconductor substrate, a buried oxide layer ( 16,56 ) on the thin etch stop layer, and a semiconductor layer ( 18,58 ) of a second surface orientation on the buried oxide layer. An etch penetrates to the thin etch stop layer. Another etch, which is chosen to minimize the damage to the underlying semiconductor substrate, exposes a portion of the semiconductor substrate. An epitaxial semiconductor ( 28,66 ) is then grown from the exposed portion of the semiconductor substrate to form a semiconductor region having the first surface orientation and having few, if any, defects. The epitaxially grown semiconductor region is then used for enhancing one type of transistor while the semiconductor layer of the second surface orientation is used for enhancing a different type of transistor.

Claims (61)

1. A method of making a semiconductor device structure, comprising:

providing a semiconductor substrate comprising:

a first semiconductor layer having a first surface orientation;

a first dielectric layer over the first semiconductor layer, wherein the first dielectric layer comprises a high K dielectric;

a second dielectric layer over the first dielectric layer; and

a second semiconductor layer over the second dielectric layer, wherein the second semiconductor layer has a second surface orientation;

performing a patterned etch through the second semiconductor layer and the second dielectric layer to form an opening in the second semiconductor layer and the second dielectric layer, wherein:

the patterned etch is stopped on the first dielectric layer; and

the patterned etch comprises a first etch type;

etching through the first dielectric layer to the first semiconductor layer using a second etch type whereby the first semiconductor layer has an exposed portion at the opening;

epitaxially growing a semiconductor region of the first surface orientation from the exposed portion into the opening;

forming a transistor of the first type in the semiconductor region;

forming a transistor of the second type in the second semiconductor layer.

2. The method of claim 1 , wherein:

the first dielectric layer has a first thickness;

the second dielectric layer has a second thickness; and

the second thickness is at least five times greater than the first thickness.

3. The method of claim 1 , wherein the second etch type comprises a hot gas that contains chlorine.

4. The method of claim 3 , wherein the second etch type is further characterized as being hydrochloric acid.

5. The method of claim 4 , wherein the second etch type is further characterized as applying the hot gas at a temperature of at least 500 degrees Celsius.

6. The method of claim 1 , wherein the second etch type etches the first dielectric layer at a significantly greater rate than the first semiconductor layer, the second dielectric layer, and the second semiconductor layer.

7. The method of claim 1 , further comprising, prior to the step of etching through the first dielectric layer, the following steps:

filling the opening with an insulating material; and

pattern etching through the insulating material to leave a portion of the insulating material along a perimeter of the opening for providing isolation between the first transistor and the second transistor.

8. The method of claim 1 , further comprising forming an antireflective coating over the insulating material prior to pattern etching through the insulating material.

9. The method of claim 1 , further comprising:

forming a sidewall spacer along a perimeter of the opening prior to the step of etching through the first dielectric layer;

removing at least a first portion of the sidewall spacer; and

forming an isolation region where the first portion of the sidewall spacer was removed.

10. The method of claim 1 , wherein the first surface orientation comprises ( 110 ), the second surface orientation comprises ( 100 ), the first type of transistor comprises P channel, the second type of transistor comprises N channel, and the first semiconductor region is of a different material composition from the first semiconductor layer.

11. A method of forming a semiconductor device structure, comprising:

providing a semiconductor substrate comprising:

a first semiconductor layer having a first crystal orientation;

a first dielectric layer over the first semiconductor layer;

a second dielectric layer over the first dielectric layer, wherein the first dielectric layer comprises a high K dielectric layer that is at least five times thicker than the second dielectric layer; and

a second semiconductor layer over the second dielectric layer, wherein the second semiconductor layer has a second crystal orientation;

etching through the second semiconductor layer and the second dielectric layer whereby the first dielectric layer has an exposed portion;

etching through the first dielectric layer whereby the first semiconductor layer has an exposed portion; and

epitaxially growing a semiconductor region from the exposed portion of the first semiconductor layer.

12. The method of claim 11 , wherein:

the etching through the second dielectric layer comprises applying a fluorine-containing gas; and

the step of etching through the first dielectric layer comprises applying a chlorine-containing gas at temperature of at least 500 degrees Celsius.

13. The method of claim 11 , further comprising

forming a first transistor in the semiconductor region; and

forming a second transistor in the second semiconductor layer, wherein the second transistor is a different type from the first transistor.

14. The method of claim 11 , wherein the first crystal orientation is a surface orientation of ( 110 ) and the second crystal orientation is a surface of orientation of ( 100 ).

15. The method of claim 11 , further comprising, after etching through the second dielectric layer and prior to etching through the first dielectric layer, the following steps:

depositing an insulating material; and

pattern etching through the insulating material to the first dielectric layer to leave an opening through the insulating material for the exposed portion of the first insulating layer.

16. A method of forming a semiconductor device structure, comprising:

providing a semiconductor substrate comprising:

a first semiconductor layer having a first crystal orientation;

a first dielectric layer over the first semiconductor layer;

a second dielectric layer over the first dielectric layer; and

a second semiconductor layer over the second dielectric layer, wherein the second semiconductor layer has a second crystal orientation;

etching through the second semiconductor layer and the second dielectric layer whereby the first dielectric layer has an exposed portion;

etching through the first dielectric layer whereby the first semiconductor layer has an exposed portion; and

epitaxially growing a semiconductor region from the exposed portion of the first semiconductor layer, wherein the step of etching through the second semiconductor layer and the second dielectric layer leaves an opening, further comprising:

forming a sidewall spacer along a perimeter of the opening prior to the step of etching through the first dielectric layer;

removing at least a first portion of the sidewall spacer; and

forming an isolation region where the first portion of the sidewall spacer was removed.

Assignments (23)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE LISTED CHANGE OF NAME SHOULD BE MERGER AND CHANGE PREVIOUSLY RECORDED AT REEL: 040652 FRAME: 0180. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Jan 12, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 041354/0148 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0757 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 13, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024397/0001 →
SECURITY AGREEMENT Recorded Dec 9, 2008
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 021936/0772 →
SECURITY AGREEMENT Recorded Feb 2, 2007
From: FREESCALE SEMICONDUCTOR, INC.; FREESCALE ACQUISITION CORPORATION; FREESCALE ACQUISITION HOLDINGS CORP.; FREESCALE HOLDINGS (BERMUDA) III, LTD.
To: CITIBANK, N.A. AS COLLATERAL AGENT
Reel/Frame 018855/0129 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 30, 2006
From: SADAKA, MARIAM G.; NGUYEN, BICH-YEN; WHITE, TED R.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 017749/0584 →