Method for growing epitaxial crystal
View Patent ↗It is to provide a method for growing an epitaxial crystal in which the doping conditions are set when an epitaxial crystal having a desired carrier concentration is grown. A method for growing an epitaxial crystal while a dopant is added to a compound semiconductor substrate, comprises: obtaining a relation between an off angle and a doping efficiency with regards to the same type of compound semiconductor substrate in advance; and setting a doping condition for carrying out an epitaxial growth on the compound semiconductor substrate based on the obtained relation and a value of the off angle of the subtrate.
1. A method for growing an epitaxial crystal while a dopant is added to a compound semiconductor substrate,
wherein off angles which are measured at a plurality of positions in a plane of the compound semiconductor substrate we measured off angles and an average value thereof is an average off angle; and
wherein in case that a doping efficiency to the epitaxial crystal is constant when the average off angle of the compound semiconductor substrate is not more than a predetermined angle; and that the doping efficiency is monotonically decreased when the average off angle is larger than the predetermined angle, the method comprises:
using the same type of compound semiconductor substrate, in which an in-plane variation of the measured off angles is within a predetermined range, in advance;
obtaining at least the doping efficiency in case that the average off angle of the substrate is not more than the predetermined angle, and the doping efficiency in case that the average off angle of the substrate is larger than the predetermined angle, respectively, and establishing a relation equation between the average off angle and the doping efficiency based on the obtained average off angle and the obtained doping efficiency;
substituting an average off angle of a substrate to be used for the relation equation to calculate a doping efficiency in case of using the substrate to be used, and setting a doping condition for carrying out an epitaxial growth on the compound semiconductor substrate based on the calculated doping efficiency and the doping efficiency which is constant when the average off angle of the substrate is not more than the predetermined angle: and
wherein the average off angle is 0.01° to 10°.
2. The method for growing the epitaxial crystal as claimed in claim 1 , wherein the compound semiconductor substrate is InP and the predetermined angle is 0.10°.
3. The method for growing the epitaxial crystal as claimed in claim 1 , wherein the doping condition for achieving the epitaxial crystal having a desired carrier concentration when the substrate having a specific average off angle is used, is estimated based on the relation between the average off angle of the substrate and the doping efficiency; the epitaxial crystal is grown based on the estimated doping condition; and the doping condition in which the desired carrier concentration is achieved, is established as the doping condition in case of using the substrate having the specific average off angle.
4. The method for growing the epitaxial crystal as claimed in any one of claims 1 to 3 , wherein the relation between the off angle and the doping efficiency is obtained by using the compound semiconductor substrate having an in-plane variation in the measured off angles within ±0.03°.
5. The method for growing epitaxial crystal as claimed in any one of claims 1 to 3 , wherein the relation between the off angle and the doping efficiency is obtained by using the compound semiconductor substrate having the in-plane variation in the measured off angles within ±0.02°.
6. The method for growing epitaxial crystal as claimed in any one of claims 1 to 3 , wherein the same doping condition is applied to the substrates having the average off angle which is within ±0.03°.
7. The method as claimed in claim 1 , wherein the average off angle is 0.01° to 2°.