Pot-shaped copper sputtering target and manufacturing method thereof
View Patent ↗Provided is a pot-shaped copper sputtering target manufactured with die forging, wherein the Vickers hardness Hv at all locations of the inner surface of the pot-shaped target is 70 or greater. With this pot-shaped copper sputtering target, the average crystal grain size in the target structure is 65 μm or less. Further, the inner surface of the pot-shaped target comprises crystalline orientations of (220), (111), (200), (311) obtained by X-ray diffraction, and the crystalline orientation of the face subject to erosion of the pot-shaped target is of a (220) primary orientation. An object of the present invention is to obtain a manufacturing method of a high quality sputtering target by improving and devising the forging process and heat treatment process to make the crystal grain size refined and uniform, and to obtain a high-quality sputtering target.
1. A pot-shaped copper sputtering target manufactured with die forging, wherein Vickers hardness Hv at any location of the inner surface of the pot-shaped target is 70 or greater, wherein crystalline texture in the inner surface of the pot-shaped target comprises crystalline orientations of (220), (111), (200), (311) as measured by X-ray diffraction, and wherein a ratio of normalized XRD peak strengths of the (220) reflection to total of normalized XRD peak strengths of the (220), (111), (200) and (311) reflections in the face of the inner surface that is subject to sputtering erosion in the pot-shaped target during sputtering is 45% or greater.
2. The pot-shaped copper sputtering target according to claim 1 , wherein difference in the Vickers hardness Hv between a location of the inner surface having the lowest hardness and a location of the inner surface having the highest hardness Hv is within ±30% in comparison to the highest hardness.
3. The pot-shaped copper sputtering target according to claim 2 , wherein the average crystal grain size in the target structure is 65 μm or less.
4. The pot-shaped copper sputtering target according to claim 3 , wherein a ratio of average crystal grain size of a location of the inner surface at which the average crystal grain size is greatest to a location of the inner surface at which the average crystal grain size is smallest is less than 2.0.
5. The pot-shaped copper sputtering target according to claim 4 , wherein the crystalline texture in the face of the inner surface that is subject to sputtering erosion in the pot-shaped target during sputtering is of (220) as a primary orientation thereof.
6. The pot-shaped copper sputtering target according to claim 1 , wherein the average crystal grain size in the target structure is 65 μm or less.
7. The pot-shaped copper sputtering target according to claim 6 , wherein a ratio of average crystal grain size of a location of the inner surface at which the average crystal grain size is greatest to a location of the inner surface at which the average crystal grain size is smallest is less than 2.0.
8. The pot-shaped copper sputtering target according to claim 7 , wherein the crystalline texture in the face of the inner surface that is subject to sputtering erosion in the pot-shaped target during sputtering is of (220) as a primary orientation thereof.
9. The pot-shaped copper sputtering target according to claim 1 , wherein a ratio of average crystal grain size of a location of the inner surface at which the average crystal grain size is greatest to a location of the inner surface at which the average crystal grain size is smallest is less than 2.0.
10. The pot-shaped copper sputtering target according to claim 9 , wherein the crystalline texture in the face of the inner surface that is subject to sputtering erosion in the pot-shaped target during sputtering is of (220) as a primary orientation thereof.
11. The pot-shaped copper sputtering target according to claim 1 , wherein the crystalline texture in the face of the inner surface that is subject to sputtering erosion in the pot-shaped target during sputtering is of (220) as a primary orientation thereof.
12. A pot-shaped sputtering target consisting of copper and having an inner surface with Vickers hardness Hv at all locations thereof of 80 or greater, said pot-shaped sputtering target having a structure having been subject to die forging to form its pot-shape said inner surface having a crystalline texture comprising crystalline orientations of (220), (111), (200), (311) as measured by X-ray diffraction, and a ratio of normalized XRD peak strengths of the (220) reflection to total of normalized XRD peak strengths of the (220), (111), (200) and (311) reflections in a face of the inner surface that is subject to sputtering erosion during sputtering being 45% or greater.
13. The pot-shaped sputtering target according to claim 12 , wherein a primary orientation of the crystalline texture in the face of the inner surface that is subject to sputtering erosion is (220).
14. The pot-shaped copper sputtering target according to claim 12 , wherein a Vickers hardness Hv between a location of the inner surface having a lowest hardness is within 30% of a location of the inner surface having a highest hardness.
15. The pot-shaped copper sputtering target according to claim 14 , wherein the average crystal grain size in the target is 65 μm or less, and wherein a ratio of an average crystal grain size of a location of the inner surface at which the average crystal grain size is greatest to a location of the inner surface at which the average crystal grain size is smallest is less than 2.0.