Gate electrode silicidation process
View Patent ↗A fully-silicided gate electrode is formed from silicon and a metal by depositing at least two layers of silicon with the metal layer therebetween. One of the silicon layers may be amorphous silicon whereas the other silicon layer may be polycrystalline silicon. The silicon between the metal layer and the gate dielectric may be deposited in two layers having different crystallinities. This process enables greater control to be exercised over the phase of the silicide resulting from this silicidation process.
1. A method of fabricating a fully-silicided gate electrode layer comprising a predetermined silicide phase located at a first surface of the gate electrode layer, the method comprising:
forming at least one first layer of silicon;
forming a metal layer of a non-silicided metal;
forming an additional layer of silicon such that the metal layer is between the first layer(s) of silicon and the additional layer of silicon; and
simultaneously applying heat to the superposed first silicon layer(s), metal layer and additional silicon layer to convert said first silicon layer, said metal layer and said additional layer of silicon into a metal silicide having a predetermined metal silicide phase at a first surface thereof, said first surface being arranged for contacting a gate insulator.
2. A method of fabricating a fully-silicided gate electrode layer according to claim 1 , wherein said forming at least one first layer of silicon comprises forming a layer of polycrystalline silicon and said forming an additional layer of silicon comprises forming a layer of amorphous silicon.
3. A method of fabricating a fully-silicided gate electrode layer according to claim 2 , and comprising controlling the relative thicknesses of said metal layer and of said first and additional layers of silicon in order to control the phase of the metal silicide layer at said first surface that is formed during the heat-application.
4. A method of fabricating a fully-silicided gate electrode layer according to claim 2 , wherein said forming at least one first layer of silicon comprises forming at least two silicon layers having respective different crystallinities.
5. A method of fabricating a fully-silicided gate electrode layer according to claim 1 , comprising: controlling the relative thicknesses of said metal layer and of said first and additional layers of silicon in order to control the phase of the metal silicide layer at said first surface that is formed during the heat-application.
6. A method of fabricating a fully-silicided gate electrode layer according to claim 5 , wherein said forming at least one first layer of silicon comprises forming at least two silicon layers having respective different crystallinities.
7. A method of fabricating a fully-silicided gate electrode layer according to claim 1 , wherein said forming at least one first layer of silicon comprises forming at least two silicon layers having respective different crystallinities.
8. A method as claimed in claim 1 , wherein said forming at least one first layer of silicon comprises forming a layer of polycrystalline silicon and said forming an additional layer of silicon comprises forming a layer of polycrystalline silicon.
9. A method as claimed in claim 1 , wherein said simultaneously applying heat to the superposed first silicon layer(s), metal layer and additional silicon layer comprises a first anneal and a second anneal.