Lithium-containing transition metal oxide target, process for producing the same and lithium ion thin film secondary battery
View Patent ↗Proposed are a lithium-containing transition metal oxide target formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system in which the sintered compact has a relative density of 90% or higher and an average grain size of 1 μm or greater and 50 μm or less, and a lithium-containing transition metal oxide target formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system in which the intensity ratio of the (003) face, (101) face and (104) face based on X-ray diffraction using CuKα ray satisfies the following conditions: (1) Peak intensity ratio of the (101) face in relation to the (003) face is 0.4 or higher and 1.1 or lower; and (2) Peak ratio of the (101) face in relation to the (104) face is 1.0 or higher. In addition to this lithium-containing transition metal oxide target optimal for forming a thin film positive electrode for use in a thin film battery such as a three-dimensional battery and a solid state battery, also proposed are its production method and a lithium ion thin film secondary battery. In particular, the present invention aims to propose a positive electrode target capable of obtaining a thin film with superior homogeneity.
1. A lithium-containing transition metal oxide sputtering target for forming a thin film positive electrode of a lithium ion thin film secondary battery, formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system, wherein the sintered compact has a relative density of 90% or higher and an average grain size of 1 μm or greater and 50 μm or less.
2. A lithium-containing transition metal oxide sputtering target for forming a thin film positive electrode of a lithium ion thin film secondary battery according to claim 1 , wherein an intensity ratio of a (003) face, (101) face and (104) face based on X-ray diffraction using CuK a ray satisfies the following conditions: (1) Peak ratio of the (101) face in relation to the (003) face is 0.4 or higher and 1.1 or lower; and (2) Peak ratio of the (101) face in relation to the (104) face is 1.0 or higher.
3. The lithium-containing transition metal oxide target according to claim 2 , wherein the transition metal is at least one selected from Ni, Co, and Mn.
4. The production method of a lithium ion thin film secondary battery, wherein a lithium-containing transition metal oxide is used as the cathode active material by sputtering the lithium-containing transition metal oxide target according to claim 2 .
5. The lithium-containing transition metal oxide target according to claim 1 , wherein the transition metal is at least one selected from Ni, Co, and Mn.
6. The production method of a lithium ion thin film secondary battery, wherein a lithium-containing transition metal oxide is used as the cathode active material by sputtering the lithium-containing transition metal oxide target according to claim 1 .
7. The lithium-containing transition metal oxide target according to claim 1 , wherein the transition metal is Ni.
8. The lithium-containing transition metal oxide target according to claim 1 , wherein the target contains at least two different transition metals selected from the group consisting of Ni, Co and Mn.
9. The lithium-containing transition metal oxide target according to claim 1 , wherein the target contains three different transition metals including Ni, Co and Mn.
10. A production method of a lithium-containing transition metal oxide sputtering target for forming a thin film positive electrode of a lithium ion thin film secondary battery, comprising the steps of using lithium-containing transition metal salt as a precursor in which the molar ratio of Li/transition metal is 1.1 or more and 1.3 or less, oxidizing this to create lithium-containing transition metal oxides showing a hexagonal crystalline system, and pressing and sintering the lithium-containing transition metal oxides to obtain a sintered compact having a relative density of 90% or higher and an average grain size of 1 μm or greater and 50 μm or less.
11. The production method of a lithium-containing transition metal oxide sputtering target according to claim 10 , wherein the lithium-containing transition metal oxide sputtering target for forming a thin film positive electrode of a lithium ion thin film secondary battery, is formed from the sintered compact of lithium-containing transition metal oxides showing the hexagonal crystalline system, and wherein an intensity ratio of a (003) face, (101) face and (104) face based on X-ray diffraction using CuK a ray satisfies the following conditions: (1) Peak ratio of the (101) face in relation to the (003) face is 0.4 or higher and 1.1 or lower; and (2) Peak ratio of the (101) face in relation to the (104) face is 1.0 or higher.
12. The production method of a lithium-containing transition metal oxide target according to claim 11 , wherein the transition metal is at least one selected from Ni, Co, and Mn.
13. The production method of a lithium ion thin film secondary battery, wherein a lithium-containing transition metal oxide is used as the cathode active material by sputtering the lithium-containing transition metal oxide target according to claim 10 .
14. The production method of a lithium-containing transition metal oxide target according to claim 10 , wherein the transition metal is at least one selected from Ni, Co, and Mn.