Liquid dispensing systems encompassing gas removal
View Patent ↗Systems are described for delivery of a wide variety of materials in which liquid and gas or vapor states are concurrently present, from a package preferably including a fluid-containing collapsible liner. Headspace gas is removed from a pressure dispensing package prior to liquid dispensation therefrom, and ingress gas is removed thereafter during dispensation operation. At least one sensor senses presence of gas or a gas-liquid interface in a reservoir or gas-liquid separation region. A gas removal system including an integral reservoir, at least one sensor, and at least one flow control elements may be included within a connector adapted to mate with a pressure dispensing package, for highly efficient removal of gas from the liquid being dispensed from the container.
1. A connector adapted to mate with a pressure dispense package that includes a collapsible liner comprising a flexible material and arranged to hold a liquid, the connector comprising a gas removal apparatus including a ventable reservoir having a gas outlet disposed at a first level and a liquid outlet disposed at a second level arranged below the first level, and being adapted to receive liquid from the pressure dispense package, wherein the gas removal apparatus is adapted to remove gas from the liner before dispensing of a liquid from the liner;
wherein the connector further comprises a main body portion defining said reservoir and including a probe that interfaces with the liner to provide a fluid-tight seal between the liner and probe, with the probe including a conduit extending upwardly into the reservoir and terminating at an upper end of the conduit below an upper end of the reservoir, so that liquid flowing upwardly in the connector passes through the conduit and flows from the upper end thereof into the reservoir, for disengagement in the reservoir of gas from the liquid, to form a liquid level interface between the liquid and the gas in the reservoir.
2. A fluid dispensing system comprising:
a pressure dispense package adapted to hold fluid for pressure dispensing and including a vessel that defines an interior volume and a dispensing port; and
a gas removal apparatus adapted to remove gas from the pressure dispense package before pressure dispensation of the fluid;
wherein the gas removal apparatus includes a connector according to claim 1 adapted to mate with the vessel proximate to the dispensing port.
3. The system of claim 2 , wherein the gas removal apparatus is adapted to remove (i) headspace gas from the liner prior to dispensing of fluid therefrom and (ii) ingress gas entering the liner subsequent to removal of said headspace gas from the liner.
4. The system of claim 2 , wherein the vessel comprises an overpack container, said liner is disposed within said overpack container, and said overpack container comprises a wall material that is substantially more rigid than said flexible material.
5. The system of claim 2 , wherein said fluid comprises a microelectronic device manufacturing chemical reagent and is contained within the liner.
6. The system of claim 4 , further comprising a source of pressurized gas in fluid communication with a volume defined between the collapsible liner and the overpack container.
7. The system of claim 2 , wherein the gas removal apparatus further comprises:
a sensor adapted to sense accumulation of gas within the reservoir, and to responsively generate an output signal indicative of such condition; and
at least a first control element adapted to effect removal of gas from the reservoir responsive to the output signal.
8. The system of claim 7 , wherein the sensor comprises a capacitive sensor, a photosensor, or an optical sensor.
9. The system of claim 2 , wherein the ventable reservoir includes a vertical axis, an average internal cross-sectional area perpendicular to the vertical axis, and a gas collection zone disposed along an upper boundary of the ventable reservoir, wherein the gas collection zone has an internal cross-sectional area perpendicular to the vertical axis that is substantially smaller than the average internal cross-sectional area of the ventable reservoir.
10. The system of claim 9 , further comprising at least one baffle disposed within the ventable reservoir and adapted to promote transport of microbubbles to the gas collection zone.
11. The system of claim 2 , wherein the gas removal apparatus includes:
a bubble sensor operable to generate an output signal indicative of presence of bubbles in liquid dispensed from the pressure dispense package; and
a control element adapted to vent said ventable reservoir responsive to the output signal, to permit liquid substantially free of bubbles to be withdrawn from said ventable reservoir.
12. The system of claim 2 , wherein the gas removal apparatus includes:
a pressure transducer;
a chemical supply valve; and
a headspace removal valve;
wherein said headspace removal valve is operatively coupled with at least one sensor comprising any of a bubble sensor, a photodetector, and a capacitive sensor, to effect removal of gas from the pressure dispense package, and said chemical supply valve is adapted to modulate flow of the liquid dispensed from the pressure dispense package.
13. The system of claim 2 , further comprising an empty detect apparatus adapted to detect an empty state or approach to empty state of said pressure dispense package.
14. The system of claim 13 , wherein the empty detect apparatus includes a pressure transducer adapted to sense pressure droop of fluid dispensed from said pressure dispense package and to responsively generate a corresponding output signal.
15. The system of claim 2 , further comprising a switchover reservoir adapted to supply fluid deriving from said pressure dispense package, when said pressure dispense package is emptied or nearly emptied of said fluid.
16. The connector of claim 1 , wherein the gas removal apparatus is adapted to remove (i) headspace gas from the liner prior to dispensation of liquid therefrom, and (ii) ingress gas entering the liner subsequent to removal of said headspace gas from the liner.
17. The connector of claim 1 , wherein the gas removal apparatus further comprises at least one sensor adapted to sense accumulation of gas within the reservoir, and to responsively generate an output signal indicative of such condition.
18. The connector of claim 17 , wherein the gas removal apparatus further comprises at least a first control element adapted to effect removal of gas from the reservoir responsive to the output signal.
19. The connector of claim 1 , wherein the ventable reservoir includes a vertical axis, an average internal cross-sectional area perpendicular to the vertical axis, and a gas collection zone disposed along an upper boundary of the ventable reservoir, and wherein the gas collection zone includes an internal cross-sectional area perpendicular to the vertical axis that is substantially smaller than the average internal cross-sectional area of the ventable reservoir.
20. The connector of claim 19 , wherein the gas removal apparatus further comprises:
a sensor adapted to sense accumulation of gas within the gas collection zone, and to responsively generate an output signal indicative of such condition; and
at least a first control element adapted to effect removal of gas from the gas collection zone responsive to the output signal.
21. The connector of claim 1 , wherein the connector further comprises:
at least one sensor in sensing relationship with the reservoir;
a liquid discharge valve;
a gas discharge valve; and
a valve controller operatively coupled with the at least one sensor and responsively arranged to control said gas discharge valve and liquid discharge valve so as to separate gas from liquid in said reservoir, and to separately discharge said gas and said liquid.
22. The connector of claim 21 , wherein a pressure transducer is disposed in said main body portion, operatively coupled with said valve controller, and is arranged to detect an empty condition in the pressure dispense package.
23. A method comprising:
(a) pressure dispensing liquid from a pressure dispense package,
(b) removing headspace gas from the pressure dispense package prior to the pressure dispensing of liquid therefrom to a fluid-utilizing application, and
(c) removing unwanted gas entering the liquid subsequent to removal of said headspace gas from the pressure dispense package, throughout the pressure dispensing;
wherein steps (b) and (c) are performed using a gas removal apparatus including a connector according to claim 1 adapted to mate with the pressure dispense package.
24. The method of claim 23 , wherein said pressure dispense package comprises a liquid-containing liner disposed within an overpack container, and said pressure dispensing comprises supplying a pressurized gas to a space between the liner and the overpack container.
25. The method of claim 23 , further comprising:
passing said liquid to a ventable gas/liquid separation zone in said reservoir;
sensing presence or accumulation of gas in the gas/liquid separation zone; and
venting said gas from the gas/liquid separation zone responsive to the sensing step.
26. The method of claim 25 , wherein dispensation of liquid from the package to a liquid-utilizing process is performed continuously during said venting.
27. The connector of claim 1 , wherein the gas removal apparatus is adapted to remove gas from the liner before and during dispensing of liquid from the liner.
28. The system of claim 2 , wherein the gas removal apparatus is adapted to remove gas from the liner before and during dispensing of fluid from the liner.