IP Library Granted Patent US 8,518,783
Granted Patent B2
US 8,518,783 · App. 12/989,521 · Granted Aug 27, 2013

Gate structure for field effect transistor

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Quick Facts
Patent No.
US 8,518,783
App. No.
12/989,521
Granted
Aug 27, 2013
Kind
B2
Abstract

A field effect transistor having a gate structure that comprises an interfacial layer positioned in between the transistor channel region and a high-K dielectric layer of the gate stack. The interfacial layer comprises Al x Si y O z , which has a higher relative dielectric constant value than SiO 2 . A method of forming the gate structure of a field effect transistor. The method includes forming a gate stack comprising, in order: a SiO 2 -based layer adjacent a channel region of the field effect transistor; a high-K dielectric layer on the SiO 2 -based layer; and a gate electrode on the high-K dielectric layer. The method also includes introducing Al into the SiO 2 -based layer to form an Al x Si y O z interfacial layer in between the high-K dielectric layer and the channel region. A heating step to allows Al introduced into channel region to diffuse out of the channel region into the interfacial layer.

Claims (24)

1. A method of forming a gate structure of a field effect transistor, the method comprising:

forming a gate stack comprising, in order:

a SiO 2 -based layer adjacent a channel region of the field effect transistor;

a high-K dielectric layer on the SiO 2 -based layer; and

a gate electrode on the high-K dielectric layer;

performing an Al introduction step, whereby Al is introduced into the SiO 2 -based layer to form an Al x Si y O z interfacial layer in between the high-K dielectric layer and the channel region;

performing a heating step to allow Al introduced into the channel region during said Al introduction step to diffuse out of the channel region into the interfacial layer; and

compensating for a p-type tuning effect on the work function of the gate electrode due to the Al introduction step by adding n-type dopants to the gate electrode.

2. The method of claim 1 , wherein said Al introduction step comprises ion implantation.

3. The method of claim 2 , wherein the ion implantation is performed with an implantation energy in the range 2-8 keV.

4. The method of claim 3 , wherein the ion implantation is performed with a dosage level in the range 1×10 15 cm −2 to 6×10 15 cm −2 .

5. The method of claim 1 , wherein said Al introduction step comprises plasma doping (PLAD).

6. The method of claim 1 , comprising forming said gate structure on a MISFET, a FinFET, or a TrenchFET.

7. The method of claim 1 , wherein the heating step is performed at a temperature in the range 600° C. to 1100° C. for a duration between 1 s to less than a minute.

8. The method of claim 1 , wherein the heating step is performed at a temperature above 1000° C. and up to 1100° C.

9. A method of forming a gate structure of a field effect transistor, the method comprising:

forming a gate stack comprising, in order:

a SiO 2 -based layer adjacent a channel region of the field effect transistor;

a high-K dielectric layer on the SiO 2 -based layer; and

a gate electrode on the high-K dielectric layer;

performing an Al introduction step, whereby Al is introduced into the SiO 2 -based layer to form an AlSi y O z interfacial layer in between the high-K dielectric layer and the channel region;

performing a heating step to allow Al introduced into the channel region during said Al introduction step to diffuse out of the channel region into the interfacial layer; and

adding n-type dopants to the gate electrode;

wherein the step of adding n-type dopants further includes compensating for a p-type tuning effect on the work function of the gate electrode due to the Al introduction step.

Assignments (14)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
PATENT RELEASE Recorded Aug 17, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 039707/0471 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
PATENT RELEASE Recorded Apr 11, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.; MIZUHO BANK, LTD.
To: NXP B.V.
Reel/Frame 038400/0637 →
CERTIFICATE RE. TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Apr 11, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.; MIZUHO BANK, LTD.
To: NXP B.V.
Reel/Frame 038401/0296 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 15, 2016
From: NXP B.V.
To: UNITED MICROELECTRONICS CORP.
Reel/Frame 037973/0107 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2010
From: MUELLER, MARKUS; BOCCARDI, GUILLAUME; PETRY, JASMINE
To: NXP B.V.
Reel/Frame 025188/0557 →