Granted Patent B2

US 8,496,762 · App. 13/021,026 · Granted Jul 30, 2013

Abstract

Claims (22)

1. A method of preparing an aluminum or aluminum alloy substrate to accept an adherent coating thereon, the method comprising the steps of:

a) degreasing the substrate;

b) deoxidizing the substrate; and

c) providing a conversion coating on the degreased and deoxidized substrate, the conversion coating comprising:

i) a source of fluoride ions;

ii) a source of zirconium ions;

iii) an acrylic resin; and

iv) about 35 to about 100 ppm of an optical brightener selected from the group consisting of 4,4′-bis-(2-sulfostyryl)-biphenyl disodium salt, a bistriazinyl derivative of 4,4′-diaminostilbene-2,2′-disulfonic acid, sulfonated 2-(stilben-4-yl)naphthotriazoles, bis(azol-2-yl)stilbenes, bisstyrylbiphenyl sodium salt, a sufonated pyrazoline, and combinations of one or more of the foregoing,

wherein a chromium-free conversion coating is formed on the aluminum substrate that can be observed by exposing the treated substrate to UV light.

2. The method according to claim 1 , wherein the substrate is dried after the conversion coating is applied.

3. The method according to claim 2 , wherein the substrate is dried by heating the substrate to a temperature of between about 120 and 140° C.

4. The method according to claim 1 , wherein the pH adjuster is selected from the group consisting of mineral acids, organic acids, water soluble or water dispersible bases, amines, fluoroacids, and combinations of one or more of the foregoing.

5. The method according to claim 4 , wherein the pH adjuster is hydrofluoric acid.

6. The method according to claim 4 , wherein the source of fluoride ions is present in the aqueous composition at a concentration of between about 315 ppm to about 700 ppm.

7. The method according to claim 4 , wherein the source of zirconium ions is selected from the group consisting of alkali metal and ammonium fluorozirconates, zirconium carboxylates, and alkali metal and ammonium salts of zirconium hydroxy carboxylates.

8. The method according to claim 7 , wherein the source of zirconium ions is zirconium acetate.

9. The method according to claim 7 , wherein the source of zirconium ions is present in the aqueous composition at a concentration of between about 170 and about 400 ppm.

10. The method according to claim 1 , wherein the acrylic resin comprises a water soluble polyacrylic acid.

11. The method according to claim 10 , wherein the water soluble polyacrylic acid has a molecular weight of between about 50,000 to about 75,000.

12. The method according to claim 10 , wherein the acrylic resin is present in the aqueous composition at a concentration of between about 700 and about 2000 ppm.

13. The method according to claim 1 , wherein the optical brightener is 4,4′-bis-(2-sulfostyryl)-biphenyl disodiurn salt.

14. The method according to claim 1 , comprising the step of coating the conversion coated substrate with a film forming resin.

Assignments (8)