Stress-reduced Ni-P/Pd stacks for bondable wafer surfaces
View Patent ↗The invention relates to a substrate having a bondable metal coating comprising, in this order, on an Al or Cu surface: (a) a Ni—P layer, (b) a Pd layer and, optionally, (c) an Au layer, wherein the thickness of the Ni—P layer (a) is 0.2 to 10 m, the thickness of the Pd layer (b) is 0.05 to 1.0 m and the thickness of the optional Au layer (c) is 0.01 to 0.5 m, and wherein the Ni—P layer (a) has a P content of 10.5 to 14 wt.-%. The deposit internal stress of the resulting Ni—P/Pd stack is not higher than 34.48M−Pa (5,000 psi). Further, a process for the preparation of such a substrate is described.
1. A process for the preparation of a substrate having a bondable metallic coating comprising, in this order, on an Al or Cu surface:
(a) a Ni—P layer having a thickness of 0.2 to 10 μm and a P content of 10.5 to 14 wt.-%,
(b) a Pd layer having a thickness of 0.05 to 1.0 μm and, optionally,
(c) an Au layer having a thickness of 0.01 to 0.5 μm,
wherein a stack consisting of a Ni—P layer (a) and a Pd layer (b) has a deposit internal stress not higher than 34.48 MPa (5,000 psi),
the process comprising the following steps:
(i) immersing a substrate having an Al or Cu surface in a Ni—P plating bath comprising a nickel salt, and hypophosphorus acid or a bath-soluble salt thereof selected from sodium hypophosphite, potassium hypophosphite and ammonium hypophosphite, wherein the solution is free of alkali or alkaline earth metal ions capable of forming an insoluble orthophosphite
at a temperature of from about 70° C. to about 95° C. and at a pH of from about 3 to about 6 for a period of 1 to 30 min to obtain a Ni—P layer on the substrate and
(ii) immersing the Ni—P-coated substrate obtained in step (i) in a Pd plating bath comprising at least one palladium ion source, at least one reducing agent, at least one complexing agent and at least one sulfimide stabilizer additive in a quantity of 10 to 500 mg/l
at a pH of 5 to 6.5 for a period of 3 to 20 min to obtain a Pd layer on the substrate,
wherein the Pd layer is deposited onto the Ni—P layer obtained in step (i) without any activation of the Ni—P layer prior to deposition of the Pd layer and step (ii) is carried out at a temperature of from about 70 to about 90° C. or
wherein the Pd layer is deposited onto the Ni—P layer obtained in step (i) after activation of the Ni—P layer and step (ii) is carried out at a temperature of from about 40 to about 95° C.
2. The process according to claim 1 wherein the substrate is an Al wafer, the surface of which is cleaned and etched or followed by zincation prior to step (i).
3. The process according to claim 1 wherein the substrate is a Cu wafer, the surface of which is cleaned, optionally, etched, followed by Pd activation prior to step (i).
4. The process according to claim 1 , further comprising: (iii) a step of immersing the substrate coated with the Ni—P layer and the Pd layer into an Au plating bath.
5. The process according to claim 2 , further comprising: (iii) a step of immersing the substrate coated with the Ni—P layer and the Pd layer into an Au plating bath.
6. The process according to claim 3 , further comprising: (iii) a step of immersing the substrate coated with the Ni—P layer and the Pd layer into an Au plating bath.