IP Library Granted Patent US 9,548,206
Granted Patent B2
US 9,548,206 · App. 13/182,679 · Granted Jan 17, 2017

Ohmic contact structure for group III nitride semiconductor device having improved surface morphology and well-defined edge features

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Quick Facts
Patent No.
US 9,548,206
App. No.
13/182,679
Granted
Jan 17, 2017
Kind
B2
Abstract

Embodiments of an ohmic contact structure for a Group III nitride semiconductor device and methods of fabrication thereof are disclosed. In general, the ohmic contact structure has a root-mean-squared (RMS) surface roughness of less than 10 nanometers, and more preferably less than or equal to 7.5 nanometers, and more preferably less than or equal to 5 nanometers, and more preferably less than or equal to 2 nanometers, and even more preferably less than or equal to 1.5 nanometers.

Claims (77)

1. A semiconductor device comprising:

a Group III nitride semiconductor structure;

an ohmic contact structure having a root-mean-squared (RMS) surface roughness in a range between about 1.3 nanometers (nm) and about 10 nm on a surface of the Group III nitride semiconductor structure; and

an alternating series of one or more silicon layers and one or more nickel layers opposite the Group III nitride semiconductor structure.

2. The semiconductor device of claim 1 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 7.5 nm.

3. The semiconductor device of claim 1 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 5 nm.

4. The semiconductor device of claim 1 wherein the ohmic contact structure comprises:

a titanium layer on the surface of the Group III nitride semiconductor structure, wherein the alternating series of one or more silicon layers and one or more nickel layers is on a surface of the titanium layer opposite the Group III nitride semiconductor structure.

5. The semiconductor device of claim 4 wherein the ohmic contact structure further comprises a metal cap layer on a surface of the alternating series of the one or more silicon layers and the one or more nickel layers opposite the titanium layer.

6. The semiconductor device of claim 4 wherein the alternating series of the one or more silicon layers and the one or more nickel layers is an alternating series of two or more silicon layers and two or more nickel layers.

7. The semiconductor device of claim 1 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 2 nm.

8. The semiconductor device of claim 1 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 1.5 nm.

9. A semiconductor device comprising:

a Group III nitride semiconductor structure; and

an ohmic contact structure having a root-mean-squared (RMS) surface roughness in a range between about 1.3 nanometers (nm) and about 10 nm on a surface of the Group III nitride semiconductor structure, wherein the ohmic contact structure comprises:

a titanium layer on the surface of the Group III nitride semiconductor structure;

a first silicon layer on a surface of the titanium layer opposite the Group III nitride semiconductor structure;

a first nickel layer on a surface of the first silicon layer opposite the titanium layer;

a second silicon layer on a surface of the first nickel layer opposite the first silicon layer;

a second nickel layer on a surface of the second silicon layer opposite the first nickel layer;

a third silicon layer on a surface of the second nickel layer opposite the second silicon layer; and

a third nickel layer on a surface of the third silicon layer opposite the second nickel layer.

10. The semiconductor device of claim 9 wherein a thickness of the titanium layer is in a range of and including 200 Angstroms±10%.

11. The semiconductor device of claim 10 wherein:

a thickness of the first silicon layer is in a range of and including 500 Angstroms±15%;

a thickness of the first nickel layer is in a range of and including 250 Angstroms±5%;

a thickness of the second silicon layer is in a range of and including 500 Angstroms±10%;

a thickness of the second nickel layer is in a range of and including 250 Angstroms±5%;

a thickness of the third silicon layer is in a range of and including 500 Angstroms±10%; and

a thickness of the third nickel layer is in a range of and including 250 Angstroms±5%.

12. The semiconductor device of claim 11 wherein the ohmic contact structure further comprises a metal cap layer on a surface of the third nickel layer opposite the third silicon layer.

13. The semiconductor device of claim 12 wherein a thickness of the metal cap layer is in a range of and including 100 Angstroms±50%.

14. The semiconductor device of claim 13 wherein the metal cap layer is formed of one of a group consisting of: platinum (Pt), palladium (Pd), vanadium (V), tungsten (W), Iridium (Jr), and Rhodium (Rh).

15. The semiconductor device of claim 13 wherein the metal cap layer is formed of platinum (Pt).

16. The semiconductor device of claim 11 wherein, as a result of thermal annealing, the first silicon layer, the first nickel layer, the second silicon layer, the second nickel layer, the third silicon layer, and the third nickel layer chemically react to form a nickel silicide layer.

17. A method of fabrication of a semiconductor device comprising:

providing a Group III nitride semiconductor structure;

providing an ohmic contact structure having a root-mean-squared (RMS) surface roughness in a range between about 1.3 nanometers (nm) and about 10 nm on a surface of the Group III nitride semiconductor structure; and

providing an alternating series of one or more silicon layers and one or more nickel layers opposite the Group III nitride semiconductor structure.

18. The method of claim 17 wherein providing the ohmic contact structure further comprises:

providing a titanium layer on a surface of the Group III nitride semiconductor structure where the alternating series of one or more silicon layers and one or more nickel layers are provided on a surface of the titanium layer opposite the Group III nitride semiconductor structure;

providing a metal cap layer on a surface of the alternating series of the one or more silicon layers and the one or more nickel layers opposite the titanium layer; and

thermally annealing the ohmic contact structure at a temperature sufficient for the alternating series of the one or more silicon layers and the one or more nickel layers to chemically react to form nickel silicide but low enough to prevent the titanium layer from significantly reacting with the alternating series of the one or more silicon layers and the one or more nickel layers.

19. The method of claim 18 wherein the alternating series of the one or more silicon layers and the one or more nickel layers is an alternating series of two or more silicon layers and two or more nickel layers.

20. The method of claim 17 wherein providing the ohmic contact structure comprises:

providing a titanium layer on a surface of the Group III nitride semiconductor structure and providing an alternating series of one or more silicon layers and one or more nickel layers opposite the Group III nitride semiconductor structure further comprises:

providing a first silicon layer on a surface of the titanium layer opposite the Group III nitride semiconductor structure;

providing a first nickel layer on a surface of the first silicon layer opposite the titanium layer;

providing a second silicon layer on a surface of the first nickel layer opposite the first silicon layer;

providing a second nickel layer on a surface of the second silicon layer opposite the first nickel layer;

providing a third silicon layer on a surface of the second nickel layer opposite the second silicon layer;

providing a third nickel layer on a surface of the third silicon layer opposite the second nickel layer;

providing a metal cap layer on a surface of the third nickel layer opposite the third silicon layer; and

thermally annealing the ohmic contact structure at a temperature sufficient for the first silicon layer, the first nickel layer, the second silicon layer, the second nickel layer, the third silicon layer, and the third nickel layer to chemically react to form nickel silicide but low enough to prevent the titanium layer from significantly reacting with the first silicon layer.

21. The method of claim 20 wherein thermally annealing the ohmic contact structure comprises thermally annealing the ohmic contact structure at a temperature in a range of and including 200° C. to 600° C.

22. The method of claim 20 wherein a thickness of the titanium layer is in a range of and including 200 Angstroms±10%.

23. The method of claim 22 wherein:

a thickness of the first silicon layer is in a range of and including 500 Angstroms±15%;

a thickness of the first nickel layer is in a range of and including 250 Angstroms±5%;

a thickness of the second silicon layer is in a range of and including 500 Angstroms±10%;

a thickness of the second nickel layer is in a range of and including 250 Angstroms±5%;

a thickness of the third silicon layer is in a range of and including 500 Angstroms±10%; and

a thickness of the third nickel layer is in a range of and including 250 Angstroms±5%.

24. The method of claim 23 wherein a thickness of the metal cap layer is in a range of and including 100 Angstroms±50%.

25. The method of claim 24 wherein the metal cap layer is formed of one of a group consisting of: platinum (Pt), palladium (Pd), vanadium (V), tungsten (W), Iridium (Ir), and Rhodium (Rh).

26. The method of claim 24 wherein the metal cap layer is formed of platinum (Pt).

27. The method of claim 17 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 7.5 nm.

28. The method of claim 17 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 5 nm.

29. The method of claim 17 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 2 nm.

30. The method of claim 17 wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 1.5 nm.

31. A semiconductor device comprising:

a Group III nitride semiconductor structure; and

an ohmic contact structure having a root-mean-squared (RMS) surface roughness in a range between about 1.3 nanometers (nm) and about 10 nanometers (nm) on a surface of the Group III nitride semiconductor structure, wherein the ohmic contact structure comprises:

a titanium layer on the surface of the Group III nitride semiconductor structure; and

a nickel silicide layer on a surface of the titanium layer opposite the Group III nitride semiconductor structure.

32. The semiconductor device of claim 31 , wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 5 nm.

33. The semiconductor device of claim 31 , wherein the RMS surface roughness of the ohmic contact structure is less than or equal to 1.5 nm.

Assignments (9)
NOTICE OF GRANT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Mar 26, 2026
From: WOLFSPEED, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 075280/0919 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL AT REEL/FRAME NO. 64185/0755 Recorded Sep 30, 2025
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: WOLFSPEED, INC.
Reel/Frame 072989/0001 →
NOTICE OF GRANT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Sep 30, 2025
From: WOLFSPEED, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 072992/0113 →
NOTICE OF GRANT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Sep 30, 2025
From: WOLFSPEED, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 072992/0381 →
NOTICE OF GRANT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Sep 30, 2025
From: WOLFSPEED, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 072992/0467 →
NOTICE OF GRANT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Sep 30, 2025
From: WOLFSPEED, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 072992/0588 →
SECURITY INTEREST Recorded Jun 30, 2023
From: WOLFSPEED, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 064185/0755 →
CHANGE OF NAME Recorded Oct 22, 2021
From: CREE, INC.
To: WOLFSPEED, INC.
Reel/Frame 057891/0880 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 14, 2011
From: HAGLEITNER, HELMUT; GURGANUS, JASON
To: CREE, INC.
Reel/Frame 026591/0850 →